深地钻探极限工况下流型调节剂的分子工程与界面调控新进展
Advances in Molecular Engineering and Interfacial Modulation of Flow Conditioners for Deep Drilling under Extreme Conditions
DOI: 10.12677/ms.2026.1610192, PDF,   
作者: 汪春林, 杨 健, 唐天天:陕西合信油服科技股份有限公司,榆林市地层物理封堵工程技术研究中心,陕西 榆林;廖忠辉, 勇志华, 都伟超, 陈 刚, 顾雪凡*:西安石油大学,陕西省油气田环境污染控制技术与储层保护重点实验室,陕西 西安
关键词: 高温水基钻井液;流型调节剂;低黏高切;疏水缔合;纳米复合材料;High-Temperature Water-Based Drilling Fluid; Flow Conditioner; Low-Viscosity and High-Gel-Strength; Hydrophobic Association; Nanocomposite
摘要: 深层–超深层油气井、地热井及长水平段钻井作业使水基钻井液面临高温、高盐、高密度及复杂剪切历史的多重耦合挑战。围绕“低黏高切”这一核心目标,本文从高温流变失稳机理、功能材料构筑、代表性原始研究证据及工程适配性四个层面,系统梳理了天然/生物基聚合物、耐温合成聚合物、聚合物–纳米复合材料及混合金属氢氧化物等技术路线,并明确区分专用流型调节剂的直接流变证据与降滤失、抑制等多功能添加剂的协同作用证据。综合分析表明,实现高温流变稳定的关键并非单纯提升表观黏度,而是在有效控制塑性黏度与循环压耗的前提下,构建具有可逆恢复能力的低剪切网络结构;当前调控手段主要包括强化水化/刚性链段设计、疏水或温敏缔合、有限微交联以及颗粒界面节点构筑。然而,现有研究仍面临试验制度不统一、原位高温高压及长周期循环实验数据不足、全配方相容性与规模化验证薄弱等问题。后续应加强构效关系、动态评价方法与工程边界条件的协同研究,以提升实验结论向井下实际工况转化的可靠性与适用性。
Abstract: Deep to ultra-deep oil/gas wells, geothermal boreholes, and extended-reach horizontal sections expose water-based drilling fluids to a formidable combination of elevated temperature, high salinity, high density, and complex shearing histories. Aiming at the “low-viscosity, high-gel-strength” paradigm, this review critically evaluates progress across four interrelated dimensions—thermal rheological failure mechanisms, functional material design, representative experimental evidence, and engineering applicability. Technical routes examined include natural/bio-based polymers, thermally stable synthetic polymers, polymer-nanocomposite systems, and mixed metal hydroxides, with deliberate discrimination between direct rheological contributions from dedicated flow conditioners and synergistic effects from multifunctional additives (e.g., fluid-loss reducers and shale inhibitors). The findings suggest that high-temperature rheological stability hinges not on boosting apparent viscosity per se, but on establishing a reversible low-shear network that keeps plastic viscosity and circulation pressure losses within acceptable bounds. Current strategies revolve around rigid-chain/hydration-enhanced segments, hydrophobic or thermosensitive association, mild micro-crosslinking, and particulate interfacial junctions. Nonetheless, unresolved issues persist—inconsistent testing protocols, scarcity of in-situ HTHP and long-term cyclic data, weak full-formulation compatibility checks, and insufficient field-scale validation. Advancing this field thus calls for integrated studies bridging structure-property relationships, dynamic evaluation techniques, and realistic downhole constraints, so that laboratory conclusions become more reliably translatable to subsurface operations.
文章引用:汪春林, 杨健, 唐天天, 廖忠辉, 勇志华, 都伟超, 陈刚, 顾雪凡. 深地钻探极限工况下流型调节剂的分子工程与界面调控新进展[J]. 材料科学, 2026, 16(10): 73-86. https://doi.org/10.12677/ms.2026.1610192

参考文献

[1] 张雁, 屈沅治, 张志磊, 等. 超高温水基钻井液技术研究现状及发展方向[J]. 油田化学, 2022, 39(3): 540-547.
