Jansson, K., Ahlfors, S., Frejd, T., Kihlberg, J. and Magnusson, G.J. (1988) 2-(Trimethylsilyl)ethyl Glycosides. 3. Synthesis, Anomeric Deblocking, and Transformation into 1,2-Trans 1-O-Acyl Sugars. The Journal of Organic Chemistry, 53, 5629-5647.
http://dx.doi.org/10.1021/jo00259a006
被以下文章引用:
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标题:
两种新型三甲基硅乙基葡萄糖苷的合成与表征Synthesis and Characterization of Two Novel 2-(Trimethylsilyl)ethyl Glucosides
作者:
乐晗, 金笑, 向学慧, 丁侃, 曲欢欢
关键字:
葡萄糖苷, 核磁共振, 结构表征, 合成Glucosides, NMR, Structure Elucidation, Synthesis
期刊名称:
《Journal of Organic Chemistry Research》, Vol.4 No.2, 2016-06-09
摘要:
本文报道了化学方法高效合成两种新型三甲基硅乙基葡萄糖苷的策略，所合成的化合物结构分别经高分辨质谱、一维和二维核磁共振谱确证。该两种新型葡萄糖苷作为寡糖合成的单糖砌块，可为未来我们构建新的寡糖结构片段提供物质基础和技术参考。
Two novel 2-(trimethylsilyl)ethyl glucosides have been synthesized by a short and efficient route starting from D-Glucose. Their structures were elucidated by applying high-resolution mass spectra, one-dimensional and two-dimensional NMR techniques. These glucosides were prepared and used as intermediate building blocks in the scheme developed for oligosaccharide construction.