三维交错多孔氧化铜纳米片的制备及其对葡萄糖的无酶检测
Preparation of Three-Dimensional Porous Copper Oxide Nanoflakes and Its Non-Enzymatic Detection of Glucose
DOI: 10.12677/MS.2017.73042, PDF, HTML, XML, 下载: 1,557  浏览: 2,660  国家自然科学基金支持
作者: 邵长旭, 陈守刚:中国海洋大学材料科学与工程研究院,山东 青岛
关键词: 多孔氧化铜纳米片无酶传感葡萄糖Porous Copper Oxide Nanoflakes Non-Enzymatic Sensor Glucose
摘要: 本文采用液固反应与高温退火相结合的方法,在不使用有机试剂及稳定剂的条件下在铜基体上成功的合成了三维交错多孔氧化铜纳米片。氧化铜的三维多孔结构,使其具有大的比表面积并且纳米片上的介孔和微孔有利于电子的传递。利用壳聚糖良好的生物兼容性,导电性和成膜性制备壳聚糖氧化铜有机–无机复合材料电极用于葡萄糖的无酶电化学检测。此电极具有制备简单、响应快速检测线低的优点,并且在常见干扰物尿酸,抗坏血酸,多巴胺等共存条件下对葡萄糖检测具有良好的选择性。
Abstract: In this paper, three-dimensional porous copper oxide nanoflakes were successfully synthesized on the copper substrate without the use of organic reagents and stabilizers by the combination of liq-uid-solid reaction and high-temperature annealing. The three-dimensional porous structure of copper oxide has a large specific surface area, and the mesopores and micropores on the nanosheets are conducive to the transmission of electron. Using good biocompatibility, conductivity and film of chitosan are used to prepare chitosan copper oxide organic-inorganic composite electrode for nonenzymatic glucose electrochemical sensor. This electrode has the advantages of simple preparation, fast response and low detection line and the sensor is almost insensitive to common interference, such as dopamine, uric acid and ascorbic acid.
文章引用:邵长旭, 陈守刚. 三维交错多孔氧化铜纳米片的制备及其对葡萄糖的无酶检测[J]. 材料科学, 2017, 7(3): 309-317. https://doi.org/10.12677/MS.2017.73042

参考文献

[1] Wild, S., Roglic, G., Green, A., Sicree, R. and King, H. (2004) Global Prevalence of Diabetes: Estimates for the Year 2000 and Projections for 2030. Diabetes Care, 27, 1047-1053.
https://doi.org/10.2337/diacare.27.5.1047
[2] Kurniawan, F., Tsakova, V. and Mirsky, V.M. (2006) Gold Nano-particles in Nonenzymatic Electrochemical Detection of Sugars. Electroanalysis, 18, 1937-1942.
https://doi.org/10.1002/elan.200603607
[3] Wang, J. (2008) Electrochemical Glucose Biosensors. Chemistry Review, 108, 814.
[4] Wang, Z., Liu, S., Wu, P. and Cai, C. (2009) Detection of Glucose Based on Direct Electron Transfer Reaction of Glucose Oxidase Immobilized on Highly Ordered Polyaniline Nanotubes. Analytical Chemistry, 81, 1638-1645.
https://doi.org/10.1021/ac802421h
[5] Wang, J. and Pamidi, P.V.A. (1997) Sol−Gel-Derived Gold Composite Electrodes. Analytical Chemistry, 69, 4490- 4494.
https://doi.org/10.1021/ac970680x
[6] Salimi, A. and Roushani, M. (2005) Non-Enzymatic Glucose Detection Free of Ascorbic Acid Interference Using Nickel Powder and Nafion Sol–Gel Dispersed Renewable Carbon Ceramic Electrode. Electrochemistry Communications, 7, 879-887.
https://doi.org/10.1016/j.elecom.2005.05.009
[7] Meng, L., Jin, J., Yang, G., Lu, T., Zhang, H. and Cai, C. (2009) Nonenzymatic Electrochemical Detection of Glucose Based on Palladium−Single-Walled Carbon Nanotube Hybrid Nanostructures. Analytical Chemistry, 81, 7271-7280.
https://doi.org/10.1021/ac901005p
[8] Song, Y.-Y., Zhang, D., Gao, W. and Xia, X.-H. (2005) Nonenzymatic Glucose Detection by Using a Three-Dimen- sionally Ordered, Macroporous Platinum Template. Chemistry—A Euro-pean Journal, 11, 2177-2182.
https://doi.org/10.1002/chem.200400981
[9] Zhang, X., Chan, K.-Y., You, J.-K., Lin, Z.-G. and Tseung, A.C.C. (1997) Partial Oxidation of Glucose by a Pt|WO3 Electrode. Journal of Electroanalytical Chemistry, 430, 147-153.
https://doi.org/10.1016/S0022-0728(97)00138-1
[10] Yuan, J.H., Wang, K. and Xia, X.H. (2005) Highly Ordered Platinum-Nanotubule Arrays for Amperometric Glucose Sensing. Advanced Functional Materials, 15, 803-809.
https://doi.org/10.1002/adfm.200400321
[11] Yu, X.-Y., Xu, R.-X., Gao, C., Luo, T., Jia, Y., Liu, J.-H., et al. (2012) Novel 3D Hierarchical Cotton-Candy-Like CuO: Surfactant-Free Solvothermal Synthesis and Application in As(III) Removal. ACS Applied Materials & Interfaces, 4, 1954-1962.
https://doi.org/10.1021/am201663d
[12] Huang, J., Zhu, Y., Yang, X., Chen, W., Zhou, Y. and Li, C. (2015) Flexible 3D Porous CuO Nanowire Arrays for Enzymeless Glucose Sensing: In Situ Engineered versus Ex Situ Piled. Nanoscale, 7, 559-569.
https://doi.org/10.1039/C4NR05620E
[13] Xiao, X., Wang, M., Li, H., Pan, Y. and Si, P. (2014) Non-Enzymatic Glucose Sensors Based on Controllable Nanoporous Gold/Copper Oxide Nanohybrids. Talanta, 125, 366-371.
https://doi.org/10.1016/j.talanta.2014.03.030
[14] Niu, X., Lan, M., Zhao, H. and Chen, C. (2013) Highly Sensitive and Selective Nonenzymatic Detection of Glucose Using Three-Dimensional Porous Nickel Nanostructures. Analytical Chemistry, 85, 3561-3569.
https://doi.org/10.1021/ac3030976
[15] Zhang, Y., Liu, Y., Su, L., Zhang, Z., Huo, D., Hou, C., et al. (2014) CuO Nanowires Based Sensitive and Selective Non-Enzymatic Glucose Detection. Sensors and Actuators B: Chemical, 191, 86-93.
https://doi.org/10.1016/j.snb.2013.08.096
[16] Sun, S., Zhang, X., Sun, Y., Yang, S., Song, X. and Yang, Z. (2013) Hierarchical CuO Nanoflowers: Water-Required Synthesis and Their Application in a Nonenzymatic Glucose Biosensor. Physical Chemistry Chemical Physics, 15, 10904-10913.
https://doi.org/10.1039/c3cp50922b