海洋氧化亚氮研究现状与展望
Research Status and Prospect of Marine Nitrous Oxide
DOI: 10.12677/AG.2014.43014, PDF, HTML, 下载: 3,258  浏览: 12,373 
作者: 林华：厦门大学环境与生态学院，厦门
关键词: 氧化亚氮；分布；机制；通量；Nitrous Oxide； Distribution； Mechanism； Flux
摘要: 氧化亚氮(N2O)是主要的温室气体之一，影响全球气候，对大气化学也有着重要作用。而海洋是大气中N2O的重要排放源，特别是在近岸海区，N2O的释放量尤为显著。本文概述了海洋中N2O的分布特征、产生和消耗的控制机理及海–气N2O交换通量，并展望了海水N2O的新技术方法，如稳定同位素技术和波长扫描–光腔衰荡光谱技术，以期成为今后海洋N2O的研究利器。
Abstract: Nitrous oxide (N2O) is an important greenhouse gas, playing a significant role in the global climate system. The world ocean is believed to be a net natural source of atmospheric N2O, among which the coastal ocean is responsible for a large part of the oceanic N2O emissions. In this paper, the present research progresses of the marine N2O dissolution, fluxes and behavior are reviewed, and in addition, new methods determining the dissolved N2O are introduced, including stable isotopes application and wavelength-scanned cavity ring-down spectrophotometer, so as to provide novel techniques for researching of ocean N2O cycle in the future.
文章引用：林华. 海洋氧化亚氮研究现状与展望 [J]. 地球科学前沿, 2014, 4(3): 115-121. http://dx.doi.org/10.12677/AG.2014.43014

参考文献

[1] Solomon, S., Qin, D., Manning, M., Chen, Z., Marquis, M., Averyt, K.B., Tignor, M. and Miller, H.L. (2007) Climate change 2007: The physical science basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press, Cambridge.
[2] Albritton, D., Derwent, R., Isaksen, I. and Wuebbles, L.M. (1996) Radiative forcing of climate change. In: Houghton, J.T., et al., Eds., Climate Change 1995: The Science of Climate Change, Cambridge University Press, New York, 118- 131.
[3] Crutzen, P.J. (1970) The influence of nitrogen oxides on the atmospheric ozone content (NO and nitrogen dioxide influence on ozone concentration and production rate in stratosphere). Royal Meteorological Society, Quarterly Journal, 96, 320-325.
[4] Khalil, M.A.K. and Rasmussen, R.A. (1992) The global sources of nitrous oxide. Journal of Geophysical Research, 97, 14651-14660.
[5] Nevison, C.D., Weiss, R.F. and Erickson Iii, D.J. (1995) Global oceanic emissions of nitrous oxide. Journal of Geophysical Research, 100, 15809-15820.
[6] Seitzinger, S.P., Kroeze, C. and Styles, R.V. (2000) Global distribution of N2O emissions from aquatic systems: Natural emissions and anthropogenic effects. Chemosphere-Global Change Science, 2, 267-279.
[7] Bange, H.W., Rapsomanikis, S. and Andreae, M.O. (1996) Nitrous oxide in coastal waters. Global Biogeochemical Cycles, 10, 197-207.
[8] Naqvi, S.W.A., Jayakumar, D.A., Narvekar, P.V., Naik, H., Sarma, V.V.S.S., D’Suza, W., Joseph, S. and George, M.D. (2000) Increased marine production of N2O due to intensifying anoxia on the Indian continental shelf. Nature, 408, 346-349.
[9] Gruber, N. (2008) Nitrogen in the marine environment. 2nd Edition, Academic Press, San Diego, 1-51.
[10] Codispoti, L.A. and Christensen, J.P. (1985) Nitrification, denitrification and nitrous oxide cycling in the eastern tropical South Pacific Ocean. Marine Chemistry, 16, 277-300.
[11] Kim, K. and Craig, H. (1990) Two-isotope characterization of N2O in the Pacific Ocean and constraints on its origin in deep water. Nature, 347, 58-61.
