纳米CeO2的制备研究进展
Research Progress of Preparation of Nano CeO2
DOI: 10.12677/CMP.2014.33004, PDF, HTML,  被引量 下载: 3,067  浏览: 9,996  科研立项经费支持
作者: 崔 丽, 胡雅琴：安徽大学物理与材料科学学院，合肥；孟凡明：安徽大学安徽省信息材料与器件重点实验室，合肥
关键词: 二氧化铈；固相法；液相法；气相法；水热法；CeO2； Solid Phase Method； Liquid Phase Method； Gas Phase Method； Hydrothermal Method
摘要: 二氧化铈是一种廉价且用途极广的工业材料，具有广阔的市场应用前景。二氧化铈在催化、固体氧化物燃料电池、功能陶瓷、紫外吸收材料中具有广泛的应用。本文通过对氧化铈的结构特点及其电子及能带特点的分析，介绍了四种制备氧化铈的方法分别是固相法，液相法，气相法和水热法。
Abstract: CeO2 is a kind of cheap industrial materials widely used; it has a broad market prospect. CeO2 has been widely used in catalysis, solid oxide fuel cell, functional ceramics, and UV absorption materials. In this paper, by analyzing the structure characteristics, the electron energy and the characteristics of cerium oxide, four kinds of preparation of cerium oxide are introduced which are solid phase method, liquid phase method, gas phase method, and hydrothermal method.
文章引用：崔丽, 胡雅琴, 孟凡明. 纳米CeO2的制备研究进展[J]. 凝聚态物理学进展, 2014, 3(3): 28-32. http://dx.doi.org/10.12677/CMP.2014.33004

参考文献

[1] Tsai, M.S. (2005) Formation of nanocrystalline cerium oxide and crystal growth. Journal of Crystal Growth, 274, 632-637.
[2] Yu, S.H., Coflen, H. and Armin, F. (2004) High quality CeO2 nanocrtstals stabilized by a double hy-drophilic block copolymer. Colloids and Surfaces A, 243, 49-52.
[3] 李霞章, 陈杨, 陈志刚 (2007) 纳米CeO2颗粒的制备及其化学机械抛光性能研究. 摩擦学学报, 27, 1-5.
[4] Hasegawa, Y., Imanaka, N. and Adachi, G. (2003) Gerium ion conducting solid electrolyte. Journal of Solid State Chemistry, 171, 387-390.
[5] Kasper, J., Fornsiero, P. and Graziani, M. (1999) Use of CeO2 based oxidesin the three-way catalysis. Gatal Today, 50, 285-298.
[6] La, R.J., Hu, Z.A., Li, H.L., et al. (2004) Template systhesis of CeO2 ordered nanoware arrays. Materials Science and Engi-neering: A, 368, 145-148.
[7] Yang, X.H., Shao, C.L., Liu, Y.C., et al. (2005) Nanofibers of CeO2 via an electrospin-ning technique. Thin Solid Films, 478, 228-231.
[8] Pan, C.S., Zhang, D.S. and Shi, L.Y. (2008) CTAB assisted hy-drothermal synthesis, controlled conversion and CO oxidation prosperities of nanoplates, nanotubes, and nanorods. Journal of Solid State Chemistry, 181, 1298-1306.
[9] Zhou, K.B., Wang, X., Sun, X.M., et al. (2005) Enhance cata-lytic activity of ceria nanorods from well-defines reactive crystal planes. Journal of Catalysis, 229, 206-212.
[10] Yang, Z.J., Yang, Y.Z., Liang, H., et al. (2009) Hydrothermal synthesis of monodisperse CeO2 nanocubes. Materials Letters, 63, 1774-1777.
[11] Chen, G.Z., Zhu, F.F., Sun, X., Sun, S.S. and Chen, R.P. (2011) Benign synthesis of ceria hollow nanocrystals by a template-free method. CrystEngComm, 13, 2904-2908.
[12] Guo, Z.Y., Jian, F.F. and Du, F.L. (2009) A simple method to controlled synthesis of CeO2 hollow microspheres. Scripta Materialia, 61, 48-51.
[13] Cui, Q.Z., Dong, X.T., Wang, J.X. and Li, M. (2008) Direct fabrication of cerium oxide hollow nanofibers by electrospinning. Journal of Rare Earths, 26, 664-669.
[14] 孔祥晋, 潘湛昌, 肖楚民 (2005) 纳米氧化铈催化作用研究探讨. 化学与生物工程, 2, 1-3.
[15] 李泽彬, 姚有峰, 李富强, 殷春浩 (2010) 二氧化铈的电子结构与导电性研究. 徐州工程学院学报, 1, 12-15.
[16] 李永绣, 陈伟凡, 周雪珍, 程昌明, 辜子英, 胡建东 (2004) 氯化钠在球形纳米氧化铈形成过程中的作用. 中国稀土学报, 5, 636-640.
[17] 王彬, 吴介达, 李雄平, 牛明勤 (2002) 纳米氧化铈粉体的制备与表征. 精细化工, 12, 881-883.
[18] Ying, J.Y., Liu, W., Flytzanistephanopoulos, M. and Tschope, A. (1995) Redox activity of nonstoichiometric cerium oxide-based nanocrystalline cataltsts. Journal of Catalysis, 157, 42-50.
[19] 肖楚民, 潘占昌, 张环华, 李秀珍, 黄慧民 (2003) 碳酸氢铵沉淀法制备二氧化铈超细粉体. 冶金工程, 1, 41-43.
[20] Gnanam, S. and Rajendran, V. (2011) Synthesis of CeO2 or α-Mn2O3 nanoparticles sol-gel process and their optical properties. Journal of Sol-Gel Science and Technology, 58, 62-69.
[21] 贺拥军, 杨伯伦 (2003) 微乳液和沉淀剂耦合法制备CeO2纳米粒子. 化学通报, 2, 120-124.
[22] Lu, X.H., Huang, X., Xie, S.L., Zheng, D.Z., Liu, Z.Q., Liang, C.L. and Tong, Y.X. (2010) Facile electrochemical synthesis of single crystalline CeO2 octahedrons and their optical properties. Langmuir, 26, 7569-7573.
[23] Yu, R.B., Yan, L., Zheng, P., Chen, J. and Xing, X.R. (2008) Controlled synthsis of CeO2 flower-like and well-aligned nanorod hierarchical architectures by a phosphate-assisted hydrothermal route. Journal of Physical Chemistry C, 112, 19896-19900.
[24] Zhou, K.B., Yang, Z.Q. and Yang, S. (2007) Highly reducible CeO2 nanotubes. Chemistry of Materials, 19, 1215- 1217.
[25] Kaneko, K., lnoke, K., Freitag, B., Hungria, A.B., Midgley, P.A., Hansen, T.W., et al. (2007) Structural and morphological characterization of cerium oxide nanocrystals prepared by hdrothermal synthesis. Nano Letters, 7, 421-425.

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