柴油–天然气–氢气三燃料化学反应机理研究
Study on the Chemical Reaction Mechanism of Diesel-Natural Gas-Hydrogen Three Fuels
摘要: 本文为了探究RCCI三燃料(柴油–天然气–氢气)燃烧领域中，特定两组化学反应机理对于真实燃烧情况的预测合理性，对三燃料燃烧化学反应机理进行数值模拟研究，对比了不同机理对于正庚烷，天然气，氢气点火延迟时间和层流火焰速度的模拟结果，发现143-746机理在对正庚烷、氢气的层流火焰速度和对天然气、正庚烷的点火延迟时间方面的模拟效果更好，76-464机理在天然气层流火焰速度方面优于143-746机理，对氢气点火延迟时间的模拟方面二者与实验值的偏差程度类似，区别并不明显。综合考虑认为143-746机理更适合应用在RCCI三燃料燃烧的相关研究中。
Abstract: In order to explore the rationality of the prediction of the real combustion situation of specific two groups of chemical reaction mechanisms in the field of RCCI three-fuel (diesel-natural gas-hydrogen) combustion, this paper conducts numerical simulation research on the chemical reaction mecha-nism of three-fuel combustion, compares the simulation results of different mechanisms for n-heptane, natural gas and hydrogen ignition delay time and laminar flow flame velocity, and finds that the 143-746 mechanism has a better simulation effect in the laminar flow flame velocity of n-heptane and hydrogen and the ignition delay time of natural gas and n-heptane. The 76-464 mechanism is superior to the 143-746 mechanism in terms of natural gas laminar flow flame veloc-ity, and the simulation of hydrogen ignition delay time has a similar degree of deviation from the experimental value, and the difference is not obvious. Based on comprehensive consideration, it is believed that the mechanism of 143-746 is more suitable for the research of RCCI three-fuel com-bustion.
文章引用：秦文瑾, 景瑞雄, 王家富, 严俊. 柴油–天然气–氢气三燃料化学反应机理研究[J]. 建模与仿真, 2023, 12(1): 150-158. https://doi.org/10.12677/MOS.2023.121015

参考文献

[1] 张保良. 车用替代燃料及发展研究[J]. 中原工学院学报, 2021, 32(4): 16-21.
[2] De Robbio, R., Cameretti, M.C. and Tuccillo, R. (2020) Ignition and Combustion Modelling in a Dual Fuel Diesel Engine. Propulsion and Power Research, 9, 116-131. [Google Scholar] [CrossRef] 
[3] Sánchez, A.L. and Williams, F.A. (2014) Recent Advances in Understanding of Flammability Characteristics of Hydrogen. Progress in Energy and Combustion Science, 41, 1-55. [Google Scholar] [CrossRef] 
[4] Li, H.L., Gatts, T., Liu, S., et al. (2018) An Experimental Investigation on the Combustion Process of a Simulated Turbocharged Spark Ignition Natural Gas Engine Operated on Stoichiometric Mixture. Journal of Engineering for Gas Turbines and Power, 140, Article ID: 091504. [Google Scholar] [CrossRef] 
[5] Dhole, A., Bhattacharya, A., de Kloe, R., et al. (2022) Orientation Dependent In-terface Morphology and Oxide Stability in a Commercial Niobium Alloy: Explaining Experimental Results with Density Func-tional Theory. Acta Materialia, 229, Article ID: 117793. [Google Scholar] [CrossRef] 
[6] 张韦, 常少月, 陈朝辉, 陈贵升. DNH三燃料简化化学动力学机理的构建与验证[J]. 燃烧科学与技术, 2017, 23(4): 331-338.
[7] Huang, H.Z., Lv, D.L., Zhu, J.Z., et al. (2019) Development of a New Reduced Diesel/Natural Gas Mechanism for Dual-Fuel Engine Combustion and Emission Prediction. Fuel, 236, 30-42. [Google Scholar] [CrossRef] 
[8] Rahimi, A., Fatehifar, E. and Khoshbakhti Saray, R. (2010) Development of an Optimized Chemical Kinetic Mechanism for Homogeneous Charge Compression Ignition Combustion of a Fuel Blend of n-Heptane and Natural Gas Using a Genetic Algorithm. Journal of Automobile Engineering, 224, 1141-1159. [Google Scholar] [CrossRef] 
[9] 张鹏, 洪延姬, 段立伟, 马第, 张广兆. 等离子体对碳氢燃料点火延迟时间影响的研究进展[J]. 机电产品开发与创新, 2012, 25(4): 1-3.
[10] 刘耀东. 基础燃料(PRF)及汽油表征燃料(TRF)化学反应动力学骨架模型的研究[D]: [博士学位论文]. 大连: 大连理工大学, 2013.
[11] Senecal, P.K., Pomraning, E. and Richards, K.J. (2003) Multi-Dimensional Modeling of Direct-Injection Diesel Spray Liquid Length and Flame Lift-off Length Using CFD and Parallel Detailed Chemistry. SAE Technical Paper, SAE International, Warrendale. [Google Scholar] [CrossRef] 
[12] Shen, H.-P., Steinberg, J., Vanderover, J. and Oehlschlaeger, W.A. (2009) A Shock Tube Study of the Ignition of n-Heptane, n-Decane, n-Dodecane, and n-Tetradecane at Elevated Pressures. Energy & Fuels, 23, 2482-2489. [Google Scholar] [CrossRef] 
[13] Zhang, Y.J., Huang, Z.H., Wei, L.J., Zhang, J.X. and Law, C.K. (2012) Experi-mental and Modeling Study on Ignition Delays of Lean Mixtures of Methane, Hydrogen, Oxygen, and Argon At Elevated Pressures. Combustion & Flame, 159, 918-931. [Google Scholar] [CrossRef] 
[14] Van Lipzig, J.P.J., Nilsson, E.J.K., De Goey, L.P.H. and Konnov, A.A. (2011) Laminar Burning Velocities of n-Hep- tane, Iso-Octane, Ethanol and Their Binary and Tertiary Mixtures. Fuel, 90, 2773-2781. [Google Scholar] [CrossRef] 
[15] Rozenchan, G., Zhu, D.L., Law, C.K. and Tse, S.D. (2002) Outward Propagation, Burning Velocities, and Chemical Effects of Methane Flames up to 60 ATM. Proceedings of the Combustion In-stitute, 29, 1461-1470. [Google Scholar] [CrossRef] 
[16] Dong, C., Zhou, Q.L., Zhang, Q.X., et al. (2009) Experimental Study on the Laminar Flame Speed of Hydrogen/Na- tural Gas/Air Mixtures. Frontiers of Chemical Engineering in China, 88, 1858-1863. [Google Scholar] [CrossRef] 

为你推荐