过渡金属基底原位修饰直接用于电催化水分解反应的研究进展
Research Progress of in Situ Modification of Transition Metal Substrates for Direct Elec-trocatalytic Water Splitting
DOI: 10.12677/NAT.2021.113008, PDF,    国家自然科学基金支持
作者: 郭艳玲, 熊 康, 顾伟诗, 周清稳*:南通大学,公共卫生学院,环境卫生与绿色化学研究所,江苏 南通
关键词: 过渡金属基底原位修饰电催化反应研究进展 Transition Metal In Situ Modification of Substrates Electrocatalysis Reactions Research Progress
摘要: 过渡金属基底电催化材料具有催化性能良好、储量丰富、价格低廉等诸多优势,在新型非贵金属催化剂研究中得到了广泛的关注。通过对其基底原位修饰能够获得丰富的催化活性位点,可以直接用于电催化反应。这篇综述讨论了几种基底原位修饰过渡金属的方法,展望了基底原位修饰形成的新型催化剂的发展趋势与方向。
Abstract: Transition metal substrates electrocatalysis materials have many advantages, such as superior catalytic performance, abundant reserves, inexpensive price and so on. Thus they have drawn wide attention in the study of new non-precious metal catalysts. Abundant active sites can be obtained by in-situ modification of the substrates, which can be directly used in electrocatalysis reactions. In this review, several methods of in-situ modification of transition metals on substrates are discussed, and the development trend and direction of new catalysts formed by in-situ modification of substrates are prospected.
文章引用:郭艳玲, 熊康, 顾伟诗, 周清稳. 过渡金属基底原位修饰直接用于电催化水分解反应的研究进展[J]. 纳米技术, 2021, 11(3): 59-69. https://doi.org/10.12677/NAT.2021.113008

参考文献

[1] Strmcnik, D., Uchimura, M., Wang, C., Subbaraman, R., Subbaraman, R., Danilovic, N., van der Vliet, D., et al. (2013) Improving the Hydrogen Oxidation Reaction Rate by Promotion of Hydroxyl Adsorption. Nature Chemistry, 5, 300-306. [Google Scholar] [CrossRef] [PubMed]
[2] Yan, J., Yao, Z., Mietek, J. and Qiao, S.Z. (2015) Design of Electrocata-lysts for Oxygen and Hydrogen-Involving Energy Conversion Reactions. Chemical Society Reviews, 44, 2060-2086. [Google Scholar] [CrossRef
[3] Feng, J.X., Xu, H., Dong, Y.T., Ye, S.-H., Tong, Y.-X. and Li, G.-R. (2016) FeOOH/Co/FeOOH Hybrid Nanotube Arrays as High-Performance Electrocatalysts for the Oxygen Evolution Reaction. Angewandte Chemie International Edition, 55, 3694-3698. [Google Scholar] [CrossRef] [PubMed]
[4] Zhang, X., Liu, R., Zang, Y., Liu, G., Wang, G., Zhang, Y., et al. (2016) Co/CoO Nanoparticles Immobilized on Co-N-Doped Carbon as Trifunctional Electrocatalysts for Oxygen Reduc-tion, Oxygen Evolution and Hydrogen Evolution Reactions. Chemical Communications, 52, 5946-5949. [Google Scholar] [CrossRef
[5] Zeng, J.R., Gao, M.Y., Zhang, Q.B., Yang, C., Li, X.T., Yang, W.Q., et al. (2017) Facile Electrodeposition of Cauliflower-Like S-Doped Nickel Microsphere Films as Highly Active Catalysts for Electrochemical Hydrogen Evolution. Journal of Materials Chemistry A, 29, 15056-15064. [Google Scholar] [CrossRef
[6] Anantharaj, S., Ede, S., Sakthikumar, K., Sakthikumar, K., Karthick, K., Mishra, S., et al. (2016) Recent Trends and Perspectives in Electrochemical Water Splitting with an Emphasis on Sulfide, Selenide, and Phosphide Catalysts of Fe, Co, and Ni: A Review. ACS Catalysis, 6, 8069-8097. [Google Scholar] [CrossRef
[7] Zhang, W., Li, D.H., Zhang, L.Z., She, X. and Yang, D. (2019) NiFe-Based Nanostructures on Nickel Foam as Highly Efficiently Electro-Catalysts for Oxygen and Hydrogen Evolution Reactions. Journal of Energy Chemistry, 39, 39-53. [Google Scholar] [CrossRef
[8] 王燕勇. 层状双金属氢氧化物及其衍生物电催化性能的研究[D]: [博士学位论文]. 长沙: 湖南大学, 2018.
