高硼硅玻璃材料结构及性能研究进展
Research Progress on the Structure and Properties of High Borosilicate Glass
DOI: 10.12677/OJNS.2020.86070, PDF, HTML, XML,  被引量 下载: 838  浏览: 1,995  科研立项经费支持
作者: 陈 慧, 盛嘉伟*：浙江工业大学材料科学与工程学院，浙江 杭州；浙江工业大学温州科学技术研究院，浙江 温州；孙 青, 张 俭：浙江工业大学材料科学与工程学院，浙江 杭州；严 俊：浙江工业大学温州科学技术研究院，浙江 温州
关键词: 高硼硅玻璃；玻璃结构；性能分析；发展趋势；High Borosilicate Glass； Glass Structure； Performance Analysis； Development Trend
摘要: 高硼硅玻璃具有优良的化学稳定性、热稳定性和良好的机械性能，已经广泛地应用在仪器玻璃，防火玻璃、平板显示及太阳能电池等领域中。随着浮法技术的发展以及玻璃加工技术的进步，高硼硅玻璃将在更多的领域得到应用。本文综述了高硼硅玻璃的研究现状，分析了其组成、结构及热膨胀、化学稳定性等性能之间的关系，评价了其工艺难度、应用情况等方面，并对今后高硼硅玻璃的发展方向和突破点进行了展望。
Abstract: High borosilicate glass has excellent chemical stability, thermal stability and good mechanical properties, and has been widely used in instrument glass, fireproof glass, flat panel display and solar cells and other fields. With the development of float technology and the progress of glass processing technology, high borosilicate glass will be applied in more fields. This paper reviews the research status of high borosilicate glass, analyzes the relationship between its composition, structure, thermal expansion, chemical stability and other properties, evaluates its process difficulty, application and other aspects, and forecasts the development direction and breakthrough points of high borosilicate glass in the future.
文章引用：陈慧, 孙青, 张俭, 严俊, 盛嘉伟. 高硼硅玻璃材料结构及性能研究进展[J]. 自然科学, 2020, 8(6): 603-610. https://doi.org/10.12677/OJNS.2020.86070

参考文献

[1] Windisch, C.F., Pierce, E.M., Burton, S.D., et al. (2011) Deep-UV Raman Spectroscopic Analysis of Structure and Dissolution Rates of Silica-Rich Sodium Borosilicate Glasses. Journal of Non-Crystalline Solids, 357, 2170-2177.
https://doi.org/10.1016/j.jnoncrysol.2011.02.046
[2] 田英良, 张磊, 戴琳, 等. TFT-LCD基板玻璃化学组成的发展状况与展望[J]. 硅酸盐通报, 2010, 29(6): 1348-1352.
[3] Jouglard, D., Neyret, M., Del Campo, L., et al. (2018) Electrical Property Investigations and Microstructure Characterization of a Nuclear Borosilicate Glass Ceramic. Journal of Nuclear Materials, 510, 27-37.
https://doi.org/10.1016/j.jnucmat.2018.07.053
[4] Kang, S., Wang, X., Xu, W., et al. (2017) Effect of B2O3 Content on Structure and Spectroscopic Properties of Neodymium-Doped Calcium Aluminate Glasses. Optical Materials, 66, 287-292.
https://doi.org/10.1016/j.optmat.2017.02.021
[5] Yin, H., Yang, C., Gao, Y., et al. (2018) Fabrication and Characterization of Strontium-Doped Borate-Based Bioactive Glass Scaffolds for Bone Tissue Engineering. Journal of Alloys and Compounds, 743, 564-569.
https://doi.org/10.1016/j.jallcom.2018.01.099
[6] 何峰, 房玉, 刘佳, 等. B2O3对硼硅酸盐玻璃结构和性能的影响[J]. 武汉理工大学学报, 2012, 34(2): 1-4.
