两个基于1-三氮唑-4-四氮唑苯的配位聚合物的合成、结构及荧光性
Synthesis, Structure and Fluorescence of Two Coordination Polymers Based on 1-Triazole-4-Tetrazole Benzene
摘要: 近年来,多孔配位聚合物在气体储存、分离以及复合光、电、磁等多功能领域具有诱人的前景而备受关注。本文主要采用1-三氮唑-4-四氮唑苯有机配体分别与铜(I)、银(I)离子自组装得到2个新颖的配位聚合物,并对其组装规律和构效关系进行探索。
Abstract: Recently, porous coordination polymers (PCPs) have attracted great interest on account of their potential application in gas storage and separation, and as optoelectronic and magnetic materials. In this work, by utilizing the 1-Triazole-4-Tetrazole Benzene ligands with copper (I) salt and silver (I), we have successfully constructed two novel PCPs. Efforts have been focused on the exploration of self-assembly and the relationship between structures and properties.
文章引用:房小钰, 吴宁, 陈欣雨, 严政. 两个基于1-三氮唑-4-四氮唑苯的配位聚合物的合成、结构及荧光性[J]. 物理化学进展, 2017, 6(1): 17-25. https://doi.org/10.12677/JAPC.2017.61003

参考文献

[1] Cui, Y., Yue, Y., Qian, G. and Chen, B. (2012) Luminescent Functional Metal-Organic Frameworks. Chemical Reviews, 112, 1126-1162. https://doi.org/10.1021/cr200101d
[2] Kreno, L., Leong, K., Farha, O., Allendorf, M., Van Duyne, R. and Hupp, J. (2012) Metal-Organic Framework Materials as Chemical Sensors. Chemical Reviews, 112, 1105-1125. https://doi.org/10.1021/cr200324t
[3] Lan, A., Li, K., Wu, H., Olson, D., Emge, T., Ki, W., Hong, M. and Li, J. (2009) A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives. Angewandte Chemie International Edition, 48, 2334-2338. https://doi.org/10.1002/anie.200804853
[4] Wen, T., Zhang, D.-X., Liu, J., Lin, R. and Zhang, J. (2013) A Multifunctional Helical Cu(I) Coordination Polymer with Mechanochromic, Sensing and Photocatalytic Properties. Chemical Communications, 49, 5660-5662. https://doi.org/10.1039/c3cc42241k
[5] Perruchas, S., Goff, X. F. L., Maron, S., Maurin, I., Guillen, F., Garcia, A., Gacoin, T. and Boilot, J.-P. (2010) Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster. Journal of the American Chemical Society, 132, 10967-10969. https://doi.org/10.1021/ja103431d
[6] Tsukuda, T., Kawase, M., Dairiki, A., Matsumoto, K. and Tsubomura, T. (2010) Brilliant Reversible Luminescent Mechanochromism of Silver(I) Complexes Containing o-bis(diphenylphosphino)benzene and Phosphinesulfide. Chemical Communications, 46, 1905-1907. https://doi.org/10.1039/b921111j
[7] Strasser, C.E. and Catalano, V.J. (2010) “On-Off” Au(I)•••Cu(I) Interactions in a Au(NHC)2 Luminescent Vapochromic Sensor. Journal of the American Chemical Society, 132, 10009-10011. https://doi.org/10.1021/ja104585q
[8] Wen, T., Zhang,D.-X., Zhang, H.-X., Zhang, H.-B. and Zhang, J., Li, D.-S. (2014) Re-dox-Active Cu(I) Boron Imidazolate Framework for Mechanochromic and Catalytic Applications. Chemical Communications, 50, 8754-8756. https://doi.org/10.1039/C4CC02057J
[9] Wen, T., Zhang, D.-X., Ding, Q.-R., Zhang, H.-B. and Zhang, J. (2014) Two Luminescent Cu(I) Coordination Polymers Based on the 1-(4-tetrazolephenyl)imidazole ligand for Sensing of Nitrobenzene. Inorganic Chemistry Frontiers, 1, 389-392. https://doi.org/10.1039/c4qi00016a
[10] Ling, Y., Chen, Z.-X., Zhou,Y.-M., Weng, L.-H. and Zhao, D.-Y. (2011) A Novel Green Phosphorescent Silver(I) Coordination Polymer with Three-Fold Interpenetrated CdSO4-Type Net Generated via in Situ Reaction. CrystEngComm, 13, 1504-1508. https://doi.org/10.1039/C0CE00546K