JAPC  >> Vol. 6 No. 3 (August 2017)

    碳量子点的制备与应用
    Synthesis and Applications of Carbon Quantum Dots

  • 全文下载: PDF(1137KB) HTML   XML   PP.128-136   DOI: 10.12677/JAPC.2017.63016  
  • 下载量: 423  浏览量: 1,298   国家自然科学基金支持

作者:  

叶明富,陈丙才,方 超,陈国昌:安徽工业大学和县化工产业发展研究院化学与化工学院,安徽 马鞍山;
吴延红:山东华宇工学院,山东 德州;
孔祥荣:北京建筑材料科学研究总院有限公司,北京

关键词:
碳量子点纳米材料制备方法应用Carbon Quantum Dots Nanomaterials Preparation Methods Applications

摘要:

碳量子点(Carbon quantum dots, CQDs)是一种新型的碳纳米材料,因其强的量子限域效应和稳定的荧光性能等一系列优异性能,吸引了化学、物理、材料和生物等各领域科学家的广泛关注。本文主要综述了CQDs的不同合成方法及其应用。

Carbon quantum dots (CQDs), a novel class of carbon nanomaterials, have received wide attention due to their strong quantum confinement effect and stable photoluminescence property. This article reviews the different synthetic methodologies to achieve good performance of CQDs. At the same time, the applications of CQDs are also reviewed in the article.

文章引用:
叶明富, 陈丙才, 方超, 吴延红, 陈国昌, 孔祥荣. 碳量子点的制备与应用[J]. 物理化学进展, 2017, 6(3): 128-136. https://doi.org/10.12677/JAPC.2017.63016