[7] Dhara, A., Mishra, R.K., Shukla, R., et al. (2016) A Comparative Study on the Structural Aspects of Sodium Borosilicate Glasses and Barium Borosilicate Glasses: Effect of Al2O3 Ad-dition. Journal of Non-Crystalline Solids, 447, 283-289.
https://doi.org/10.1016/j.jnoncrysol.2016.04.040
[8] Moesgaard, M. and Yue, Y. (2016) Compositional De-pendence of Fragility and Glass Forming Ability of Calcium Aluminosilicate Melts. Journal of Non-Crystalline Solids, 355, 867-873.
https://doi.org/10.1016/j.jnoncrysol.2009.04.004
[9] Dell, W.J., Bray, S.J. and Xiao, S.Z. (1983) 11B NMR Studies and Structure Modeling of Na2O-B2O3-SiO2 Glasses of High Soda Content. Journal of Non-Crystalline Solids, 58, 1-16.
https://doi.org/10.1016/0022-3093(83)90097-2
[10] El-Egili, K. (2003) Infrared Studies of Na2O-B2O3-SiO2 and Al2O3-Na2O-B2O3-SiO2 Glasses. Physics B: Condensed Matter, 325, 340-348.
https://doi.org/10.1016/S0921-4526(02)01547-8
[11] Du, L.S., Jonathan, F. and Stebbins (2003) Solid-State NMR Study of Metastable Immiscibility in Alkali Borosilicate Glasses. Journal of Non-Crystalline Solids, 315, 239-255.
https://doi.org/10.1016/S0022-3093(02)01604-6
[12] Da Silva, R.C., Kubaski, E.T., Tenório-Neto, E.T., et al. (2019) Foam Glass Using Sodium Hydroxide as Foaming Agent: Study on the Reaction Mechanism in Soda-Lime Glass Matrix. Journal of Non-Crystalline Solids, 511, 177-182.
https://doi.org/10.1016/j.jnoncrysol.2019.02.003
[13] 韩娟, 何峰, 梅书霞, 等. Na2O/B2O3对硼硅酸盐玻璃结构与性能的影响[J]. 武汉理工大学学报, 2015, 37(3): 13-17.
[14] 郭宏伟, 赵聪聪, 池龙兴, 等. Al2O3含量对无碱铝硼硅玻璃网络结构的影响[J]. 玻璃, 2019, 46(4): 1-7.
[15] Yin, H., Gao, Y., Gong, Y., et al. (2018) Wavelength Dependence of Tb3+ Doped Magneto-Optical Glass Verdet Constant. Ceramics International, 44, 10929-10933.
https://doi.org/10.1016/j.ceramint.2018.03.156
[16] Lacomb, M., Rice, D. and Stebbins, J.F. (2016) Network Oxygen Sites in Calcium Aluminoborosilicate Glasses: Results from 17O{27Al} and 17O{11B} Double Resonance NMR. Journal of Non-Crystalline Solids, 447, 248-254.
https://doi.org/10.1016/j.jnoncrysol.2016.06.024
[17] Wu, J. and Stebbins, J.F. (2009) Effects of Cation Field Strength on the Structure of Aluminoborosilicate Glasses: High-Resolution 11B, 27Al and 23Na MAS NMR. Journal of Non-Crystalline Solids, 355, 556-562.
https://doi.org/10.1016/j.jnoncrysol.2009.01.025
[18] Ollier, N., Charpentier, T., Boizot, B., et al. (2004) A Raman and MAS NMR Study of Mixed Alkali Na-K and Na-Li Aluminoborosilicate Glasses. Journal of Non-Crystalline Solids, 341, 26-34.
https://doi.org/10.1016/j.jnoncrysol.2004.05.010
[19] 李秀明, 赵高凌, 刘史敏, 等. 低铝高硼硅玻璃基本形成过程及性能研究[J]. 功能材料, 2010, 41(5): 855-857.
