亚胺类共价有机框架材料在光催化应用中的最新进展
Latest Advances in Imine-Based Covalent Organic Frameworks for Photocatalytic Applications
DOI: 10.12677/ms.2026.163048, PDF,   
作者: 邓梓瑜, 梁语嫣, 董坤范, 贾静茹, 周峻安, 傅仰河*：浙江师范大学含氟新材料研究所，先进催化材料教育部重点实验室，浙江 金华
关键词: 亚胺类共价有机框架；光催化；合成方法；应用；Imine-Based Covalent Organic Frameworks； Photocatalysis； Synthesis Methods； Applications
摘要: 共价有机框架(Covalent Organic Frameworks, COFs)是一类由有机构筑单元通过强共价键精准连接而成的新型多孔有机材料。这类材料兼具可调控的拓扑结构、永久孔隙率、高结晶度、大比表面积及优异的化学与物理稳定性，为其在多类光催化领域的应用奠定了坚实基础。连接化学是调控COFs合成过程与物化性质的核心要素，在众多连接方式中，亚胺键因制备简便、结构与功能兼具丰富的可设计性，已发展为构筑COFs材料最常用且最重要的连接方式之一。本文系统阐述亚胺连接COFs的设计策略与合成方法，进而综述其在光催化领域的研究进展，并深入剖析该类材料在实际应用中面临的挑战。
Abstract: Covalent organic frameworks (COFs) are a novel class of porous organic materials constructed from organic building blocks via precise linkage by strong covalent bonds. Featuring tailorable topological structures, permanent porosity, high crystallinity, large specific surface areas, and excellent chemical and physical stability, these materials lay a solid foundation for their applications in various photocatalytic fields. Linkage chemistry serves as the core factor in regulating the synthesis process and physicochemical properties of COFs. Among diverse linkage types, the imine linkage has become one of the most commonly used and crucial linkages for constructing COFs owing to its facile preparation and remarkable designability in both structure and function. This review systematically elaborates the design strategies and synthetic methods of imine-linked COFs, further summarizes the research progress of these materials in photocatalysis, and deeply analyzes the challenges encountered in their practical applications.
文章引用：邓梓瑜, 梁语嫣, 董坤范, 贾静茹, 周峻安, 傅仰河. 亚胺类共价有机框架材料在光催化应用中的最新进展[J]. 材料科学, 2026, 16(3): 28-34. https://doi.org/10.12677/ms.2026.163048

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