固定化ZIF-67在过硫酸盐高级氧化工艺水处理领域的应用
Application of Immobilized ZIF-67 in the Treatment of Process Water in the Advanced Oxidation Process of Peroxide
摘要: 沸石咪唑骨架-67 (ZIF-67)由金属离子Co2+和2-甲基咪唑配体组成，是一种典型的金属有机框架(MOF)材料。作为新兴的多功能材料，基于ZIF-67的材料因其异常高的比表面积、可调控的孔隙率以及优异的热化学稳定性，在合成与应用领域日益受到关注。但其制备通常以粉末状为主，因此在实际水处理应用中受限。目前仍迫切需要开发出具有催化活性、制备便捷且可简单回收的基底支撑型MOFs。本文重点探讨其在过硫酸盐高级氧化工艺(PS-AOPs)废水处理领域的研究进展。本文总结了固定化ZIF-67催化剂在PS-AOPs中的制备策略及应用。最后，我们展望ZIF-67基材料及其衍生物在PS-AOPs处理有机废水的未来发展方向。
Abstract: Zirconium imidazole framework-67 (ZIF-67), composed of the metal ion Co2+ and 2-methylimidazole ligand, is a typical metal-organic framework (MOF) material. As an emerging multifunctional material, ZIF-67-based materials have garnered increasing attention in synthesis and application due to their exceptionally high specific surface area, tunable porosity, and excellent thermochemical stability. Their preparation is predominantly at the nanoscale, which limits their application in solution reactions. There remains an urgent need to develop substrate-supported MOFs with catalytic activity, convenient preparation, and simple recovery. This article focuses on the research progress of ZIF-67-based materials in the field of wastewater treatment using persulfate advanced oxidation processes (PS-AOPs). It summarizes the latest enhancement strategies for immobilized ZIF-67 catalysts in PS-AOPs. Finally, we outline future application directions for ZIF-67-based materials in the treatment of organic wastewater through PS-AOPs.
文章引用：朱纳玉, 卢欣怡, 唐昊昱, 黄涵, 刘超. 固定化ZIF-67在过硫酸盐高级氧化工艺水处理领域的应用[J]. 水污染及处理, 2026, 14(2): 87-97. https://doi.org/10.12677/wpt.2026.142010

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