提高特种玻璃紫外透过率的研究进展
Recent Research on Improving Ultraviolet Transmittance of Special Glass
DOI: 10.12677/MS.2019.94039, PDF,    科研立项经费支持
作者: 肖 荣, 黄程远, 廖维维, 廖秋刚, 李 巍:福建工程学院材料科学与工程学院,福建 福州;赖建雄:福州大学材料科学与工程学院,福建 福州
关键词: 紫外透过率特种玻璃离子特性光学碱度UV Transmittance Special Glass Ionic Characteristics Optical Alkalinity
摘要: 紫外光独特的特性引发了人们对如何提高特种玻璃对紫外光的透过率的研究。由于传统的单晶氟化物和高纯石英玻璃成本高昂且制备工艺复杂,人们一直在尝试研制新型特种玻璃来替代,主要有硅酸盐、硼酸盐、磷酸盐等不同体系。本文系统探讨了离子特性和光学碱度两个重要因素对紫外透射率的影响,同时对改善玻璃结构及掺杂改性来提高特种玻璃紫外透过率的方法进行了分析。
Abstract: The special properties of ultraviolet light attracted the research on how to improve the transmit-tance of special glass to ultraviolet light. Due to the high cost and complicated preparation process of the traditional single-crystal fluoride and high-purity quartz glass, people have been trying to develop new types of special glass to replace them, which mainly including silicate, borate, phos-phate and other different systems. In this paper, the effects of two important factors, ionic charac-teristics and optical alkalinity, on the ultraviolet transmittance are systematically discussed. The methods of improving glass structure and doping modification to improve the ultraviolet trans-mittance of special glass are also analyzed.
文章引用:肖荣, 赖建雄, 黄程远, 廖维维, 廖秋刚, 李巍. 提高特种玻璃紫外透过率的研究进展[J]. 材料科学, 2019, 9(4): 299-303. https://doi.org/10.12677/MS.2019.94039

参考文献

[1] Sackey, S.S., Vowotor, M.K., Owusu, A., et al. (2015) Spectroscopic Study of UV Transparency of Some Materials. Environment and Pollution, 4, 1-17.
[2] Luo, Z., Lu, A., Chen, B., et al. (2011) Effects of SrO/ZnO on Structure and Properties of UV-Transmitting Boropho-Phosphosilicate Glass. Physica B, 406, 4558-4563.
[3] Skuja, L., Hirano, M., Hosono, H., et al. (2005) Defects in Oxide Glasses. Physica Status Solidi, 2, 15-24.
[4] Tran, D.C., Sigel, G.H. and Bendow, J.R.B. (1984) Heavy Metal Fluoride Glasses and Fibers a Review. Journal of Lightwave Technology, 2, 566-586. [Google Scholar] [CrossRef
[5] Karmakar, B., Kundu, P. and Dwivedi, R.N. (2002) UV Transparency and Structure of Fluorophosphate Glasses. Materials Letters, 57, 953-958.
[6] Karmakar, B., Kundu, P. and Dwivedi, R.N. (2001) Effect of Vacuum Dehydroxylation on the UV Transparency and Structure of Metaphosphate Glasses. Materials Letters, 47, 371-375.
[7] Duffy, J.A. and Ingram, M.D. (1976) An Interpretation of Glass Chemistry in Terms of the Optical Basicity Concept. Journal of Non-Crystalline Solids, 21, 373-410. [Google Scholar] [CrossRef
[8] 张洋. 透深紫外光学玻璃[J]. 中国建材, 2017(5): 106-107.
[9] Duffy, J.A. (2001) Ultraviolet Transparency of Glass a Chemical Approach in Terms of Band Theory, Polarisability and Electronegativity. Physics and Chemistry of Glasses, 42, 151-157.
[10] 胡玉叶, 张劼, 赵莉, 等. SiO2-Li2O玻璃结构与紫外透过性能的研究[J]. 材料导报, 2013, 27(s1): 192-194.
[11] 崔乔乔, 丁明烨, 倪亚茹, 等. 锂铝硅磷酸盐玻璃结构与紫外透过性能的关系[J]. 光学技术, 2013, 39(6): 565-570.
[12] Jimenez, J.A. (2017) Ag and Si Codoped Phosphate Glasses Plasmonic Nanocomposites with Enhanced UV Transparency. Journal of the American Ceramic Society, 100, 125-132.
[13] Jimenez, J.A. (2017) Silicon-Induced UV Transparency in Phosphate Glasses and Its Application to the Enhancement of the UV Type B Emission of Gd3+. ACS Applied Materials & Inter-faces, 9, 15599-15604.
[14] Jimenez, J.A. (2016) On the Graphite-Induced UV Transparency in Phosphate Glasses. Optical Materials, 62, 42-46.
[15] Jimenez, J.A., Sendova, M., Fachini, E.R., et al. (2016) Enhanced UV Transparency in Phosphate Glasses via Multi-Wall Carbon Nanotubes. Journal of Materials Chemistry C, 4, 9771-9778.
[16] Chen, G., Baccaro, S., Giorgi, R., et al. (2009) Ultraviolet Transparency and Activator Oxidation State of Ce3+-Doped Phosphate Glasses. Journal of Non-Crystalline Solids, 326-327, 339-342.
[17] 邵冲云, 许文彬, 刘力挽, 等. Al3+/Yb3+/P5+掺杂对石英玻璃紫外透过和紫外激发荧光的影响[J]. 无机材料学报, 2015, 30(12): 1327-1333.