[9] 冀国超, 赵笑飞. 过渡金属磷化物在电解水制氢方向的研究进展[J]. 化工管理, 2018(33): 69-71.
[10] Song, Y.F., Zhao, Y.H., Nan, G.Z., Chen, W., Guo, Z., Li, S., et al. (2020) Electrocatalytic Oxidation of Methane to Ethanol via NiO/Ni Interface. Applied Catalysis B: Environmental, 270, Article ID: 118888. [Google Scholar] [CrossRef
[11] Hao, J., Liu, J.W., Wu, D., Chen, M., Liang, Y., Wang, Q., et al. (2021) In Situ Facile Fabrication of Ni(OH)2 Nanosheet Arrays for Electrocatalytic Coproduction of Formate and Hy-drogen from Methanol in Alkaline Solution. Applied Catalysis B: Environmental, 281, Article ID: 119510. [Google Scholar] [CrossRef
[12] Wu, L.B., Yu, L., Zhang, F.H., McElhenny, B., Luo, D., Karim, A., et al. (2020) Heterogeneous Bimetallic Phosphide Ni2P-Fe2P as an Efficient Bifunctional Catalyst for Water/Seawater Splitting. Advanced Functional Materials, 31, Article ID: 2006484. [Google Scholar] [CrossRef
[13] Ksenia, F., Petko, C., Ivelina, Z., Sicklinger, J., Stefanic, G., Dö-blinger, M., et al. (2015) Iron-Doped Nickel Oxide Nanocrystals as Highly Efficient Electrocatalysts for Alkaline Water Splitting. ACS Nano, 9, 5180-5188. [Google Scholar] [CrossRef] [PubMed]
[14] Daniel, F., Mary, W.L., Michal, B., Sanwald, K.E., Cai, Y., Wise, A.M., et al. (2015) Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting. Journal of the American Chemistry Society, 137, 1305-1313. [Google Scholar] [CrossRef] [PubMed]
[15] Zhang, J., Jiang, W.J., Niu, S., Zhang, H., Liu, J., Li, H., et al. (2020) Organic Small Molecule Activates Transition Metal Foam for Efficient Oxygen Evolution Reaction. Advanced Materials, 32, Article ID: 1906015. [Google Scholar] [CrossRef] [PubMed]
[16] Niu, S., Jiang, W.J., Tang, T., Yuan, L.-P., Luo, H. and Hu, J.-S. (2019) Autogenous Growth of Hierarchical NiFe(OH)x/FeS Nanosheet-On-Microsheet Arrays for Synergistically En-hanced High-Output Water Oxidation. Advanced Functional Materials, 29, Article ID: 1902180. [Google Scholar] [CrossRef
[17] Li, Y.J., Zhang, H.C., Jiang, M., Zhang, Q., He, P. and Sun, X.M. (2017) 3D Self-Supported Fe-Doped Ni2P Nanosheet Arrays as Bifunctional Catalysts for Overall Water Splitting. Ad-vanced Functional Materials, 27, Article ID: 1702513. [Google Scholar] [CrossRef
[18] Kou, T.Y., Wang, S.W., Jesse, L., Chen, M., Oliver, S.R.J., Ye, Y., et al. (2019) Ni Foam-Supported Fe-Doped β-Ni(OH)2 Nanosheets Show Ultralow Overpotential for Oxygen Evolution Reaction. ACS Energy Letters, 4, 622-628. [Google Scholar] [CrossRef
[19] Dong, G.F., Fang, M., Zhang, J.S., Wei, R., Shu, L., Liang, X., et al. (2017) In Situ Formation of Highly Active Ni-Fe Based Oxygen-Evolving Electrocatalysts via Simple Reactive Dip-Coating. Journal of materials Chemistry A, 5, 11009-11015. [Google Scholar] [CrossRef
