有机胺聚氨酯发泡催化剂
Organic Amine Catalysts for Polyurethane Foam
DOI: 10.12677/HJCET.2017.71008, PDF, HTML, XML, 下载: 2,455  浏览: 5,615  科研立项经费支持
作者: 魏梦怡, 钱 超, 陈新志：浙江大学化学工程与生物工程学院，浙江 杭州；叶小明, 张 琪：浙江大学化学工程与生物工程学院，浙江 杭州；四川之江高新材料股份有限公司，四川 遂宁；史雅静：浙江大学化学工程与生物工程学院；张 超, 张 华：四川之江高新材料股份有限公司，四川 遂宁
关键词: 聚氨酯；发泡；催化剂；分类；Polyurethane； Foam； Catalyst； Classification
摘要: 发泡催化剂是聚氨酯泡沫材料生产过程中的关键技术之一。针对发泡催化剂的分子结构设计及其生产工艺，国内外的研究不断深入。本文根据聚氨酯泡沫材料的发泡原理及其对催化剂性能要求，系统地总结了有机胺类发泡催化剂在聚氨酯工业中的应用，并着重推荐了在发泡、环保性能等方面具有潜力的新型聚氨酯发泡催化剂品种。
Abstract: Foaming catalyst is one of the key technologies in the production of polyurethane foam. In view of the molecular structure design and production process of the foam catalyst, the research at home and abroad has been deeply studied. According to polyurethane foam foaming principle and the catalyst performance requirements, this article systematically summarizes the organic amine foaming catalyst in the polyurethane industry in the application, and emphatically recommends in foaming, environmental performance and potential new-type polyurethane foam catalyst varieties.
文章引用：魏梦怡, 叶小明, 张琪, 史雅静, 张超, 张华, 钱超, 陈新志. 有机胺聚氨酯发泡催化剂[J]. 化学工程与技术, 2017, 7(1): 48-54. http://dx.doi.org/10.12677/HJCET.2017.71008

参考文献

[1] 潘方鸣, 郭琦, 胡达. 水性聚氨酯在湿法合成革中的应用初探[C]//中国化工学会, 中国聚氨酯工业协会. 2010水性聚氨酯行业年会论文集: 2010年卷. 温州: 中国化工学会, 2010: 120-122.
[2] Kurańska, M., Prociak, A., Kirpluks, M., et al. (2015) Polyurethane-Polyisocyanurate Foams Modified with Hydroxyl Derivatives of Rapeseed Oil. Industrial Crops and Products, 74, 49-57. https://doi.org/10.1016/j.indcrop.2015.06.006
[3] Gwon, J.G., Kim, S.K. and Kim, J.H. (2016) Sound Absorption Behavior of Flexible Polyurethane Foams with Distinct Cellular Structures. Materials & Design, 89, 48-54. https://doi.org/10.1016/j.matdes.2015.10.017
[4] Fu, Y.Q., Huang, W.M., Luo, J.K., et al. (2015) 9-Polyurethane Shape-Memory Polymers for Biomedical Applications: Shape Memory Polymers for Biomedical Applications. Woodhead Publishing, 167-195. https://doi.org/10.1016/b978-0-85709-698-2.00009-x
[5] Liu, C., Xiang, B., Liu, Y., et al. (2016) Synthesis of Aqueous and Hydroxy-Terminated Polyurethanes: Impacts of Formulation Parameters by Orthogonal Matrix Design. Progress in Organic Coatings, 90, 1-9. https://doi.org/10.1016/j.porgcoat.2015.09.017
[6] Gama, N.V., Soares, B., Freire, C.S.R., et al. (2015) Bio-Based Polyurethane Foams toward Applications beyond Thermal Insulation. Materials & Design, 76, 77-85. https://doi.org/10.1016/j.matdes.2015.03.032
[7] Ji, D., Fang, Z., He, W., et al. (2015) Polyurethane Rigid Foams Formed from Different Soy-Based Polyols by the Ring Opening of Epoxidised Soybean Oil with Methanol, Phenol, and Cyclohexanol. Industrial Crops and Products, 74, 76-82. https://doi.org/10.1016/j.indcrop.2015.04.041
[8] 黄茂松. 浅谈我国聚氨酯弹性体发展动态[J]. 聚氨酯工业, 2004, 19(6): 14-16, 20.
[9] 全球聚氨酯发展现状与展望[J]. 工程塑料应用, 2005, 33(2): 29.
