调节pH值和加缓蚀剂咪唑啉防止碳钢在除盐水中的腐蚀
Study on the Effect of Adjusting pH Value and Adding Imidazoline Inhibitor to Prevent Carbon Steel from Corrosion in Desalting Water
DOI: 10.12677/AEPE.2015.35018, PDF, HTML, XML, 下载: 2,645  浏览: 5,906 
作者: 阳 月, 宁玉佩, 徐艳飞, 王松伟, 张 瑜, 李雨晴, 王 瑞, 谢学军*:武汉大学动力与机械学院,湖北 武汉;符 浩:国电汉川发电有限公司,湖北 汉川 ;田 林:中海油珠海天然气发电有限公司,广东 珠海
关键词: 碳钢腐蚀缓蚀剂pH咪唑啉Carbon Steel Corrosion Inhibitor pH Imidazoline
摘要: 采用失重法,研究在通大气的接近中性的50℃除盐水中,通过调节pH值、加缓蚀剂防止碳钢在除盐水中腐蚀的情况,主要研究调节pH值和加缓蚀剂咪唑啉防止碳钢腐蚀情况的差异。试验结果表明,通过调节pH值和加入咪唑啉均可防止碳钢的腐蚀,但调节pH仅在短期有效,而加入合适浓度的咪唑啉可以保持碳钢较长时间不腐蚀。
Abstract: The effect of adjusting pH and adding inhibitor to prevent carbon steel from corrosion in the de-salting water, which is close to neutral, open to atmosphere at 50˚C, is studied through weight loss method, and the difference of anti-corrosion effect between the two methods is mainly studied. The test results show that the corrosion of carbon steel can be prevented by adjusting pH and adding imidazoline, and its corrosion can be prevented by adding imidazoline with a proper concentration for a long time, only can be prevented by adjusting pH for a short period of time.
文章引用:阳月, 符浩, 宁玉佩, 田林, 徐艳飞, 王松伟, 张瑜, 李雨晴, 王瑞, 谢学军. 调节pH值和加缓蚀剂咪唑啉防止碳钢在除盐水中的腐蚀[J]. 电力与能源进展, 2015, 3(5): 117-122. http://dx.doi.org/10.12677/AEPE.2015.35018

参考文献

[1] 郑逸云, 周柏青, 李芹, 等 (2004) 水处理缓蚀剂应用现状与发展. 腐蚀科学与防护技术, 16, 101-104.
[2] 葛忻 (2002) 大型电站锅炉停炉保养研究. 重庆大学, 14-15.
[3] 谢学军, 龚洵洁, 许崇武, 彭珂如 (2012) 热力设备的腐蚀与防护. 中国电力出版社, 北京.
[4] 刘景, 包伯荣, 解群, 等 (2005) DP-1型缓蚀剂抑制硫离子对304不锈钢的侵蚀作用. 腐蚀与防护, 26, 231-233.
[5] Zhang, J.P., Zhan, Q.Y., Ren, H., Zhao, W. and Zhang, H.P. (2001) Inhibition performance of 2-mercaptobenzothia- zole derivatives in CO2 saturated solution and its adsorption behavior at Fe surface. Applied Surface Science, 253, 7416-7422.
http://dx.doi.org/10.1016/j.apsusc.2007.03.035
[6] Elazhar, M., Mernari, B., Traisnel, M., Bentiss, F. and La-grenee, M. (2001) Corrosion inhibition of mild steel by the new class of inhibitors [2,5-bis(n-pyridyl)-1,3,4-thiadiazoles] in acidic media. Corrosion Science, 43, 2229-2238.
http://dx.doi.org/10.1016/S0010-938X(01)00034-8
[7] 古宁 (2001) 碳钡在中碱性介质中的腐蚀行为. 河北省科学院学报, 18, 99-101.
[8] 杨煦珍, 杨武 (1991) 金属腐蚀电化学热力学. 化学工业出版社, 北京.
[9] 曹楚南 (1985) 腐蚀电化学原理. 化学工业出版社, 北京.
[10] 张静, 杜敏, 于会华, 王宁 (2009) 分子结构对咪唑啉缓蚀剂膜在Q235钢表面生长和衰减规律的影响. 物理化学学报, 25, 525-531.