参考文献

[1] 叶明富, 逯亚飞, 董琦, 等. Fe3O4纳米材料的制备与应用[J]. 中国陶瓷, 2014, 50(12): 9-13.
[2] 黄启同, 林小凤, 李飞明, 等. 碳量子点的合成与应用[J]. 化学进展, 2015, 27(11): 1604-1614.
[3] Xu, X., Ray, R., Gu, Y., et al. (2004) Electrophoretic Analysis and Purification of Fluorescent Single-Walled Carbon Nanotube Fragments. Journal of the American Chemical Society, 126, 12736-12737.
https://doi.org/10.1021/ja040082h
[4] Sun, Y.P., Zhou, B., Lin, Y., et al. (2006) Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence. Journal of the American Chemical Society, 128, 7756-7757.
https://doi.org/10.1021/ja062677d
[5] Lim, S.Y., Shen, W. and Gao, Z. (2015) Carbon Quantum Dots and Their Applications. Chemical Society Reviews, 44, 362-381.
https://doi.org/10.1039/C4CS00269E
[6] Tan, L.F., Huang, G.B., Liu, T.L., et al. (2016) Synthesis of Highly Bright Oil-Soluble Carbon Quantum Dots by Hot-Injection Method with N and B Co-Doping. Journal of Nanoscience and Nanotechnology, 16, 2642-2657.
https://doi.org/10.1166/jnn.2016.10936
[7] Li, X.M., Rui, M.C., Song, J.Z., et al. (2015) Carbon and Graphene Quantum Dots for Optoelectronic and Energy Devices: A Review. Advanced Functional Materials, 25, 4929-4947.
https://doi.org/10.1002/adfm.201501250
[8] 王莉, 吕婷, 阮枫萍, 等. 水热法制备的荧光碳量子点[J]. 发光学报, 2014, 35(6): 706-709.
[9] 郭璇, 莫文轩, 刘旭亮, 等. 落叶松木粉水热炭化制备碳量子点及其性能研究[J]. 林产化学与工业, 2017, 37(1): 109-115.
[10] Yang, Y.H., Cui, J.H., Zheng, M.T., et al. (2012) One-Step Synthesis of Amino-Functionalized Fluorescent Carbon Nanoparticles by Hydrothermal Carbonization of Chitosan. Chemical Communications, 48, 380-382.
https://doi.org/10.1039/C1CC15678K
[11] De, B. and karak, N. (2013) A Green and Facile Approach for the Synthesis of Water Soluble Fluorescent Carbon Dots from Banana Juice. RSC Advances, 3, 8286-8290.
https://doi.org/10.1039/c3ra00088e
[12] Sahu, S., Behera, B., Maiti, T.K., et al. (2012) Simple One-Step Synthesis of Highly Luminescent Carbon Dots from Orange Juice: Application as Excellent Bio-Imaging Agents. Chemical Communications, 48, 8835-8837.
https://doi.org/10.1039/c2cc33796g
[13] Zhang, Z., Hao, J.H., Zhang, J., et al. (2012) Protein as the Source for Synthesizing Fluorescent Carbon Dots by a One- Pot Hydrothermal Route. RSC Advances, 2, 8599-8601.
https://doi.org/10.1039/c2ra21217j
[14] Zhu, H., Wang, X.L., Li, Y.L., et al. (2009) Microwave Synthesis of Fluorescent Carbon Nanoparticles with Electrochemiluminescence Properties. Chemical Communications, 45, 5118-5120.
https://doi.org/10.1039/b907612c
[15] Chandra, S., Das, P., Bag, S., et al. (2011) Synthesis, Functionalization and Bioimaging Applications of Highly Fluorescent Carbon Nanoparticles. Nanoscale, 3, 1533-1540.
https://doi.org/10.1039/c0nr00735h
[16] Jaiswal, A., Ghosh, S.S. and Chattopadhyay, A. (2012) One Step Synthesis of C-Dots by Microwave Mediated Caramelization of Poly (Ethylene Glycol). Chemical Communications, 48, 407-409.
https://doi.org/10.1039/C1CC15988G
[17] Tang, L., Ji, R., Cao, X., et al. (2012) Deep Ultraviolet Photoluminescence of Water-Soluble Self-Passivated Graphene Quantum Dots. ACS Nano, 6, 5102-5110.
https://doi.org/10.1021/nn300760g
[18] Qin, X.Y., Lu, W.B., Asiri, A.M., et al. (2013) Microwave-Assisted Rapid Green Synthesis of Photoluminescent Carbon Nanodots from Flour and Their Applications for Sensitive and Selective Detection of Mercury(II) Ions. Sensors and Actuators B: Chemical, 26, 12-14.
[19] Li, H.T., He, X.D., Liu, Y., et al. (2011) Synthesis of Fluorescent Carbon Nanoparticles Directly from Active Carbon via a One-Step Ultrasonic Treatment. Materials Research Bulletin, 46, 147-151.
[20] Li, H.T., He, X.D., Liu, Y., et al. (2011) One-Step Ultrasonic Synthesis of Water-Soluble Carbon Nanoparticles with Excellent Photoluminescent Properties. Carbon, 49, 605-609.
[21] Tao, H., Yang, K., Ma, Z., et al. (2012) In Vivo NIR Fluorescence Imaging, Biodistribution, and Toxicology of Photoluminescent Carbon Dots Produced from Carbon Nanotubes and Graphite. Small, 8, 281-290.
https://doi.org/10.1002/smll.201101706
[22] Chen, B.S., Li, F.M., Li, S.X., et al. (2013) Large Scale Synthesis of Photoluminescent Carbon Nanodots and Their Application for Bioimaging. Nanoscale, 5, 1967-1971.
