基于LDH的核壳结构纳米复合材料的研究进展
Research Progress of the Core-Shell Structure Nanocomposite Based on LDH
DOI: 10.12677/JAPC.2017.61001, PDF, HTML, XML, 下载: 2,631  浏览: 7,345  国家自然科学基金支持
作者: 朱亚彤, 刘 东, 刘 沙, 唐晓妍, 刘建强:山东大学,物理学院,山东 济南
关键词: 层状双金属氢氧化物核壳结构纳米复合材料Layered Double Hydroxide Core-Shell Structure Nanocomposite
摘要: 层状双金属氢氧化物(LDH)是一类具有层状结构的新型功能材料,近年来基于LDH的核壳结构纳米复合材料由于具有组成结构多样化、组分间呈现协同效应、性能容易调控等特点,其制备与应用研究引起了广泛关注。本文首先综述了最近几年基于LDH的核壳结构纳米复合材料的常用制备方法,主要包括共沉淀法、自组装法和原位生长法,并对这些方法的优缺点进行了分析;然后又讨论了基于LDH的核壳结构纳米复合材料的应用现状,着重阐述了该类材料在吸附、催化、超级电容器和生物医学等方面的应用情况;最后也对该领域存在的问题及其发展趋势进行了总结讨论。
Abstract: Layered double hydroxide (LDH) is a novel functional material with layered structure. With all the excellent properties including diverse composition structures, synergistic effect between the components and highly controllable performance, the study of preparation and applications of the LDH-based core-shell structure nanocomposite has been widely considered for their attractive properties in recent years. At first, the common preparation methods of the LDH-based core-shell structure nanocomposite were summarized, mainly including co-precipitation, self-assembly and in situ growth methods. The advantages as well as disadvantages of these methods were also compared and analyzed. Secondly, the application status of the LDH-based core-shell nanocomposite was focused on their applications in adsorption, catalysis, supercapacitor and biomedicine. The problems and trends of this nanocomposite were concluded and discussed finally.
文章引用:朱亚彤, 刘东, 刘沙, 唐晓妍, 刘建强. 基于LDH的核壳结构纳米复合材料的研究进展[J]. 物理化学进展, 2017, 6(1): 1-8. https://doi.org/10.12677/JAPC.2017.61001

参考文献

[1] Gawande, M.B., Goswami, A., Asefa, T., et al. (2015) Core-Shell Nanoparticles: Synthesis and Applications in Catalysis and Electrocatalysis. Chemical Society Reviews, 44, 7540-7590. https://doi.org/10.1039/C5CS00343A
[2] Han, D.Y., Wang, C.Q., Li, D.D., et al. (2015) NiO/ZnO Core-Shell Nanoparticles in Situ Synthesis via Microemulsion Method. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 46, 794-797. https://doi.org/10.1080/15533174.2014.989595
[3] Galvão, T.L.P., Neves, C.S., Caetano, A.P.F., et al. (2016) Control of Crystallite and Particle Size in the Synthesis of Layered Double Hydroxides: Macromolecular Insights and a Complementary Modelling Tool. Journal of Colloid and Interface Science, 468, 86-94. https://doi.org/10.1016/j.jcis.2016.01.038
[4] Liu, J.Q., Song, J.Y., Xiao, H.D., et al. (2014) Synthesis and Thermal Properties of ZnAl Layered Double Hydroxide by Urea Hydrolysis. Powder Technology, 253, 41-45. https://doi.org/10.1016/j.powtec.2013.11.007
[5] Gu, Z., Atherton, J.J. and Xu, Z.P. (2015) Hierarchical Layered Double Hydroxide Nanocomposites: Structure, Synthesis and Applications. Chemical Communications, 51, 3024-3036. https://doi.org/10.1039/C4CC07715F
[6] Zhao, X.L., Liu, S.G., Wang, P.F., et al. (2015) Surfactant-Modified Flowerlike Layered Double Hydroxide-Coated Magnetic Nanoparticles for Preconcentration of Phthalate Esters from Environmental Water Samples. Journal of Chromatography A, 1414, 22-30. https://doi.org/10.1016/j.chroma.2015.07.105