[20] Poulain, G., Blanc, D., Focsa, A., et al. (2012) Selective Laser Doping from Boron Silicate Glass. Energy Procedia, 27, 455-459.
https://doi.org/10.1016/j.egypro.2012.07.093
[21] Morin, E.I., Wu, J. and Stebbins, J.F. (2014) Modifier Cation (Ba, Ca, La, Y) Field Strength Effects on Aluminum and Boron Coordination in Aluminoborosilicate Glasses: The Roles of Fictive Temperature and Boron Content. Applied Physics A, 116, 479-490.
https://doi.org/10.1007/s00339-014-8369-4
[22] 何峰, 平财明, 郑媛媛, 等. (Na2O-Al2O3)/B2O3对高硼硅酸盐玻璃粘度和热学性能的影响[J]. 硅酸盐通报, 2013, 32(6): 1022-1025.
[23] Geisler, T., Nagel, T., Kilburn, M.R., et al. (2015) The Mechanism of Borosilicate Glass Corrosion Revisited. Geochimica et Cosmochimica Acta, 158, 112-129.
https://doi.org/10.1016/j.gca.2015.02.039
[24] 李青, 张广涛, 李赫然, 等. Al2O3/SiO2摩尔比对无碱铝硼硅酸盐玻璃黏温特性的影响[J]. 硅酸盐学报, 2017, 45(10): 1516-1522.
[25] 王衍行, 祖成奎, 陈江. 组成对高硼硅玻璃粘度和膨胀系数的影响[J]. 功能材料, 2012, 43(21): 2985-2988.
[26] 刘小青, 何峰, 房玉. 硼硅酸盐玻璃结构与其熔体性质研究[J]. 硅酸盐通报, 2013, 32(5): 804-807+813.
[27] 朱奎, 程金树, 陆平, 等. Al2O3对硼硅酸盐玻璃结构和性能的影响[J]. 硅酸盐通报, 2017, 36(1): 396-400.
[28] 高景德, 王祥珩, 王祥珩, 等. Li2O对硼硅酸盐玻璃结构与性能的影响[J]. 武汉理工大学学报, 2015, 37(5): 15-20.
[29] Song, S., Wen, Z., Liu, Y., et al. (2011) Bi-Doped Borosilicate Glass as Sealant for Sodium Sulfur Battery. Journal of Non-Crystalline Solids, 357, 3074-3079.
https://doi.org/10.1016/j.jnoncrysol.2011.04.014
[30] Song, S., Wen, Z., Zhang, Q., et al. (2010) A Novel Bi-Doped Borosilicate Glass as Sealant for Sodium Sulfur Battery. Part 1: Thermophysical Characteristics and Structure. Journal of Power Sources, 195, 384-388.
https://doi.org/10.1016/j.jpowsour.2009.06.041
[31] 李雄伟, 王觅堂, 李梅, 等. Y2O3对锌硼硅玻璃化学稳定性和结构的影响[J]. 稀土, 2016, 37(6): 39-45.
[32] 刘尧龙, 陆平, 程金树. ZrO2对高硼硅玻璃高温粘度和表面张力的影响[J]. 硅酸盐通报, 2016, 35(9): 2777-2780+2786.
[33] 王倩, 应浩, 韩高荣. 高硼硅玻璃的复合澄清剂研究[J]. 玻璃, 2006(1): 6-10.
[34] 朱奎. 高硼硅防火玻璃的组成、结构和性能的研究[D]: [硕士学位论文]. 武汉: 武汉理工大学, 2017.
[35] 万军鹏. 浮法硼硅酸盐平板玻璃组成、结构与性能的研究[D]: [博士学位论文]. 武汉: 武汉理工大学, 2008.
[36] 许周速, 程成. CdSe量子点掺杂硼硅酸盐玻璃的光学性能[J]. 硅酸盐学报, 2018, 46(11): 1529-1534.
[37] Xu, Z., Liu, X., Jiang, C., et al. (2018) Effect of Topological Structure on Photoluminescence of PbSe Quantum Dot-Doped Borosilicate Glasses. Journal of the American Ceramic Society, 101, 1508-1515.
https://doi.org/10.1111/jace.15331
[38] Cheng, C., Wang, F. and Cheng, X. (2020) PbSe Quantum-Dot-Doped Broadband Fiber Amplifier Based on Sodium-Aluminum-Borosilicate-Silicate Glass. Optics & Laser Technology, 122, Article ID: 105812.
https://doi.org/10.1016/j.optlastec.2019.105812