https://doi.org/10.1039/c2nr32675b
[23] Nie, H., Li, M.J., Li, Q.S., et al. (2014) Carbon Dots with Continuously Tunable Full-Color Emission and Their Application in Ratiometric pH Sensing. Chemistry of Materials, 26, 3104-3112.
https://doi.org/10.1021/cm5003669
[24] Bourlinos, A.B., Stassinopoulos, A., Anglos, D., et al. (2008) Surface Functionalized Carbogenic Quantum Dots. Small, 4, 455-458.
https://doi.org/10.1002/smll.200700578
[25] Zhou, J.G., Booker, C., Li, R.Y., et al. (2007) An Electrochemical Avenue to Blue Luminescent Nanocrystals from Multiwalled Carbon Nanotubes (MWCNTs). Journal of the American Chemical Society, 129, 744-745.
https://doi.org/10.1021/ja0669070
[26] Lu, J., Yang, J.X., Wang, J.Z., et al. (2009) One-Pot Synthesis of Fluorescent Carbon Nanoribbons, Nanoparticles, and Graphene by the Exfoliation of Graphite in Ionic Liquids. ACS Nano, 3, 2367-2375.
https://doi.org/10.1021/nn900546b
[27] Li, H.T., He, X.D., Kang, Z.H., et al. (2010) Water-Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design. Angewandte Chemie International Edition, 49, 4430-4434.
https://doi.org/10.1002/anie.200906154
[28] Cao, L., Wang, X., Meziani, M.J., et al. (2007) Carbon Dots for Multiphoton Bioimaging. Journal of the American Chemical Society, 129, 11318-11319.
https://doi.org/10.1021/ja073527l
[29] Hu, S.L., Niu, K.Y., Sun, J., et al. (2009) One-Step Synthesis of Fluorescent Carbon Nanoparticles by Laser Irradiation. Journal of Materials Chemistry, 19, 484-488.
https://doi.org/10.1039/B812943F
[30] Li, X.Y., Wang, H.Q., Shimizu, Y., et al. (2011) Preparation of Carbon Quantum Dots with Tunable Photoluminescence by Rapid Laser Passivation in Ordinary Organic Solvents. Chemical Communications, 47, 932-934.
https://doi.org/10.1039/C0CC03552A
[31] Bottini, M., Balasubramanian, C., Dawson, M.I., et al. (2006) Isolation and Characterization of Fluorescent Nanoparticles from Pristine and Oxidized Electric Arc-Produced Single-Walled Carbon Nanotubes. Journal of Physical Chemistry B, 110, 831-836.
https://doi.org/10.1021/jp055503b
[32] Xu, J., Sahu, S.Q., Cao, L., et al. (2011) Carbon Nanoparticles as Chromophores for Photon Harvesting and Photoconversion. ChemPhysChem, 12, 3604-3608.
https://doi.org/10.1002/cphc.201100640
[33] 孙墨杰, 赵志海, 陈红梅, 等. 碳量子点的合成研究进展与展望[J]. 化学通报, 2016, 79(6): 691-698.
[34] 吴腾飞, 敖燕辉, 王沛芳, 等. 碳量子点的合成和应用[J]. 材料导报, 2016, 30(7): 30-35.
[35] Li, H.T., Liu, R.H., Lian, S.Y., et al. (2013) Near-Infrared Light Controlled Photocatalytic Activity of Carbon Quantum Dots for Highly Selective Oxidation Reaction. Nanoscale, 5, 3289-3297.
https://doi.org/10.1039/c3nr00092c
[36] Li, H.T., Liu, R.H., Kong, W.Q., et al. (2014) Carbon Quantum Dots with Photo-Generated Proton Property as Efficient Visible Light Controlled Acid Catalyst. Nanoscale, 6, 867-873.
https://doi.org/10.1039/C3NR03996J
[37] Liu, R.H., Huang, H., Li, H.T., et al. (2013) Metal Nanoparticle/Carbon Quantum Dot Composite as a Photocatalyst for High-Efficiency Cyclohexane Oxidation. ACS Catalysis, 4, 328-336.
https://doi.org/10.1021/cs400913h
[38] Chen, X. and Mao, S.S. (2007) Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications. Chemical Reviews, 107, 2891-2959.
https://doi.org/10.1021/cr0500535
[39] Mirtchev, P., Henderson, E.J, Soheilnia, N., et al. (2012) Solution Phase Synthesis of Carbon Quantum Dots as Sensitizers for Nanocrystalline TiO2 Solar Cells. Journal of Materials Chemistry, 22, 1265-1269.
https://doi.org/10.1039/C1JM14112K
[40] Xiong, H.Y., Zhang, X.H., Dong, B.H., et al. (2013) The Preparation of Carbon Dots/Ionic Liquids-Based Electrolytes and Their Applications in Quasi-Solid-State Dye-Sensitized Solar. Electrochimica Acta, 88, 100-106.
[41] Wang, F., Chen, Y.H., Liu, C.Y., et al. (2011) White Light-Emitting Devices Based on Carbon Dots’ Electroluminescence. Chemical Communications, 47, 3502-3504.
https://doi.org/10.1039/c0cc05391k
[42] Jiang, K., Sun, S., Zhang, L., et al. (2015) Red, Green, and Blue Luminescence by Carbon Dots: Full-Color Emission Tuning and Multicolor Cellular Imaging. Angewandte Chemie International Edition, 54, 5360-5363.
https://doi.org/10.1002/anie.201501193