[2] Mahto, V. and Sharma, V.P. (2004) Rheological Study of a Water Based Oil Well Drilling Fluid. Journal of Petroleum Science and Engineering, 45, 123-128.
https://doi.org/10.1016/j.petrol.2004.03.008
[3] Davoodi, S., Al-Shargabi, M., Wood, D.A., Rukavishnikov, V.S. and Minaev, K.M. (2024) Synthetic Polymers: A Review of Applications in Drilling Fluids. Petroleum Science, 21, 475-518.
https://doi.org/10.1016/j.petsci.2023.08.015
[4] 袁玥辉, 屈沅治, 高世峰, 等. 抗温抗盐水基钻井液降滤失剂研究进展[J]. 新疆石油天然气, 2023, 19(2): 62-68.
[5] Minakov, A.V., Pryazhnikov, M.I., Mikhienkova, E.I. and Voronenkova, Y.O. (2023) Systematic Experimental Study of the Temperature Dependence of Viscosity and Rheological Behavior of Water-Based Drilling Fluids with Nano-Additives. Petroleum, 9, 534-544.
https://doi.org/10.1016/j.petlm.2022.03.001
[6] Wang, Z., Sun, J., Huang, X., Lv, K. and Geng, Y. (2024) A Temperature-Sensitive Polymer with Thinner Effect as a Rheology Modifier in Deepwater Water-Based Drilling Fluids. Journal of Molecular Liquids, 393, Article ID: 123536.
https://doi.org/10.1016/j.molliq.2023.123536
[7] 屈沅治, 林凌, 黄宏军, 等. 两性离子聚合物老化对蒙脱土性质的影响[J]. 石油化工, 2022, 51(8): 931-938.
[8] Liu, L., Sun, J., Wang, R., Qu, Y., Liu, F., Yang, J., et al. (2022) Synthesis of a New High Temperature and Salt Resistant Zwitterionic Filtrate Reducer and Its Application in Water-Based Drilling Fluid. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 651, Article ID: 129730.
https://doi.org/10.1016/j.colsurfa.2022.129730
[9] Gao, S., Lin, D., Li, A., Deng, L., Dong, A. and Zhang, J. (2025) A Zwitterionic Polymer Filtrate Reducer with Enhanced Anti-Polyelectrolyte Effect for High-Temperature and High-Salinity Conditions. Chemical Engineering Journal, 508, Article ID: 161087.
https://doi.org/10.1016/j.cej.2025.161087
[10] Liu, H., Zhao, K., Wang, Q., Ni, H., Zhang, F., Xue, L., et al. (2025) Study on the Improvement of Temperature Resistance of Starch Drilling Fluid Treatment Agent by Composite Plant Phenols. Processes, 13, Article No. 622.
https://doi.org/10.3390/pr13030622
[11] Ahmed, H.E., Betiha, M.A., El-Dardir, M., et al. (2021) High-Performance Rheology Modifiers and Fluid Loss of Starch-Bentonite System Based Mud Fluids: Experimental and Optimization Study. Egyptian Journal of Chemistry, 64, 1653-1664.
[12] Du, W., Wang, X., Shan, W., Wang, W., Zhang, J. and Chen, G. (2022) Synthesis, Performance and Inhibition Mechanism of Modified Peanut Shell Nanocellulose as Shale Hydration Inhibitor. Polymer Bulletin, 80, 263-277.
https://doi.org/10.1007/s00289-022-04097-2
[13] Khashay, M., Zirak, M., Sheng, J.J., Ganat, T. and Esmaeilnezhad, E. (2025) Elevated Temperature and Pressure Performance of Water Based Drilling Mud with Green Synthesized Zinc Oxide Nanoparticles and Biodegradable Polymer. Scientific Reports, 15, Article No. 11930.
