以十水硫酸钠为主体的相变材料体系防分层剂研究
Study of an Anti-Layered Agent on Phase Change Material of Na2SO4•10H2O
摘要:
十水硫酸钠作为相变材料应用前景广阔,但是存在严重的分层现象,影响其使用效果。本文采用均匀设计软件进行了十水硫酸钠防分层剂研究,选取了五种不同的增稠剂来防止体系分层,考察了各个物质不同加入量对十水硫酸钠分层现象的影响,得到防分层剂的最佳配方。最佳配方(质量分数)为羧甲基纤维素(0.213%),聚丙烯酰胺(0.243%),白炭黑(0.968%),丙烯酸吸水树脂(0.738%),黏土(0.567)。当体系中加入此防分层剂(3%)后,十水硫酸钠相变体系无分层现象且稳定性良好。
Abstract:
As phase change material, Na2SO4•10H2O has wide application, but the serious stratification influ-ences its effects. Uniform design software was used to prepare the anti-layered agent of phase change material on Na2SO4•10H2O to get the best formula. It could be gained from the experiment that the optimum formula was: CMC (0.213%), polyacrylamide (0.243%), silica (0.968%), acrylic water-absorbent resin (0.738%), clay (0.567%). When the anti-layered agent was added, it was stability and there was no stratification.
参考文献
[1]
|
朱冬生, 刘超 (2007) 相变材料CH3COONa•3H2O的研究进展. 中国材料科技与设备, 1, 30-34.
|
[2]
|
Chen, Z.X. and Chen, G.Y. (2010) Experimental study on the thermal storage performance and preparation of glycerin used in the phase change wall. 2010 WASE International Conference on Information Engineering, Beidaihe, 14-15 August 2010, 51-54.
|
[3]
|
满亚辉, 吴文健 (2009) Na2SO4•10H2O相变过程及其相变潜热的计算. 国防科技大学学报, 2, 41-43.
|
[4]
|
Voigt, W. and Zeng, D. (2002) Solid-liquid equilibria in mixtures of molten salt hyrates for the design of heat storage materials. Pure and Applied Chemistry, 74, 1909-1920.
|
[5]
|
黄金, 柯秀芳 (2008) 无机水合盐相变材料Na2SO4•10H2O的研究进展. 材料导报, 3, 63-67.
|
[6]
|
Canbazoglu, S., et al. (2005) Enhancement of solar thermal energy storage performance using sodium thiosulfatc pentahydrate of a conventional solar water heating system. Energy and Buildings, 37, 235.
|
[7]
|
刘欣, 徐涛, 高学农, 等 (2011) 十水硫酸钠的过冷和相分离探究. 化工进展, 30, 755-758.
|
[8]
|
赵天波, 李凤艳 (2003) 用均匀设计方法对皮革处理用手感剂的研制及其应用. 日用化学工业, 2, 77-79.
|
[9]
|
李凤艳, 代党会, 赵天波 (2012) 非离子与阴离子表面活性剂复配制备石蜡微乳液. 石油化工高等学报, 2, 12- 15.
|