[7] Li, X.C., Shen, J.J., Sun, W., et al. (2015) A Super-High Energy Density Asymmetric Supercapacitor Based on 3D Core-Shell Structured NiCo-Layered Double Hydroxide@ Carbon Nanotube and Activated Polyaniline-Derived Carbon Electrodes with Commercial Level Mass Loading. Journal of Materials Chemistry A, 3, 13244-13253. https://doi.org/10.1039/C5TA01292A
[8] Shao, M.F., Li, Z.H., Zhang, R.K., et al. (2015) Hierarchical Conducting Polymer@ Clay Core-Shell Arrays for Flexible All-Solid-State Supercapacitor Devices. Small, 11, 3530-3538. https://doi.org/10.1002/smll.201403421
[9] Huo, X.L., Dai, C.F., Li, S.P., et al. (2015) Synthesis of Au yolk/LDH Shell Nanoparticles as Anticancer Vehicles. RSC Advances, 5, 8689-8692. https://doi.org/10.1039/C4RA14585B
[10] Yan, L.G., Yang, K., Shan, R.R., et al. (2015) Kinetic, Isotherm and Thermodynamic Investigations of Phosphate Adsorption onto Core-Shell Fe3O4@ LDHs Composites with Easy Magnetic Separation Assistance. Journal of Colloid and Interface Science, 448, 508-516. https://doi.org/10.1016/j.jcis.2015.02.048
[11] Zhou, Q.X., Lei, M., Li, J., Zhao, K. and Liu, Y. (2016) Determination of 1-Naphthol and 2-Naphthol from Environmental Waters by Magnetic Solid Phase Extraction with Fe@MgAl-Layered Double Hydroxides Nanoparticles as the Adsorbents Prior to High Performance Liquid Chromatography. Journal of Chromatography A, 1441, 1-7. https://doi.org/10.1016/j.chroma.2016.02.061
[12] Ji, X.Q., Zhang, W.L., Shan, L., Tian, Y. and Liu, J. (2015) Self-Assembly Preparation of SiO2@Ni-Al Layered Double Hydroxide Composites and Their Enhanced Electrorheological Characteristics. Scientific Reports, 5, 18367. https://doi.org/10.1038/srep18367
[13] Jiang, S.D., Song, L., Zeng, W.R., et al. (2015) Self-Assembly Fabrication of Hollow Mesoporous Silica@Co-Al Layered Double Hydroxide@ Graphene and Application in Toxic Effluents Elimination. ACS Applied Materials & Interfaces, 7, 8506-8514. https://doi.org/10.1021/acsami.5b00176
[14] Ning, F.Y., Shao, M.F., Zhang, C.L., et al. (2014) Co3O4@Layered Double Hydroxide Core/Shell Hierarchical Nanowire Arrays for Enhanced Supercapacitance Performance. Nano Energy, 7, 134-142. https://doi.org/10.1016/j.nanoen.2014.05.002
[15] Chen, C.P., Felton, R., Buffet, J.C. and O’Hare, D. (2015) Core-Shell SiO2@LDHs with Tunable Size, Composition and Morphology. Chemical Communications, 51, 3462-3465. https://doi.org/10.1039/C4CC10008E
[16] Lin, Y., Zeng, Z.K., Zhu, J.R., et al. (2015) Facile Synthesis of ZnAl-Layered Double Hydroxide Microspheres with Core-Shell Structure and Their Enhanced Adsorption Capability. Materials Letters, 156, 169-172. https://doi.org/10.1016/j.matlet.2015.04.032
[17] Kartsonakis, I.A., Karaxi, E.K. and Charitidis, C.A. (2016) Evaluation of Polymer Composites Based on Core/Shell Polystyrene/Mg-Al-NO3 Layered Double Hydroxides for Chloride Entrapment. Plastics, Rubber and Composites, 45, 50-57. https://doi.org/10.1080/14658011.2015.1133116
