基于钛金属的柔性有机钙钛矿太阳能电池的制备及特性研究
Fabrication and Properties of Titanium Based Flexible Organic Perovskite Solar Cells
DOI: 10.12677/MS.2016.66048, PDF, HTML, XML, 下载: 2,063  浏览: 4,230  国家自然科学基金支持
作者: 郭 洪, 王 琳, 王 旭, 杨平雄, 敬承斌, 褚君浩:华东师范大学,信息科学技术学院,电子工程系,极化材料与器件教育部重点实验室,上海
关键词: 钛箔有机钙钛矿电池金属电池空芯光纤结构电池Titanium Foil Organic Perovskite Cell Metal Battery Hollow Fiber Structured Battery
摘要: 钛箔具有柔韧性和导电性,致密二氧化钛层可通过钛箔热氧化生成,而二氧化钛层在有机钙钛矿太阳能电池中可以作为电子传输层。本文通过使用钛箔作为支撑材料,设计并制备了柔性有机钙钛矿太阳能电池。其中通过在空气中热氧化钛箔制备致密二氧化钛电子传输层,然后利用溶液旋涂法依次在致密二氧化钛层上制备有机钙钛矿活性层、空穴传输层、透明电极层。研究表明,钛金属有机钙钛矿太阳能电池光生电压可达0.55 V,光生电流4.5 mA/cm2,该研究为制备基于柔性钛箔有机钙钛矿太阳能电池的空芯光纤太阳能电池奠定了基础。
Abstract: Titanium foil is flexible and electroconductive, and a compact titanium dioxide layer can be gen-erated by thermal oxidation of it. The titanium dioxide layer can be served as the electron transport layer of an organic perovskite solar cell. A flexible perovskite solar cell was designed and fabricated by using the titanium foil as the substrate in this work. A titanium dioxide electron transport layer was formed by sintering the foil in air, then a perovskite organic active layer, a hole transport layer and a transparent electrode layer were deposited in sequence on the titanium dioxide layer via spin coating method. The as-prepared solar cell exhibits a photovoltage and photocurrent of 0.55 V and 4.5 mA/cm2, respectively. A hollow fiber structured organic perovskite solar cell is possibly established based on the flexible titanium foil solar cell.
文章引用:郭洪, 王琳, 王旭, 杨平雄, 敬承斌, 褚君浩. 基于钛金属的柔性有机钙钛矿太阳能电池的制备及特性研究[J]. 材料科学, 2016, 6(6): 378-385. http://dx.doi.org/10.12677/MS.2016.66048

参考文献

[1] Yang, W.S., Noh, J.H., Jeon, N.J., Kim, Y.C., Ryu, S., Seo, J. and Seok, S.I. (2015) High-Performance Photovoltaic Perovskite Lay-ers Fabricated through Intramolecular Exchange. Science, 348, 1234-1237. https://doi.org/10.1126/science.aaa9272
[2] You, J.B., Hong, Z.R., Yang, Y. (Michael), et al. (2014) Low-Temperature Solu-tion-Processed Pervoskite Solar Cells with High Efficiency and Flexibility. ACS Nano, 8, 1674-1680. https://doi.org/10.1021/nn406020d
[3] Zhou, H.P., Chen, Q., Li, G., et al. (2014) Interface Engineering of Highly Efficient Perov-skite Solar Cells. Science, 345, 542-548.
[4] Jeon, N.J., Noh, J.H., Yang, W.S., et al. (2015) Compositional Engineering of Per-voskite Materials for High- Performance Solar Cells. Research Letter, 517, 476-481.
[5] 吴进明, 甘澍霆, 甘宪. 金属钛表面制备二氧化钛薄膜的方法[P]. 国家发明专利. 申请号: 200310106400.2.
[6] 符慧德. 热管式光伏光热综合利用系统的理论和实验研究[D]: [博士学位论文]. 合肥: 中国科学技术大学, 2012: 12-36.
[7] Jing, C.-B., Guo, H., Hu, Z.-G., et al. (2014) Metallic Attenuated Total Reflection Infrared Hollow Fibers for Robust Optical Transmissionsystems. Applied Physics Letters, 105, 011102. https://doi.org/10.1063/1.4887002
[8] 杨建军, 郭泉辉, 毛立群, 李庆霖, 张治军, 汪汉卿. 商品二氧化钛的光催化性能比较[J]. 化学研究, 2001(2): 12-14.
[9] 张保丰, 刘德波, 周亚军, 蒋爱云. TiO2薄膜制备技术研究进展[J]. 热加工工艺, 2012(22): 153-156.
[10] 黄伯云, 李成功, 石力开, 等. 有色金属材料手册[M]. 北京: 化学工业出版社, 2009: 300-625.
[11] 郭洪, 梁赪, 花修春, 马海生, 郭文锋, 敬承斌, 褚君浩. 全反射氧化锗空芯光纤弹性弯曲半径的计算与验证[J].光电子•激光, 2015, 26(2): 392-396.