[20] Ren, J.T., Yuan, G.G., Weng, C.C., Chen, L. and Yuan, Z.-Y. (2018) Uniquely Integrated Fe-Doped Ni(OH)2 Nanosheets for Highly Efficient Oxygen and Hydrogen Evolution Reactions. Nanoscale, 10, 10620-10628. [Google Scholar] [CrossRef
[21] Li, D.R., Pan, Z.Q., Tao, H., Li, J., Gu, W., Li, B., et al. (2020) Self-Derivation-Behaviour of Substrates Realizing Enhanced Oxygen Evolution Reaction. Chemical Communications, 56, 12399-12402. [Google Scholar] [CrossRef
[22] Yuan, H.F., Wang, S.M., Gu, X.D., Tang, B., Li, J. and Wang, X. (2019) One-Step Solid-phase Boronation to Fabricate Self-Supported Porous FeNiB/FeNi Foam for Efficient Electrocat-alytic Oxygen Evolution and Overall Water Splitting. Journal of Materials Chemistry A, 7, Article ID: 19554. [Google Scholar] [CrossRef
[23] Zhong, H.X., Wang, J., Meng, F.L. and Zhang, X. (2016) In Situ Acti-vating Ubiquitous Rust towards Low-Cost, Efficient, Free Standing, and Recoverable Oxygen Evolution Electrodes. An-gewandte Chemie International Edition, 55, 9937-9941. [Google Scholar] [CrossRef] [PubMed]
[24] Tang, C., Abdullah, M.A. and Sun, X.P. (2016) Highly-Active Oxygen Evolution Electrocatalyzed by a Fe-Doped NiSe Nanoflake Array Electrode. Chemical Communications, 52, 4529-4532. [Google Scholar] [CrossRef
[25] Wei, L., Goh, K.L., Özgür, B., Enis Karahan, H., Chang, J., Zhai, S., et al. (2017) A Hierarchically Porous Nickel-Copper Phos-phide Nano-Foam for Efficient Electrochemical Splitting of Water. Nanoscale, 9, 4401-4408. [Google Scholar] [CrossRef
[26] Xiang, Q., Li, F., Chen, W.L., Ma, Y., Wu, Y., Gu, X., et al. (2018) In-Situ Vertical Growth of Fe-Ni Layered Double Hydroxide Arrays on Fe-Ni Alloy Foil: Interfacial Layer Enhanced Electrocatalyst with Small Overpotential for Oxygen Evolution Reaction. ACS Energy Letters, 3, 2357-2365. [Google Scholar] [CrossRef
[27] Liu, M.S., Chen, T., Zhang, W.X., Wei, S., Cheng, Y. and Liu, J. (2021) In Situ Construction of Pollen-Petal-Like Heterostructured Co3O4-CeO2 on 3D FeNi3 Foam as a Bifunctional Catalyst for Overall Water Splitting. Sustainable Energy Fuels, 5, 2181-2189. [Google Scholar] [CrossRef
[28] Wu, Y., Li, F., Chen, W.L., Xiang, Q., Ma, Y., Zhu, H., et al. (2018) Coupling Interface Constructions of MoS2/Fe5Ni4S8 Heterostructures for Efficient Electrochemical Water Splitting. Ad-vanced Materials, 30, Article ID: 1803151. [Google Scholar] [CrossRef] [PubMed]
[29] Bu, X.M., Wei, R.J., Gao, W., Lan, C. and Ho, J.C. (2019) A Unique Sandwich Structure of a CoMnP/Ni2P/NiFe Electrocatalyst for Highly Efficient Overall Water Splitting. Journal of Materials Chemistry A, 7, 12325-12332. [Google Scholar] [CrossRef
[30] Chen, J.S., Ren, J.W., Menny S., Fellinger, T. and Antonietti, M. (2016) Stainless Steel Mesh-Supported NiS Nanosheet Array as Highly Efficient Catalyst for Oxygen Evolution Reac-tion. ACS Applied Materials & Interfaces, 8, 5509-5516. [Google Scholar] [CrossRef] [PubMed]