[12] Butler, J.H., Elkins, J.W. and Thompson, T.M. (1989) Tropospheric and dissolved N2O of the West Pacific and East Indian Oceans during the EI Nino southern oscillation event of 1987. Journal of Geophysical Research, 94, 14865- 14877.
[13] Cohen, Y. (1978) Consumption of dissolved nitrous oxide in an anoxic basin, Saanich inlet, British-Columbia. Nature, 272, 235-237.
[14] Walter, S., Breitenbach, U., Bange, H.W., Nausch, G. and Wallace, D.W.R. (2006) Distribution of N2O in the Baltic Sea during transition from anoxic to oxic conditions. Biogeosciences, 3, 557-570.
[15] Elkins, J.W., Wofsy, S.C., McElroy, M.B., Kaplan, W.A. and Kolb, C.E. (1978) Aquatic sources and sinks for nitrous oxide. Nature, 275, 602-606.
[16] Bange, H.W., Rapsomanikis, S. and Andreae, M.O. (1996) Nitrous oxide emissions from the Arabian Sea. Geophysical Research Letters, 23, 3175-3178.
[17] de Bie, M.J.M., Middelburg, J.J., Starink, M. and Laanbroek, H.J. (2002) Factors controlling nitrous oxide at the microbial community and estuarine scale. Marine Ecology Progress Series, 240, 1-9.
[18] Dai, M., Wang, L., Guo, X., Zhai, W., Li, Q., He, B. and Kao, S.J. (2008) Nitrification and inorganic nitrogen distribution in a large perturbed river/estuarine system: The Pearl River Estuary, China. Biogeosciences, 5, 1227-1244.
[19] Seitzinger, S.P., Pilson, M.E.Q. and Nixon, S.W. (1983) Nitrous oxide production in nearshore marine sediments. Science, 222, 1244-1246.
[20] Hemond, H.F. and Duran, A.P. (1989) Fluxes of N2O at the sediment-water and water-atmosphere boundaries of a nitrogen-rich river. Water Resources Research, 25, 839-846.
[21] Howarth, R.W., Billen, G., Swaney, D., Townsend, A., Jaworski, N., Lajtha, K., Downing, J.A., Elmgren, R., Caraco, N. and Jordan, T. (1996) Regional nitrogen budgets and riverine N & P fluxes for the drainages to the North Atlantic Ocean: Natural and human influences. Biogeochemistry, 35, 75-139.
[22] De Wilde, H.P.J. and De Bie, M.J.M. (2000) Nitrous oxide in the Schelde Estuary: Production by nitrification and emission to the atmosphere. Marine Chemistry, 69, 203-216.
[23] de Bie, M.J.M., Starink, M., Boschker, H.T.S., Peene, J.J. and Laanbroek, H.J. (2002) Nitrification in the Schelde Estuary: Methodological aspects and factors influencing its activity. FEMS Microbiology Ecology, 42, 99-107.
[24] Barnes, J. and Owens, N.J.P. (1998) Denitrification and nitrous oxide concentrations in the Humber Estuary, UK, and adjacent coastal zones. Marine Pollution Bulletin, 37, 247-260.
[25] Usui, T., Koike, I. and Ogura, N. (2001) N2O production, nitrification and denitrification in an estuarine sediment. Estuarine, Coastal and Shelf Science, 52, 769-781.
[26] Cornejo, M., Farias, L. and Gallegos, M. (2007) Seasonal cycle of N2O vertical distribution and air-sea fluxes over the continental shelf waters off central Chile (~36˚S). Progress in Oceanography, 75, 383.
[27] Pierotti, D. and Rasmussen, R.A. (1980) Nitrous oxide measurements in the Eastern Tropical Pacific Ocean. Tellus, 32, 56-72.
[28] Ronner, U. (1983) Distribution, production and consumption of nitrous oxide in the Baltic Sea. Geochimica et Cosmochimica Acta, 47, 2179-2188.
[29] Upstill-Goddard, R.C., Barnes, J. and Owens, N.J.P. (1999) Nitrous oxide and methane during the 1994 SW monsoon in the Arabian Sea/northwestern Indian Ocean. Journal of Geophysical Research-Oceans, 104, 30067-30084.
