含蒽环的钳状氮杂环卡宾前体及银卡宾的合成
Synthesis of Pincer-Type N-Heterocylic Carbene Predecessors Based on Anthracene Moity and Its Silver Carbene
DOI: 10.12677/SSC.2015.32004, PDF, HTML, XML, 下载: 2,574  浏览: 8,398 
作者: 黄 昆*:西华师范大学化学与化工学院,四川 南充;四川文理学院化学化工学院,四川 达州;秦大斌*:西华师范大学化学与化工学院,四川 南充
关键词: 氮杂环卡宾钳状N-Heterocylic Carbene Anthracene Pincer
摘要: 钳状氮杂环卡宾广泛用于阴离子识别和金属卡宾络合物制备。本文合成了四种含蒽环的钳状氮杂环卡宾前体和一种银氮杂环卡宾络合物,并对其结构进行了表征。
Abstract: Pincer-type N-heterocylic Carbene (NHC) predecessor have been widely applied in anion recognition and preparation of meal NHCs. Herein, four pincer-type NHC predecessors and one of its silver complex containing anthracene ring were synthesized and characterized by NMR spectra.
文章引用:黄昆, 秦大斌. 含蒽环的钳状氮杂环卡宾前体及银卡宾的合成[J]. 合成化学研究, 2015, 3(2): 24-27. http://dx.doi.org/10.12677/SSC.2015.32004

参考文献

[1] Arduengo, A.J. Harlow, R.L. and Kline, M. (1991) A stable crystalline carbene. Journal of the American Chemical Society, 113, 361-363.
http://dx.doi.org /10.1021/ja00001a054
[2] Lin, J.C.Y., Huang, R.T.W., Lee, C.S., et al. (2009) Coinage metal-N-heterocyclic carbene complexes. Chemical Reviews, 109, 3561-3598.
http://dx.doi.org /10.1021/cr8005153
[3] Lin, I.J.B. and Vasam, C.S. (2007) Preparation and application of N-heterocyclic carbene complexes of Ag(I). Coordination Chemistry Reviews, 251, 642-670.
http://dx.doi.org /10.1016/j.ccr.2006.09.004
[4] Garrison, J.C. and Youngs, W.J. (2005) Ag(I) N-heterocyclic carbene complexes: Synthesis, structure, and application. Chemical Reviews, 105, 3978-4008.
http://dx.doi.org /10.1021/cr050004s
[5] Kantche,E.A.B., OBrien, C.J. and Organ, M.J. (2007) Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions—A synthetic chemists perspective. Angewandte Chemie International Edition, 46, 2768-2813.
http://dx.doi.org /10.1002/anie.200601663
[6] Nebioglu, A.K., Panzne, M.J., Tessier, C.A., et al. (2007) N-Heterocyclic carbine-silver complexes: A new class of antibiotics. Coordination Chemistry Reviews, 252, 884-89.
http://dx.doi.org /10.1016/j.ccr.2006.08.019
[7] Qin, D., Zeng, X.S., Li, Q.S., et al. (2007) Silver(I) N-heterocyclic carbene-bridged calix-[4] arene analogues as efficient [60]fullerene receptor. Chemical Communications, 38, 147-149.
http://dx.doi.org /10.1039/B612421F
[8] Liu, Q.X., Yao, Z.Q., Zhao, X.J., et al. (2011) Two N-heterocyclic carbene silver(I) cyclophanes: Synthesis, structural studies, and recognition for p-phenylenediamine. Organometallics, 30, 3732-3739.
http://dx.doi.org /10.1021/om1012117
[9] Kim, S.K., Seo, E., Han, S.J., et al. (2008) A new imidazolium acridine derivative as fluorescent chemosensor for pyrophosphate and dihydrogen phosphate. Tetrahedron, 64, 6402-6405.
http://dx.doi.org /10.1016/j.tet.2008.04.085
[10] Lee, H.N., Singh, N.J., Kim, S.K., et al. (2007) New imidazolium systems bearing two pyrene groups as fluorescent chemosensors for anions and anion induced logicgates. Tetrahedron Letters, 48, 169-172.
http://dx.doi.org /10.1016/j.tetlet.2006.10.161
[11] Ghosh, K., Saha, I. and Patra, A. (2009) Design and synthesis of an ortho-phenylenediamine-based open cleft: A selective fluorescent chemosensor for dihydrogen phosphate. Tetrahedron Letters, 50, 2392-2397.
http://dx.doi.org /10.1016/j.tetlet.2009.02.215
[12] Kim, S.K., Singh, N,J., Kwon, J., et al. ( 2006) Fluorescent imidazolium receptors for the recognition of pyrophosphate. Tetrahedron, 62, 6065-6072.
http://dx.doi.org /10.1016/j.tet.2006.03.107
[13] Shi, Z.W., Li, Y. and Lu, G.Y. (2005) Synthes is of 1,8-D ihydroxy-9,10-dihydroan thracene. Chemical Journal of Chinese Universities, 26, 667-670.
[14] Casnati, A., Pochini, A., Ungaro, R., et al. (1995) Synthesis, complexation, and membrane transport studies of 1,3-alternate calix[4] arene-crown-6 conformers: A new class of cesium selective ionophores. Journal of the American Chemical Society, 117, 2767-2777.
http://dx.doi.org /10.1021/ja00115a012