生物形态多孔分级结构氧化锡纳米材料的制备研究
Preparation of Biomorphic Porous Hierarchical SnO2 Nanomaterials
DOI: 10.12677/nat.2011.11005, PDF, HTML,  被引量 下载: 3,863  浏览: 12,535  国家自然科学基金支持
作者: 位莉, 苏慧兰, 宋钫, 张荻*:上海交通大学金属基复合材料国家重点实验室;文元振:韩国基础科学支援研究院光州分院
关键词: 多孔分级结构氧化锡遗态材料花粉
Porous Hierarchy; Tin Oxide; Biomorphic Nanomaterials; Pollen Grains
摘要: 利用生物模板(油菜花粉)自身的分级结构,以四氯化锡酒精溶液为前躯体,通过搅拌、清洗、干燥、碳化、煅烧等简单有效的处理方法制得了与油菜花粉内部结构相似的三维有序多孔结构氧化锡纳米材料。采用XRD、FESEM、HRTEM测试手段,从结构、组织和成分方面,对天然生物材料和不同煅烧温度下(300℃、400℃、500℃)所制备的氧化锡遗态材料进行了对比研究,并详细阐述了模板复制过程及生物模板在遗态材料合成过程中的作用。
Abstract: In this work, three-dimensional well-organized SnO2 with porous hierarchy has been successfully synthesized by using pollen grains as the biotemplate and SnCl4-ethanol solution as the precursor. A series of simple and effective procedures, such as stirring, rinsing, drying, carbonizing, calcinations, etc, were employed. XRD, FESEM, and HRTEM analysis were carried out to investigate the structures and compositions of original pollen grains and the final products calcinated at different temperatures (300℃,400℃, and 500℃). A detailed explanation is given on the biotemplating synthesis of porous hierarchical SnO2 nanomaterials.
文章引用:位莉, 苏慧兰, 宋钫, 文元振, 张荻. 生物形态多孔分级结构氧化锡纳米材料的制备研究[J]. 纳米技术, 2011, 1(1): 22-26. http://dx.doi.org/10.12677/nat.2011.11005

参考文献

[1] Y. Ping. Magnetic properties of fine cobalt particles prepared by metal atom reduction. Appl. Phys., 1990, 67(9): 4502-4504.
[2] M. Uehara. Staircase behavior in the magnetization reversal of a chemically disordered magnet at low temperature. Phys. Lett., 1986, 114(1): 23-26.
[3] P. Ball. Science at the stomic scale. Nature, 1992, 355(6363): 761.
[4] A. Hagfeidt. Light-induced redox reactions in nanocrystalline systems. Chem. Rev., 1995, 95(1): 49-68.
[5] A. J. Legget. Dynamics of the dissipative two-state system. Rev. Mod. Phys., 1987, 59(1): 1-85.
[6] 郭正. 多孔气敏性氧化物纳米材料的制备与应用研究[D]. 安徽:中国科学技术大学, 2008.
[7] T. Okabe. Research and Development of Woodceramics-Woody Porous Carbon Materials. Tokyo: Publishing Co., Ltd, 1996: 2.
[8] J. G. Huang, T. Kunitake. Nano-Precision Replication of Natural Cellulosic Substances by Metal Oxides. J. Am. Chem. Soc., 2003, 125(39): 11834-11835.
[9] 张荻. 遗态材料的制备及微观组织分析[J]. 中国科学E辑, 2004, 34(7): 721-729.
[10] S. R. Hall. Fabrication of Porous Titania(Brookite) Microparticles with Complex Morphology by Sol-Gel Replication of Pollen Grains. Chem. Mater., 2006, 18(3): 598-600.
[11] H. L. Zhao, D. H. L. Ng, Z. Q. Lu, et al. Carbothermal synthesis of SnxSb anode material for secondary lithium-ion battery. J. Alloys Compd., 2005, 395(1-2): 192-200.
[12] 杨同欢, 周学酬, 李求忠等. 纳米Sn/SnO2/石墨复合材料作为锂离子电池负极材料的研究[J]. 化工时刊, 2008, 22(6): 1-3.
[13] 严辉, 马黎君, 陈光华等. 金属Sn薄膜的高温氧化与表面特征[J]. 物理学报, 1997, 46(8): 1658-1664.
[14] T. X. Fan, S. K. Chow, D. Zhang. Biomorphic mineralization: From biology to materials. Prog. Mater Sci., 2009, 54(5): 83-85.
[15] Y. Y. Lv, L. S. Yu, H. Y. Huang, et al. Preparation, characterization of P-doped TiO2 nanoparticles and their excellent photocatalystic properties under the solar light irradiation. J. Alloys Compd., 2009, 488(1): 314-319.
[16] M. A. Khan, X. Wei, X. Y. Jiang, et al. Influence of p-doping hole transport layer on the performance of organic light-emitting devices. Semicond. Sci. Technol., 2008, 23(5).