[30] Oudot, C., Jean-Baptiste, P., Fourre, E., Mormiche, C., Guevel, M., Ternon, J.F. and Le Corre, P. (2002) Transatlantic equatorial distribution of nitrous oxide and methane. Deep-Sea Research Part I—Oceanographic Research Papers, 49, 1175-1193.
[31] Walter, S., Bange, H.W., Breitenbach, U. and Wallace, D.W.R. (2006) Nitrous oxide in the North Atlantic Ocean. Biogeosciences, 3, 607-619.
[32] Bange, H.W. and Andreae, M.O. (1999) Nitrous oxide in the deep waters of the world’s oceans. Global Biogeochemical Cycles, 13, 1127-1135.
[33] Bange, H.W., Rapsomanikis, S. and Andreae, M.O. (2001) Nitrous oxide emissions from the Arabian Sea: A synthesis. Atmospheric Chemistry and Physics, 1, 61-71.
[34] Hashimoto, L.K., Kaplan, W.A., Wofsy, S.C. and McElroy, M.B. (1983) Transformations of fixed nitrogen and N2O in the Cariaco Trench. Deep Sea Research Part A. Oceanographic Research Papers, 30, 575-590.
[35] Abril, G., Riou, S.A., Etcheber, H., Frankignoulle, M., de Wit, R. and Middelburg, J.J. (2000) Transient, tidal time- scale, nitrogen transformations in an estuarine turbidity maximum-fluid mud system (The Gironde, South-West France). Estuarine, Coastal and Shelf Science, 50, 703-715.
[36] Bange, H.W. (2008) Nitrogen in the marine environment. 2nd Edition, Academic Press, San Diego, 51-94.
[37] Suntharalingam, P., Sarmiento, J.L. and Toggweiler, J.R. (2000) Global significance of nitrous oxide production and transport from oceanic low-oxygen zones: A modeling study. Global Biogeochemical Cycles, 14, 1353-1370.
[38] Codispoti, L.A. (2010) Interesting times for marine N2O. Science, 327, 1339-1340.
[39] Butler, J.H. and Elkins, J.W. (1991) An automated technique for the measurement of dissolved N2O in natural waters. Marine Chemistry, 34, 47-61.
[40] Punshon, S. and Moore, R.M. (2004) Nitrous oxide production and consumption in a eutrophic coastal embayment. Marine Chemistry, 91, 37-51.
[41] Yoshida, N., Hattori, A., Saino, T., Matsuo, S. and Wada, E. (1984) 15N/14N ratio of dissolved N2O in the eastern Tropical Pacific Ocean. Nature, 307, 442-444.
[42] Yamagishi, H., Westley, M.B., Popp, B.N., Toyoda, S., Yoshida, N., Watanabe, S., Koba, K. and Yamanaka, Y. (2007) Role of nitrification and denitrification on the nitrous oxide cycle in the eastern tropical North Pacific and Gulf of California. Journal of Geophysical Research, 112.
[43] Toyoda, S., Yoshida, N., Miwa, T., Matsui, Y., Yamagishi, H., Tsunogai, U., Nojiri, Y. and Tsurushima, N. (2002) Production mechanism and global budget of N2O inferred from its isotopomers in the western North Pacific. Geophysical Research Letters, 29.
[44] Popp, B.N., Westley, M.B., Toyoda, S., Miwa, T., Dore, J.E., Yoshida, N., Rust, T.M., Sansone, F.J., Russ, M.E., Ostrom, N.E. and Ostrom, P.H. (2002) Nitrogen and oxygen isotopomeric constraints on the origins and sea-to-air flux of N2O in the oligotrophic subtropical North Pacific gyre. Global Biogeochemical Cycles, 16.
[45] Balslev-Clausen, D., Farinas, A., Buizert, C., Crosson, E. and Blunier, T. (2010) Continuous in field measurements of N2O concentration and its isotopologue and isotopomer ratios, with a field deployed mid-infrared, wavelength scanned, cavity ring-down spectroscopy instrument. EGU General Assembly Conference Abstracts, 12, 6974.