https://doi.org/10.1038/s41598-025-96900-z
[14] Wang, Z., Sun, J., Lv, K., Lu, H., Geng, Y. and Huang, X. (2025) Thermosensitive Core-Shell Polymer Microspheres for Enhanced Wellbore Stability in Deep-Water Water-Based Drilling Fluids. Journal of Molecular Liquids, 418, Article ID: 126690.
https://doi.org/10.1016/j.molliq.2024.126690
[15] Wakeel, S., Aslam, A. and Zhang, J. (2025) Advances in Polymer Nanocomposites for Drilling Fluids: A Review. Materials, 18, Article No. 4809.
https://doi.org/10.3390/ma18204809
[16] Huang, X., Sun, J., Huang, Y., Yan, B., Dong, X., Liu, F., et al. (2021) Laponite: A Promising Nanomaterial to Formulate High-Performance Water-Based Drilling Fluids. Petroleum Science, 18, 579-590.
https://doi.org/10.1007/s12182-020-00516-z
[17] Zhang, B., Wang, Q., Wei, Y., Wei, W., Du, W., Zhang, J., et al. (2022) Preparation and Swelling Inhibition of Mixed Metal Hydroxide to Bentonite Clay. Minerals, 12, Article No. 459.
https://doi.org/10.3390/min12040459
[18] 孙德军. 铝/镁混合金属氢氧化物正电胶体粒子体系的触变性[J]. 化学学报, 2001, 59(2): 163-167.
[19] 孙金声, 杨杰, 戎克生, 等. 水基钻井液用流型调节剂研究进展[J]. 新疆石油天然气, 2023, 19(2): 1-16.
[20] Dong, X., Sun, J., Huang, X., Lv, K., Geng, Y., Liu, F., et al. (2024) Development of Temperature-and Salt-Resistant Viscosifier with Dual Skeleton Structure of Microcrosslinking and Hydrophobic Association Structures and Its Application in Water-Based Drilling Fluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 684, Article ID: 133017.
https://doi.org/10.1016/j.colsurfa.2023.133017
[21] Wang, Q.B., Luo, W.J., Pan, L.F., et al. (2026) Zwitterionic-Hydrophobic Associating Polymer for Enhanced Rheology and Fluid-Loss Control in High-Temperature, High-Salinity Water-Based Drilling Fluids. Petroleum Science, 23, 4065-4081.
https://doi.org/10.1016/j.petsci.2026.03.042
[22] Xie, B., Chen, J., Chen, J., Ma, C., Zhao, L. and Tchameni, A.P. (2023) Novel Thermo-Associating Polymer/Silica Nanocomposite as a Temperature-Resistant Rheology Modifier for Bentonite-Free Water-Based Drilling Fluids. Geoenergy Science and Engineering, 222, Article ID: 211426.
https://doi.org/10.1016/j.geoen.2023.211426
[23] Wandji Djouonkep, L.D., Xie, B., Tao, H., Chen, J., Zhuo, L., Songwe Selabi, N.B., et al. (2024) Thermo-Thickening/Amphoteric Polymer Nanocomposite Incorporating Vinyl-Functionalized Nano-Silica as a Viscosifier for High-Salt and Ultra-High Temperature Water-Based Drilling Fluids. Journal of Molecular Liquids, 404, Article ID: 124866.
https://doi.org/10.1016/j.molliq.2024.124866
[24] Cheng, L., Yang, G., Zhang, S., Zhang, Y., Gao, C., Song, N., et al. (2022) Preparation and Action Mechanism of Temperature Sensitive N-Isopropylacrylamide/Nanosilica Hybrid as Rheological Modifier for Water-Based Drilling Fluid. Journal of Petroleum Science and Engineering, 219, Article ID: 111096.
https://doi.org/10.1016/j.petrol.2022.111096
[25] Cheng, L., Wang, X., Yang, G., Zhang, S., Zhang, Y., Sun, L., et al. (2025) Thermosensitive Polymer/Nanosilica Hybrid as a Multifunctional Additive in Water-Based Drilling Fluid: Rheologicalproperties and Lubrication Performance as Well as Filtration Loss Reduction Capacity. Geoenergy Science and Engineering, 244, Article ID: 213455.
