AAC  >> Vol. 4 No. 1 (February 2014)

    B-Z化学振荡反应在分析检测中的应用
    Application of B-Z Oscillating Chemical Reaction to Analytical Determination

  • 全文下载: PDF(242KB) HTML    PP.7-10   DOI: 10.12677/AAC.2014.41002  
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作者:  

魏晓霞,张小伟:陇东学院应用化学研究所,庆阳;
高锦章:西北师范大学化学化工学院,兰州

关键词:
B-Z化学振荡反应规则振荡混沌非平衡定态检测B-Z Oscillating Chemical Reaction; Regular Oscillation; Chaos; Non-Equilibrium Stationary State; Determination

摘要:
简单介绍了经典B-Z化学振荡体系,综述了化学振荡的各种行为,规则振荡、混沌、分叉在分析检测中的应用,展望了应用前景。

A brief introduction has been made for classical B-Z oscillation chemical reaction. The application of regular oscillation, chaos, and non-equilibrium stationary state in analytical determination was described. Finally, the prospec- tives of oscillation chemical reaction research and application are prospected.

文章引用:
魏晓霞, 张小伟, 高锦章. B-Z化学振荡反应在分析检测中的应用[J]. 分析化学进展, 2014, 4(1): 7-10. http://dx.doi.org/10.12677/AAC.2014.41002

参考文献

[1] 辛厚文 (1999) 非线性化学. 中国科学技术大学出版社, 合肥.
[2] Goryachev, A., Strizhak, P.E. and Kapral, R. (1997) Slow mani- fold structure and the emergence of mixed-mode oscillations. The Journal of Chemical Physics, 107, 2881-2889.
[3] Kawczynski, A.L. and Strizhak, P.E. (2000) Period adding and broken Farey tree sequence of bifurcations for mixed-mode os- cillations and chaos in the simplest three-variable nonlinear sys- tem. The Journal of Chemical Physics, 112, 6122-6130.
[4] Taylor, A.F. (2002) Mechanism and phenomenology of an oscil- lating chemical reaction. Progress in Reaction Kinetics and Me- chanism, 27, 247-325.
[5] Gao, J.Z., Wei, X.X., Yang, W., et al. (2006) Determination of 1-Naphthylamine using oscillating chemical reaction. Journal of Hazardous Materials, 144, 67-72.
[6] Marek, M. and Svobodova, E. (1975) Nonlinear phenomena in oscillatory systems of homogeneous reactions-experimental ob- servations. Biophysical Chemistry, 3, 263-273.
[7] 刘秀辉, 杨华, 高锦章, 等 (2001) 氟对别洛索夫-扎鲍京斯基振荡反应的影响. 分析化学, 11, 1318-1321.
[8] Jimenez-Prieto, R., Silva, M. and Perez-Bendito, D. (1995) Analyte pulse perturbation technique: A tool for analytic deter- mination in far from equilibrium dynamic system. Analytical Chemistry, 67, 729-734.
[9] 王洪波, 董元彦 (2003) 化学振荡反应研究进展. 化工时刊, 6, 8-11.
[10] Fell, J., et al. (1993) Deterministic chaos and the first positive Lyapunov exponents: A nonlinear analysis of the human elec- trencephalogram during sleep. Biological Cybernetics, 2, 139- 146.
[11] Strizhak, P.E. (2003) Application of chemical chaos to analytical chemistry. Advances in Complex Systems, 6, 1-17.
[12] Vukojevic, V.B., Pejic, N.D., Stanisavljev, D.R., et al. (1999) Determination of Cl−, Br−, I−, Mn2+, malonic acid and quercetin by perturbation of a non-equilibrium stationary state in the Bray- Liebhafsky reaction. Analyst, 124, 147-152.
[13] Pejic, N.D., Kolar-Anic, L., Anic, S., et al. (2006) Determination of paracetamol in pure and pharmaceutical dosage forms by pul- se perturbation technique. Journal of Pharmachutical and Bio- medical Analysis, 41, 610-615.