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Iwado,T., Hasegawa, K., Sato, T., et al. (2013) Mechanistic and exploratory investigations into the synthesis of 1,3,5- triaroylbenzenes from 1-aryl-2-propyn-1-ones and 1,3,5-triacetylbenzene from 4-methoxy-3-buten-2-one by cyclotrimerization in hot water in the absence of added acid or base. Journal of Organic Chemistry, 78, 1949-1954.
http://dx.doi.org /10.1021/jo301979p

被以下文章引用:

• 标题: 均苯三乙酮的合成研究Study on Synthesis of 1,3,5-Triacetylbenzene

  作者: 张精安, 邹训重, 刘亚杰, 张莉杰, 欧意桃, 程燕芳

  关键字: 均苯三乙酮, 甲酸乙酯, 丙酮, 合成1.3.5-Triacetylbenzene, Ethyl Formate, Acetone, Synthesis

  期刊名称: 《Studies in Synthetic Chemistry》, Vol.3 No.3, 2015-09-10

  摘要: 目的：合成均苯三乙酮。方法：利用甲酸乙酯、丙酮和乙醇钠反应生成不饱和醇钠，然后用弱酸酸化生成均苯三乙酮。结果：成功合成出均苯三乙酮，并通过TLC监测、测定其熔点及质谱和核磁共振氢谱确定其结构。结论：此合成均苯三乙酮的方法操作简单，原料价廉易得，可用于工业上合成较大量的均苯三乙酮。 Objective: 1,3,5-Triacetylbenzene was synthesized. Methods: 1,3,5-Triacetylbenzene was prepared by ethyl formate and acetone reaction with sodium ethoxide and then the producing unsaturated sodium ethoxide solution was acidified with weak acid. Results: 1,3,5-Triacetylbenzene was synthesized and confirmed by TLC, melting point, 13C-NMR and 1H-NMR. Conclusion: The operating method of the synthesis of 1,3,5-triacetylbenzene was simple, cheap and easily available for the raw materials, so it could be used for the industrial synthesis of relatively large quantities.