https://doi.org/10.1016/j.geoen.2024.213455
[26] Yang, J., Sun, J., Wang, R., Liu, F., Wang, J., Qu, Y., et al. (2022) Laponite-Polymer Composite as a Rheology Modifier and Filtration Loss Reducer for Water-Based Drilling Fluids at High Temperature. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 655, Article ID: 130261.
https://doi.org/10.1016/j.colsurfa.2022.130261
[27] Yang, J., Wang, R., Sun, J., Wang, J., Liu, L., Qu, Y., et al. (2023) Nanolaponite/Comb Polymer Composite as a Rheological Modifier for Water-Based Drilling Fluids. ACS Applied Nano Materials, 6, 13453-13465.
https://doi.org/10.1021/acsanm.3c02079
[28] Prakash, V., Sharma, N. and Bhattacharya, M. (2021) Effect of Silica Nano Particles on the Rheological and HTHP Filtration Properties of Environment Friendly Additive in Water-Based Drilling Fluid. Journal of Petroleum Exploration and Production Technology, 11, 4253-4267.
https://doi.org/10.1007/s13202-021-01305-z
[29] Smith, S.R., Rafati, R., Sharifi Haddad, A., Cooper, A. and Hamidi, H. (2018) Application of Aluminium Oxide Nanoparticles to Enhance Rheological and Filtration Properties of Water Based Muds at HPHT Conditions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 537, 361-371.
https://doi.org/10.1016/j.colsurfa.2017.10.050
[30] Rezaei, A., Nooripoor, V. and Shahbazi, K. (2020) Applicability of Fe3O4 Nanoparticles for Improving Rheological and Filtration Properties of Bentonite-Water Drilling Fluids in the Presence of Sodium, Calcium, and Magnesium Chlorides. Journal of Petroleum Exploration and Production Technology, 10, 2453-2464.
https://doi.org/10.1007/s13202-020-00920-6
[31] Edalatfar, M., Yazdani, F. and Salehi, M.B. (2021) Synthesis and Identification of ZnTiO3 Nanoparticles as a Rheology Modifier Additive in Water-Based Drilling Mud. Journal of Petroleum Science and Engineering, 201, Article ID: 108415.
https://doi.org/10.1016/j.petrol.2021.108415
[32] Xia, P. and Pan, Y. (2023) Effects of Nanosilica on the Properties of Brine-Base Drilling Fluid. Scientific Reports, 13, Article No. 20462.
https://doi.org/10.1038/s41598-023-47932-w
[33] Talebi Sarokolai, F. and Shiri, Y. (2025) Zwitterionic Nanocomposites Grafted onto Titanium Dioxide Enhanced Water-Based Drilling Fluid for High-Temperature and High-Salinity Deep Resource Development. Scientific Reports, 15, Article No. 44107.
https://doi.org/10.1038/s41598-025-27853-6
[34] Tchameni, A.P., Nagre, R.D., Yin, S., Wang, L., Wang, X., Zhou, S., et al. (2025) A Thermo-Associating Copolymer Integrated with Biogenic Nanosilica as a Novel Viscosifier in Low Solid Drilling Fluids. Petroleum Science, 22, 2884-2904.
https://doi.org/10.1016/j.petsci.2025.04.020
[35] Gao, F., Xu, P., Zhang, H., Wang, H., Zhao, X., Li, X., et al. (2025) Preparation of a Nanomaterial-Polymer Dynamic Cross-Linked Gel Composite and Its Application in Drilling Fluids. Gels, 11, Article No. 614.
https://doi.org/10.3390/gels11080614
[36] Martin, C., Nourian, A., Babaie, M. and Nasr, G.G. (2024) Innovative Drilling Fluid Containing Sand Grafted with a Cationic Surfactant Capable of Drilling High Pressure and High Temperature Geothermal and Petroleum Wells. Geoenergy Science and Engineering, 237, Article ID: 212767.