[18] Yan, Q.J., Zhang, Z., Zhang, Y.L., et al. (2015) Hierarchical Fe3O4 Core-Shell Layered Double Hydroxide Composites as Magnetic Adsorbents for Anionic Dye Removal from Wastewater. European Journal of Inorganic Chemistry, 2015, 4182-4191. https://doi.org/10.1002/ejic.201500650
[19] Xia, S.X., Du, W.C., Zheng, L.P., Chen, P. and Hou, Z. (2014) A Thermally Stable and Easily Recycled Core-Shell Fe2O3@CuMgAl Catalyst for Hydrogenolysis of Glycerol. Catalysis Science & Technology, 4, 912-916. https://doi.org/10.1039/c3cy00990d
[20] Chen, C.P., Byles, C.F.H., Buffet, J.C., et al. (2016) Core-Shell Zeolite@Aqueous Miscible Organic-Layered Double Hydroxides. Chemical Science, 7, 1457-1461. https://doi.org/10.1039/C5SC03208C
[21] Dou, Y.B., Zhang, S.T., Pan, T., et al. (2015) TiO2@Layered Double Hydroxide Core-Shell Nanospheres with Largely Enhanced Photocatalytic Activity toward O2 Generation. Advanced Functional Materials, 25, 2243-2249. https://doi.org/10.1002/adfm.201404496
[22] Guo, Q.X., Zhang, Q.H., Wang, H.Z., Zhao, Z. and Liu, Z. (2016) Core-Shell Structured ZnO@Cu-Zn-Al Layered Double Hydroxides with Enhanced Photocatalytic Efficiency for CO2 Reduction. Catalysis Communications, 77, 118-122. https://doi.org/10.1016/j.catcom.2016.01.019
[23] Shao, M.F., Ning, F.Y., Wei, M., Evans, D.G. and Duan, X. (2014) Hierarchical Nanowire Arrays Based on ZnO Core-Layered Double Hydroxide Shell for Largely Enhanced Photoelectrochemical Water Splitting. Advanced Functional Materials, 24, 580-586. https://doi.org/10.1002/adfm.201301889
[24] Li, Z.H., Shao, M.F., Zhou, L., et al. (2016) A Flexible All-Solid-State Micro-Supercapacitor Based on Hierarchical CuO@Layered Double Hydroxide Core-Shell Nanoarrays. Nano Energy, 20, 294-304. https://doi.org/10.1016/j.nanoen.2015.12.030
[25] Wu, S.X., Hui, K.S. and Hui, K.N. (2015) One-Dimensional Core-Shell Architecture Composed of Silver Nanowire@Hierarchical Nickel-Aluminum Layered Double Hydroxide Nanosheet as Advanced Electrode Materials for Pseudocapacitor. The Journal of Physical Chemistry C, 119, 23358-23365. https://doi.org/10.1021/acs.jpcc.5b07739
[26] Li, X., Yang, Z.C., Qi, W., et al. (2016) Binder-Free Co3O4@NiCoAl-Layered Double Hydroxide Core-Shell Hybrid Architectural Nanowire Arrays with Enhanced Electrochemical Performance. Applied Surface Science, 363, 381-388. https://doi.org/10.1016/j.apsusc.2015.12.039
[27] Yan, M.N., Zhang, Z.G., Cui, S.M., et al. (2014) Improvement of Pharmacokinetic and Antitumor Activity of Layered Double Hydroxide Nanoparticles by Coating with PEGylated Phospholipid Membrane. International Journal of Nanomedicine, 9, 4867-4878.
[28] Wang, J., Zhu, R.R., Gao, B., et al. (2014) The Enhanced Immune Response of Hepatitis B Virus DNA Vaccine Using SiO2@ LDH Nanoparticles as an Adjuvant. Biomaterials, 35, 466-478. https://doi.org/10.1016/j.biomaterials.2013.09.060
[29] Bi, X., Fan, T. and Zhang, H. (2014) Novel Morphology-Controlled Hierarchical Core@Shell Structural Organo-Layered Double Hydroxides Magnetic Nanovehicles for Drug Release. ACS Applied Materials & Interfaces, 6, 20498-20509. https://doi.org/10.1021/am506113s