镁基类离子液体制备及物化性质的测定
Synthesis and Physicochemical Properties Determination of Magnesium Ionic Liquid
DOI: 10.12677/MS.2017.71003, PDF, HTML, XML, 下载: 1,583  浏览: 3,469  科研立项经费支持
作者: 刘永昌, 刘婷婷, 寇运凯, 牟善良:临沂大学化学化工学院,山东 临沂
关键词: 氯化胆碱离子液体物化性质氯化镁Choline Chloride Ionic Liquid Physical and Chemical Properties Magnesium Chloride
摘要: 以氯化胆碱和六水氯化镁为原料,采用自组装反应直接合成镁基类离子液体。对合成的类离子液体的粘度、电导率、密度和组成的变化关系进行了分析。结果表明合成的温度和组成是影响类离子液体物化性能的关键因素。随着温度和组成的变化,镁基类离子液体的粘度、电导率、密度均发生显著的变化。
Abstract: With choline chloride magnesium chloride hydrate as raw material, magnesium ion liquid was synthesized by self-assembly reaction. The viscosity, conductivity, density and composition of the ionic liquids were analyzed. The results show that the temperature and composition were the key factors affecting the physicochemical properties of the ionic liquids. With the change of temperature and composition, the viscosity, conductivity and density of magnesium ionic liquids were changed significantly.
文章引用:刘永昌, 刘婷婷, 寇运凯, 牟善良. 镁基类离子液体制备及物化性质的测定[J]. 材料科学, 2017, 7(1): 19-24. http://dx.doi.org/10.12677/MS.2017.71003

参考文献

[1] 李颖, 胡双岚, 程建华, 娄文勇. 酸性离子液体催化油酸酯化合成生物柴油[J]. 催化学报, 2014, 35(3): 396-406.
[2] 李永莲, 林凯城. 新型绿色萃取剂离子液体的应用[J]. 北京工业职业技术学院学报, 2015, 14(2): 30-34.
[3] 苏轶坤, 姚营, 辛亮亮, 汤皎宁. 在离子液体中用阳极氧化铝模板电沉积制备稀土镧纳米线[J]. 应用化工, 2006, 35(8): 572-574.
[4] Abbott, A.P., Capper, G., Davies, D.L. and Rasheed, R.K. (2004) Ionic Liquid Analogues Formed from Hydrated Metal Salts. Chemistry: A Euro-pean Journal, 10, 3769-3774. https://doi.org/10.1002/chem.200400127
[5] 张文智, 徐达锋, 吴锡尊. 镁在DMF中电沉积机理的研究[J]. 物理化学学报, 1989, 5(1): 103-106.
[6] Iwagishi, T., Nakatsuka, Y., Yamamoto, H., Koyama, K. and Shirai, H. (2004) Zinc-Magnesium Alloy Electrodeposition from ZnBr2-1-Ethyl-3-Methylim Idazolium Bromide Molten Salts with Glycerin. Electro-chemistry, 72, 618-623.
[7] 云美峰, 王建朝. 二甲基甲酰胺中Mg2+的电化学性质[J]. 青海师范大学学报, 2011, 27(2): 42-45.
[8] Amir, N., Vestfrid, Y., Chusid, O., Gofer, Y. and Aurbach, D. (2007) Progress in Nonaqueous Magnesium Electro-chemistry. Journal of Power Sources, 174, 1234-1240. https://doi.org/10.1016/j.jpowsour.2007.06.206
[9] Katase, T., Onishi, T., Imashuku, S., Murase, K., Hirato, T. and Awakura, Y. (2005) Water Content and Properties of Aliphatic Ammonium Imide-Type Room Temperature Ionic Liquid Containing Metal Ions. Electrochemistry, 73, 686- 691.
[10] 岳都元. ChCl-MgCl2型(类)离子液体的制备、表征及电化学应用[D]: [博士学位论文]. 西宁: 中国科学院青海盐湖研究所, 2013.