https://doi.org/10.1016/j.geoen.2024.212767
[37] Zhao, X., Zhang, X., Zhang, H., Geng, T., Yi, W. and Li, H. (2026) Experimental Study on Nano-Silica for Improving Rheological Properties of Water-Based Drilling Fluids in Deepwater Deep Wells. Arabian Journal of Chemistry, 19, Article ID: 11352025.
https://doi.org/10.25259/ajc_1135_2025
[38] Li, J., Ji, Y.X., Ni, X.X., Lv, K., Huang, X. and Sun, J. (2024) A Micro-Crosslinked Amphoteric Hydrophobic Association Copolymer as High Temperature-and Salt-Resistance Fluid Loss Reducer for Water-Based Drilling Fluids. Petroleum Science, 21, 1980-1991.
https://doi.org/10.1016/j.petsci.2024.01.021
[39] Li, J., Sun, J., Lv, K., Ji, Y., Ji, J. and Liu, J. (2022) Nano-Modified Polymer Gels as Temperature-and Salt-Resistant Fluid-Loss Additive for Water-Based Drilling Fluids. Gels, 8, Article No. 547.
https://doi.org/10.3390/gels8090547
[40] Dejtaradon, P., Hamidi, H., Chuks, M.H., Wilkinson, D. and Rafati, R. (2019) Impact of ZnO and CuO Nanoparticles on the Rheological and Filtration Properties of Water-Based Drilling Fluid. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 570, 354-367.
https://doi.org/10.1016/j.colsurfa.2019.03.050
[41] Ospanov, Y.K. and Kudaikulova, G.A. (2025) Synergistic Effects of Graphene Oxide and Nanocellulose on Water-Based Drilling Fluids: Improved Filtration and Shale Stabilization. Polymers, 17, Article No. 949.
https://doi.org/10.3390/polym17070949
[42] Luo, Y., Lin, L., Luo, P., Guo, Y., Xie, S., Wang, M., et al. (2023) Polymer Nanocomposite ADA@SM as a High-Temperature Filtrate Reducer for Water-Based Drilling Fluids and Its Filtration Loss Mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 672, Article ID: 131701.
https://doi.org/10.1016/j.colsurfa.2023.131701
[43] Pang, S., Xuan, Y., Zhu, L. and An, Y. (2025) Zwitterionic Polymer Grafted Nano-SiO2 as Fluid Loss Agent for High Temperature Water-Based Drilling Fluids. Journal of Molecular Liquids, 417, Article ID: 126542.
https://doi.org/10.1016/j.molliq.2024.126542
[44] Jia, X., Liu, N. and Zhao, X. (2025) Optimizing Nanosilica-Enhanced Polymer Synthesis for Drilling Fluids via Response Surface Methodology: Enhanced Fluid Performance Analysis. Journal of Composites Science, 9, Article No. 263.
https://doi.org/10.3390/jcs9060263
[45] Sun, Y.W., Sun, J.S., Lv, K.H., et al. (2026) Enhancing the Performance of High-Temperature, High-Salinity, High-Density Water-Based Drilling Fluid Using a Rheological Modifier with Low Viscosity and High Yield Point Characteristic. Petroleum Science, 23, 4145-4164.
https://doi.org/10.1016/j.petsci.2026.03.027
[46] Tian, W., Wang, Q., Liu, X., Du, W., Zhang, J. and Gang, C. (2022) Investigation of Dioscorea oppositifolia L. as Green Lubricant in Water-Based Drilling Fluids. Green Materials, 10, 169-175.
https://doi.org/10.1680/jgrma.21.00017
[47] Chen, W., Li, J., Yang, H.W., et al. (2026) A Symbolic Regression Method Integrated with Physical Constraints for Predicting Drilling Fluid Shear Stress in a Wide Temperature-Pressure Range. Petroleum Science Bulletin, 11, 879-893.