JOCR  >> Vol. 5 No. 1 (March 2017)

    4-氨基安替比林希夫碱的合成、晶体结构及其荧光性质研究
    Study on Synthesis, Crystal Structure and Fluorescence Properties of Schiff Base from 4-Aminoantipyrine

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作者:  

刘巧茹,赵亚新,彭勤龙,薛灵伟,赵干卿:平顶山学院化学与环境工程学院,河南 平顶山

关键词:
希夫碱4-氨基安替比林晶体结构荧光性质Schiff Base 4-Aminoantipyrine Crystal Structure Fluorescence Property

摘要:

合成了水杨醛缩4-氨基安替比林希夫碱,通过红外光谱仪、核磁共振仪、元素分析仪、单晶X-衍射仪对产物的结构进行了表征,并对其与五种金属离子作用时的荧光性质进行了检测。结果表明:该希夫碱晶体属于单斜晶系,空间群为P2(1)/n,晶胞参数a = 0.7603 nm,b = 0.7508 nm,c = 2.7246 nm,α = 90.00˚,β = 95.43˚,γ = 90.00˚。V = 1.548 nm3,Z = 4,Dc = 1.314 g/cm3,μ = 0.088 mm−1,F(000) = 648,ρmax = 218 e∙nm−3,ρmin = −155 e∙nm−3。该希夫碱与金属作用后,在676 nm (λmax)具有较强的荧光吸收,其中Cu2+和Co2+所产生的荧光增强效应显著。

The title compound Schiff base was synthesized from salicylaldehyde and 4-aminoantipyrine. Its structure was characterized by IR, 1H NMR, Elemental Analyzer and X-ray single-crystal diffraction. Fluorescent property about the title compound complexed with five kinds of metal ions was investigated. The results show that the compound crystallizes in the monoclinic space group P2(1)/n with cell parameters: a = 0.7603 nm, b = 0.7508 nm, c = 2.7246 nm, α = 90.00˚, β= 95.43˚, γ = 90.00˚. V = 1.548 nm3, Z = 4, Dc = 1.314 g/cm3, μ = 0.088 mm−1, F(000) = 648, ρmax = 218 e∙nm−3, ρmin = −155 e∙nm−3. The complexes exhibited strong fluorescence absorption at 676 nm (λmax). Fluorescence enhancement effect produced by Cu2+, Co2+ is remarkable.

文章引用:
刘巧茹, 赵亚新, 彭勤龙, 薛灵伟, 赵干卿. 4-氨基安替比林希夫碱的合成、晶体结构及其荧光性质研究[J]. 有机化学研究, 2017, 5(1): 1-7. https://doi.org/10.12677/JOCR.2017.51001

参考文献

[1] Zhang, X.L. (2016) Synthesis, Crystal Structures, and Antibacterial Activities of Schiff Base nickel(II) and Cadmium(II) Complexes with Tridentate Schiff Bases. Russian Journal of Coordination Chemistry, 42, 436-441.
https://doi.org/10.1134/S107032841607006X
[2] Pardasani, R.T. and Pardasani, P. (2015) Magnetic Properties of Complex of Cobalt(II) with Tridentate Schiff Base Derived by the Condensation of Salicylaldehyde and Furfuraldehyde with o-Phenyldiamine. Magnetic Properties of Paramagnetic Compounds, 31B, 714.
[3] 王澈, 侯鹏, 李崧, 等. 席夫碱及其金属配合物的合成及生物活性[J]. 化学通报, 2009, 29(4): 334-339.
[4] Fatemeh, M., Bita, S., Ahmad, S., et al. (2016) Synthesis, Spectral Characterization, X-Ray Crystal Structure, Electrochemical Studies, and DNA Interactions of a Schiff Base Pro-Ligand and Its Homobimetallic Com-plexes Containing the Cysteaminemoiety. Transition Metal Chemistry, 41, 475-484.
https://doi.org/10.1007/s11243-016-0043-6
[5] Bu, J., Duan, H.D. and Wang, X.J. (2014) Fluorescence Sensors for Cu2+ Based on Conjugated Indole Schiff Base. Research on Chemical Intermediates, 40, 3119-3126.
https://doi.org/10.1007/s11164-013-1157-5
[6] 庞海霞, 徐保明, 陈彦国, 等. 一种新型Pb(Ⅱ)配位聚合物的合成、表征及性质研究[J]. 人工晶体学报, 2014, 43(1): 242-247.
[7] Yu, C.W., Zhang, J., Li, J.H., et al. (2011) Fluorescent Probe for Copper(II) Ion Based on a Rhodaminespirolactame Derivative, and Its Application to Fluorescent Imaging in Living Cells. Microchimica Acta, 174, 247-255.
[8] Saleem, M., Khang, C.H., Kim, M., et al. (2016) Chromo/Fluorogenic Detection of Co2+, Hg2+ and Cu2+ by the Simple Schiff Base Sensor. Journal of Fluorescence, 26, 11-22.
https://doi.org/10.1007/s10895-015-1723-x
[9] 庞海霞, 龚兴厚, 张正强, 等. 一种新型双核锰(II) 配合物的合成、表征及磁性能研究[J]. 人工晶体学报, 2015, 44(7): 2012-2016.
[10] Li, Y., Liu, Z., Zhu, W., et al. (2015) Two Different Emission-Wavelength Fluorescent Probes for Aluminum Ion based on Tunable Fluorophores in Aqueous Media. Journal of Fluorescence, 25, 603-611.
https://doi.org/10.1007/s10895-015-1541-1
[11] Sheldrick, G.M. (1997) SADABS. Program for Empirical Absorption Correc-tion of Area Detector. University of Göttingen, Germany.
[12] Sheldrick, G.M. (1997) SHELXL97, Program for the Solution of Crystal Structures. University of Göttingen, Germany.
[13] 邱建超, 毕彩丰, 范玉华, 等. 苯甲醛缩4-氨基安替比林希夫碱的合成、晶体结构和量子化学研究[J]. 中国海洋大学学报, 2008, 38(6): 985-991.