[10] 郁维铭. 关于我国聚氨酯泡沫塑料发展的报告[C]//中国聚氨酯工业协会, 中国合成树脂基塑料工业信息总站. 第一届中国聚氨酯行业发展国际论坛暨2005PU泡沫行业加速淘汰ODS专题峰会论文集. 上海, 2005: 63-68.
[11] 翁汉元. 聚氨酯工业的最近发展[J]. 化学推进剂与高分子材料, 2003, 19(1): 8-13.
[12] 朱长春, 吕国会. 中国聚氨酯产业现状及“十三五”发展规划建议[J]. 聚氨酯工业, 2015, 3: 1-25.
[13] 李焱. 聚氨酯材料的研究进展[J]. 北京工商大学学报(自然科学版), 2004, 22(5): 13-16.
[14] 陈凤福. 聚氨酯泡沫塑料用催化剂的作用及机理[J]. 聚氨酯工业, 1986, 31(4): 22-26.
[15] 拾方治, 赫振华, 吕伟民. 沥青发泡原理及发泡特性的试验研究[J]. 建筑材料学报, 2004, 7(2): 183-187.
[16] 丁祥勇. 聚氨酯发泡在客车上的应用[J]. 客车技术与研究, 2003, 25(1): 31-33.
[17] 环保聚氨酯弹性体催化剂[J]. 橡胶参考资料, 2014, 44(6): 56-56.
[18] 刘益军.聚氨酯的助剂[M]. 北京: 化学工业出版社, 2008: 90-94.
[19] Webers, V.J. (1948) The Leuckart Reaction—A Study of the Mechanism. Journal of American Chemical Society, 70, 1422-1424. https://doi.org/10.1021/ja01184a038
[20] Kadyrov, R. and Riermeier, T.H. (2003) Highly Enantioselective Hydrogen-Transfer Reductive Amination: Catalytic Asymmetric Synthesis of Primary Amines. Angewandte Che-mie—International Edition, 42, 5472-5474. https://doi.org/10.1002/anie.200352503
[21] Alexander, E.R. and Wildman, R.B. (1948) Studies on the Mechanism of the Leuckart Reaction. Journal of. American Chemical Society, 70, 1187-1189. https://doi.org/10.1021/ja01183a091
[22] Lavandera, I., Koszelewski, D. and Kroutil, W. (2010) Enzymatic Biosynthesis of Amines. AT507050.
[23] Kayaki, Y., Ikeda, H., Tsurumaki, J.I., Shimizu, I. and Yamamoto, A. (2008) Catalytic Behavior of Cationic Hydridoruthenium(II) Complex, [RuH(NH3)(PMe3)(4)](+), in H-2-Hydrogenation and Transfer Hydrogenation of Imines. Bulletin of the Chemical Society of Japan, 81, 1053-1061. https://doi.org/10.1246/bcsj.81.1053
[24] 周少东. 若干氢转移反应的基础及应用研究[D]: [博士学位论文]. 杭州: 浙江大学, 2013.
[25] Connolly, T.J., Constantinescu, A., Lane, T.S., Matchett, M., Mcgarry, P. and Paperna, M. (2005) Assessment of a Reductive Amination Route to Methyl(3-nitrobenzyl)amine Hydrochloride. Organic Process Research & Development, 9, 837-842. https://doi.org/10.1021/op050120x
[26] Bomann, M.D., Guch, I.C. and Dimare, M. (1995) A Mild, Pyridine-Borane-Based Reductive Amination Protocol. Journal of Organic Chemistry, 60, 5995-5996. https://doi.org/10.1021/jo00123a049
[27] Mathre, D.J. and Shinkai, I. (2001) 2-Amino-3-Methyl-1,1-Diphenyl-1-Butanol. E-EROS Encyclopedia of Reagents for Organic Synthesis.
[28] Jung, Y.J., Bae, J.W., Park, E.S., Chang, Y.M. and Yoon, C.M. (2003) An Efficient Conversion of Nitroaromatics and Aromatic Amines to Tertiary Amines in One-Pot Way. Tetrahedron, 59, 10331-10338. https://doi.org/10.1016/j.tet.2003.09.054
[29] Klemmens, P., Schroll, G. and Lawesson, S.O. (1968) Reaction between Acyloins and Secondary Amines. Arkiv for Kemi, 28, 405.
[30] 张琪, 叶小明, 张超, 张华, 叶开天, 张依. 系列聚氨酯催化剂的制备方法[P]. 中国专利, CN10534120A. 2016-02-24.
[31] 张超, 张华, 苏佳辉, 张琪. 合成N-甲基吗啉的方法及所用的负载型催化剂[P]. 中国专利, CN104941647A. 2015-09-30.