AAC  >> Vol. 3 No. 3 (August 2013)

    基于金纳米粒子的对乙酰氨基酚传感器的研究
    Electrochemical Sensor for Acetaminophen Based on Gold Nanoparticles

  • 全文下载: PDF(750KB) HTML   XML   PP.15-21   DOI: 10.12677/AAC.2013.33004  
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作者:  

庞莹:辽宁师范大学化学化工学院,大连;
徐芬:辽宁师范大学化学化工学院,大连;桂林电子科技大学材料科学与工程学院;
孙立贤:桂林电子科技大学材料科学与工程学院,桂林

关键词:
对乙酰氨基酚金纳米粒子修饰电极循环伏安法Acetaminophen; Au Nanoparticles; Modified Electrode; Cyclic Voltammetry

摘要:
本文采用循环伏安法将金纳米粒子修饰在玻碳电极表面,制备了GNPs/GC修饰电极。对修饰电极进行电化学及表面形貌的表征,通过循环伏安法和交流阻抗法研究了ACOPGNPs/GC电极上的电化学行为。本文探讨了不同实验条件对电极性能的影响,在最优条件下,ACOP线性浓度范围分别为2.0 × 107~2.0 × 105 molL11.4 × 104~3.78 × 103 mol∙L1,其检出限为3.6 × 108 molL1(S/N = 3:1),回收率97.7%~101.0%。 

A kind of GNPs/GC modified electrode was prepared by electrodeposited gold nanoparticles on the surface of glassy carbon electrode based on the cyclic voltammetry. Electrochemical properties and surface morphology of the modified electrode were characterized. The electrochemical behaviors of acetaminophen (ACOP) at GNPs/GC electrode were investigated by cyclic voltammetry and electrochemical impedance spectrum (EIS). The influences of different experimental conditions on the electrode performance were discussed. Under optimal conditions, a linear relationship of ACOP concentration with peak current was obtained over the concentration range of 2.0 × 10−7 - 2.0 × 10−5 mol∙L−1 and 1.4 × 10−4 - 3.78 × 10−3 mol∙L−1, respectively. The detection limit was 3.6 × 10−8 mol∙L−1 (S/N = 3:1) and the recovery was 97.7% - 101.0%.

文章引用:
庞莹, 徐芬, 孙立贤. 基于金纳米粒子的对乙酰氨基酚传感器的研究[J]. 分析化学进展, 2013, 3(3): 15-21. http://dx.doi.org/10.12677/AAC.2013.33004

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