NaGd(MoO4)2: Tb3+, Eu3+荧光粉的水热合成及发光性质研究
Hydrothermal Synthesis and Luminescent Properties of Spindle-Like NaGd(MoO4)2: Tb3+, Eu3+ Phosphors
DOI: 10.12677/APP.2015.512026, PDF, HTML, XML,  被引量 下载: 2,526  浏览: 8,120 
作者: 丁 瑶*：哈尔滨师范大学，物理与电子工程学院，黑龙江 哈尔滨
关键词: 水热法；NaGd(MoO4)2；Tb3+；Eu3+；Hydrothermal Synthesis； NaGd(MoO4)2； Tb3+； Eu3+
摘要: 采用水热法合成了NaGd(MoO4)2: Tb3+, Eu3+荧光粉。利用X射线衍射(XRD)对样品进行了测试，所制样品的衍射峰与标准卡片PDF#25-08282一致。样品的发光性质通过激发光谱和发射光谱进行了表征。证实了从Tb3+到Eu3+有能量传递的存在。
Abstract: Tb3+, Eu3+ codoped NaGd(MoO4)2 phosphors were prepared by the method of hydrothermal pro- cess. The structure of the phosphors was characterized by the X-ray diffraction (XRD), which was corresponded to JCPDS card with # 25-0828. The photoluminescence properties of the prepared products were characterized by the excitation and emission spectra. The energy transfer from Tb3+ to Eu3+ in NaGd(MoO4)2 phosphors was confirmed.
文章引用：丁瑶. NaGd(MoO4)2: Tb3+, Eu3+荧光粉的水热合成及发光性质研究[J]. 应用物理, 2015, 5(12): 188-194. http://dx.doi.org/10.12677/APP.2015.512026

参考文献

[1] Zhang, Q., Meng, Q.Y. and Sun, W.J. (2013) The Concentration Dependence of Luminescent Properties for Eu3+ Doped CaWO4 Micron Spherical Phosphors. Journal of Optical Materials, 35, 915-922.
http://dx.doi.org/10.1016/j.optmat.2012.11.012
[2] Zhang, Y. and Hao, J.H. (2013) Metal-Ion Doped Luminescent Thin Films for Optoelectronic Applications. Journal of Materials Chemistry C, 1, 5607-5618.
http://dx.doi.org/10.1039/c3tc31024h
[3] Zhang, Z.W., Ma, D.Q., Yue, Y., Ma, M.Z. and Liu, R.P. (2015) Wide-Band Excited LaBMoO6:Eu3+ Red Phosphor for White-Light-Emitting Diode. Journal of Alloys and Compounds, 636, 113-116.
http://dx.doi.org/10.1016/j.jallcom.2015.01.134
[4] Wen, D.W., Feng, J.J., Li, J.H., Shi, J.X., Wu, M.M. and Su, Q. (2015) K2Ln(PO4)(WO4):Tb3+, Eu3+ (Ln = Y, Gd and Lu) Phosphors: Highly Efficient Pure Red and Tuneable Emission for White Light-Emitting Diodes. Journal of Materials Chemistry C, 3, 2107-2114.
[5] Liu, Y., Liu, G.X., Wang, J.X., Dong, X.T. and Yu, W.S. (2014) Single-Component and Warm-White-Emitting Phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: Synthesis, Luminescence, Energy Transfer and Tunable Color. Inorganic Chemistry, 53, 11457-11466.
http://dx.doi.org/10.1021/ic501284y
[6] Kang, F.W., Peng, M.Y., Zhang, Q.Y. and Qiu, J.R. (2014) Abnormal Anti-Quenching and Controllable Multi-Transi- tions of Bi3+ Luminescence by Temperature in a Yellow-Emitting LuVO4:Bi3+ Phosphor for UV-Converted White LEDs. Chemistry—A European Journal, 20, 11522-11530.
http://dx.doi.org/10.1002/chem.201402081
[7] Hu, Y.S., Zhuang, W.D., Ye, H.Q., Wang, D.H., Zhang, S.S. and Huang, X.W. (2005) A Novel Red Phosphor for White Light Emitting Diodes. Journal of Alloys and Compounds, 390, 226-229.
http://dx.doi.org/10.1016/j.jallcom.2004.07.063
[8] Liu, J., Lian, H.Z. and Shi, C.S. (2007) Improved Optical Photoluminescence by Charge Compensation in the Phosphor System CaMoO4:Eu3+. Journal of Optical Materials, 29, 1591-1594.
http://dx.doi.org/10.1016/j.optmat.2006.06.021
[9] Jin, Y., Zhang, J.H., Hao, Z.D., Zhang, X. and Wang, X.J. (2011) Synthesis and Luminescence Properties of Clew- Like CaMoO4:Sm3+, Eu3+. Journal of Alloys and Compounds, 509, L348-L351.
http://dx.doi.org/10.1016/j.jallcom.2011.07.047
[10] Wang, X.F., Peng, G.H., Li, N., Liang, Z.H., Wang, X. and Wu, J.L. (2014) Hydrothermal Synthesis and Luminescence Properties of 3D Walnut-Like CaMoO4:Eu3+ Red Phosphors. Journal of Alloys and Compounds, 599, 102-107.
http://dx.doi.org/10.1016/j.jallcom.2014.02.091
[11] Xu, Z.H., Li, C.X., Li, G.G., Chai, R.T., Peng, C., Yang, D.M. and Lin, J. (2010) Self-Assembled 3D Urchin-Like NaY(MoO4)2:Eu3+/Tb3+ Microarchitectures: Hydrothermal Synthesis and Tunable Emission Colors. Journal of Physical Chemistry C, 114, 2573-2582.
http://dx.doi.org/10.1021/jp9115029
[12] Tian, Y., Chen, B.J., Hua, R.N., Yu, N.S., Liu, B.Q., Sun, J.S., Cheng, L.H., Zhong, H.Y., Li, X.P., Zhang, J.S., Tian, B.N. and Zhong, H. (2012) Self-Assembled 3D Flower-Shaped NaY(WO4)2:Eu3+ Microarchitectures: Microwave-Assisted Hydrothermal Synthesis, Growth Mechanism and Luminescent Properties. CrystEngComm, 14, 1760-1769.
http://dx.doi.org/10.1039/c1ce06232h
[13] Huang, S.H., Wang, D., Li, C.X., Wang, L.Z., Zhang, X., Wan, Y. and Yang, P.P. (2012) Controllable Synthesis, Morphology Evolution and Luminescence Properties of NaLa(WO4)2 Microcrystals. CrystEngComm, 14, 2235-2244.
http://dx.doi.org/10.1039/c2ce06450b
[14] Di, W.H., Wang, X.J., Zhu, P.F. and Chen, B.J. (2007) Energy Transfer and Heat-Treatment Effect of Photoluminescence in Eu3+-Doped TbPO4 Nanowires. Journal of Solid State Chemistry, 180, 467-473.
http://dx.doi.org/10.1016/j.jssc.2006.11.006
[15] Tian, Y., Qi, X.H., Wu, X.W., Hua, R.N. and Chen, B.J. (2009) Luminescent Properties of Y2(MoO4)3: Eu3+ Red Phos- phors with Flowerlike Shape Prepared via Coprecipitation Method. Journal of Physical Chemistry C, 113, 10767- 10772.
http://dx.doi.org/10.1021/jp901053q

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