金属有机骨架化合物历史及研究进展
History and Research Progress of Organometallic Skeleton Compounds
DOI: 10.12677/AMC.2020.81001, PDF,   
作者: 杨晨曦：陕西地建土地工程技术研究院有限责任公司，陕西 西安；陕西省土地工程建设集团有限责任公司，陕西 西安 ；自然资源部退化及未利用土地整治工程重点实验室，陕西 西安 ；陕西省土地整治工程技术研究中心，陕西 西安
关键词: 金属有机骨架化合物；配体；合成；Metal-Organic Frameworks； Ligands； Synthesis
摘要: 金属有机骨架化合物(MOFs)因其具有规律性、刚性、弹性、多变性、可设计性等许多性能，使得它成为优良的新型功能材料。本文回顾了MOFs历史，并总结了其合成方法与配体的选择，通过总结不同的合成方法，从而介绍了不同合成方法的优劣性，并总结了不同情况下所使用的方法。
Abstract: Metal-organic frameworks (MOFs) have become excellent porous materials due to their regu-larity, rigidity, elasticity, variability and designability. In this paper, the history of MOFs is re-viewed, and the synthesis methods and ligand selection of MOFs are summarized. By summariz-ing different synthetic methods, the advantages and disadvantages of different synthetic meth-ods are introduced, and the methods used in different situations are summarized.
文章引用：杨晨曦. 金属有机骨架化合物历史及研究进展[J]. 材料化学前沿, 2020, 8(1): 1-4. https://doi.org/10.12677/AMC.2020.81001

参考文献

[1] 王曼清. 金属有机化合物的合成及其应用研究[D]: [硕士学位论文]. 福州: 福州大学, 2015.
[2] Buser, H.J., Schwarzenbach, D., Peter, W., et al. (1977) The Crystal Structure of Prussian Blu: Fe4[Fe(CN)6]3.XH2O. Inorganic Chemistry, 16, 2704-2710.
[Google Scholar] [CrossRef] 
[3] Garçon, M., Bakewell, C., Sackman, G.A., et al. (2019) A Hexagonal Planar Transition-Metal Complex. Nature, 574, 390-393.
[Google Scholar] [CrossRef] [PubMed]
[4] Li, H., Eddaoud, M., O’Keeffe, M., et al. (1999) Design and Synthesis of an Exceptionally Stable and Highly Porous Metal-Organic Framework. Nature, 402, 276-279.
[Google Scholar] [CrossRef] 
[5] Forster, P.M., Thomas, P.M. and Cheetham, A.K. (2002) Biphasic Sol-vothermal Synthesis: A New Approach for Hybrid Inorganic-Organic Materials. Chemistry of Materials, 14, 17-20.
[Google Scholar] [CrossRef] 
[6] Kappe, C.O. (2004) Controlled Microwave Heating in Modern Or-ganic Synthesis. AngewandteChemie International Edition, 43, 6250-6284.
[Google Scholar] [CrossRef] [PubMed]
[7] Khan, N.A., Haque, E. and Jhung, S.H. (2010) Rapid Syntheses of a Metal-Organic Framework Material Cu3(BTC)2(H2O)3 under Microwave: A Quantitative Analysis of Accelerated Syntheses. Physical Chemistry Chemical Physics, 12, 2625-2631.
[Google Scholar] [CrossRef] [PubMed]
[8] Haque, E., Khan, N.A., Park, J.H., et al. (2010) Synthesis of a Met-al-Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study. Chemistry: A European Journal, 16, 1046-1052.
[Google Scholar] [CrossRef] [PubMed]
[9] Hwang, Y.K., Chang, J.S., Park, S.E., et al. (2005) Microwave Fabrication of MFI Zeolite Crystals with a Fibrous Morphology and Their Applications. Angewandte Chemie In-ternational Edition, 44, 556-560.
[Google Scholar] [CrossRef] [PubMed]
[10] Jhung, S.H., Chang, J.S., Kim, D.S., et al. (2004) Effects of Silica on the Synthesis of AFI Molecular Sieve in Acid and Base Conditions under Microwave Irradiation. Mi-croporous and Mesoporous Materials, 71, 135-142.
[Google Scholar] [CrossRef]