基于5-硝基间苯二甲酸铜构建的MOF孔材料的溶剂热合成
Hydrothermal Synthesis of Porous MOF Based on the 5-Nitroisophthalic Acid and Cu
DOI: 10.12677/AMC.2017.53012, PDF, HTML, XML, 下载: 2,068  浏览: 4,422  国家科技经费支持
作者: 付丽影, 冯振东, 冯 晨, 张 宁, 郝向荣：通化师范学院化学学院，吉林 通化
关键词: 5-硝基间苯二甲酸铜；铜配合物；过渡金属–有机框架；5-Nitroisophthalic Acid； Praseodymium Complexes； Transition Metal-Organic Frameworks
摘要: 过渡金属–有机骨架(MOFs)由于孔道和特定的荧光性能而得到广泛应用。本论文利用吡啶羧酸类配体5-硝基间苯二甲酸和金属Cu，利用溶剂热反应，构筑了一个新的稳定的三维MOF孔道材料。结构分析表明该配合物属三斜晶系，空间群为P-1，a = 11.674(5) Å, b = 11.752(5) Å, c = 17.213(7) Å, α = 102.093(5)˚, β = 102.282(5)˚, γ = 104.251(5) (10)˚, V = 2149.1(16) Å3。利用红外分析探讨了配体与框架的相互作用。红外分析表明羧基完全配位，框架具有稳定性，有可能会成为一个良好的稳定MOF。
Abstract: Transition metal-organic frameworks (MOFs) have been widely used because of their specific channels and fluorescent properties. In this paper, pyridine carboxylic acid ligands 5-nitroisophthalic acid and transition element Cu thermal reaction with a solvent have been used to build a new stable three-dimensional porous MOF. Structural analysis shows that the compound belongs to the triclinic system, space group P-1 a = 7.5098(7) Å, b = 8.0763(7) Å, c = 10.1827(9) Å, α = 71.6730(10)˚, β = 84.2690(10)˚, γ = 84.2690(10)˚, V = 554.07(9) Å3. The MOF framework interac-tion and stability has been explored by using IR analysis.
文章引用：付丽影, 冯振东, 冯晨, 张宁, 郝向荣. 基于5-硝基间苯二甲酸铜构建的MOF孔材料的溶剂热合成[J]. 材料化学前沿, 2017, 5(3): 91-97. https://doi.org/10.12677/AMC.2017.53012

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