摘要:
研制新型非铂催化剂已成为可再生能源研究领域的当务之急。由于稳定的化学与电化学性能,氧化锆在新型铂催化剂研究中受到了广泛关注。因此,本文首先回顾了常用氧化锆薄膜的磁控溅射法和浸涂法合成工艺与研究进展,再综述了非化学计量氧化锆、过渡金属/非过渡金属掺杂氧化锆、部分氧化碳氮化锆和热解锆基螯合物等非铂催化剂的氧还原催化研究现状,最后还展望了氧化锆基非铂催化剂发展的趋势与方向。
Development of
non-platinum catalysts for the renewable energy is urgent. Due to the excellent
chemicaland electrochemical, zirconia is attracting abroad attention in the
investigation of novel non-platinum catalysts. Therefore, this paper reviews
the status of the preparation methods such as magnetron sputtering and
dip-coating for zirconia, and summarizes the study progress of the
non-stoichiometry zirconia, transition metal/non-transition metal doped
zirconia, partially oxidized zirconium carbonitrides and pyrolyzed zirconium
base chelates. At last, this paper also looks ahead at the development of
zirconia based non-pltinum catalysts.