用于有毒染料检测的柔性SERS基底制备及其增强效应研究
Preparation of Flexi-ble SERS Substrates for Toxic Dye Detection and Its Enhancement Effect
摘要: 本文利用化学还原法和紫外法两种方法制备了柔性纳米银–细菌纳米纤维素膜，通过对罗丹明6G (R6G)的检测，比较其表面增强拉曼光谱性能。实验结果表明化学还原法比紫外法的效果好，利用化学还原法制备的纳米银–细菌纳米纤维素膜具有较强的SERS效应。柔性SERS基底在有毒染料检测方面具有巨大的潜力。
Abstract: In this study, flexible nanosilver-bacterial nanocellulose membranes were prepared by both chemical reduction and UV methods, and their surface-enhanced Raman spectro-scopic properties were compared by the detection of rhodamine 6G (R6G). The experimental results showed that the chemical reduction method was more effective than the UV method, and the na-nosilver-bacterial nanocellulose membranes prepared using the chemical reduction method had a strong SERS effect. Flexible SERS substrates have great potential for toxic dye detection.
文章引用：蒙雪, 何聪颖, 黄国现, 苏检德, 黄富城, 李燕玲, 刘凯依, 邓天霞, 宋树祥, 刘林生. 用于有毒染料检测的柔性SERS基底制备及其增强效应研究[J]. 传感器技术与应用, 2023, 11(3): 239-246. https://doi.org/10.12677/JSTA.2023.113026

参考文献

[1] Li, M., Cushing, S.K., Zhou, G. and Wu, N. (2020) Molecular Hot Spots in Surface-Enhanced Raman Scattering. Na-noscale, 12, 22036-22041. [Google Scholar] [CrossRef] 
[2] 杨玉东, 刘公召, 徐菁华, 杨林梅, 李冬至. 金纳米棒: 合成、修饰、自组装、SERS及生物医学应用[J]. 中国科学: 化学, 2015, 45(6): 581-596.
[3] 刘文婧, 杜晶晶, 景传勇. 表面增强拉曼光谱技术应用于环境污染物检测的研究进展[J]. 环境化学, 2014, 33(2): 217-228.
[4] Yaseen, T., Pu, H. and Sun, D.-W. (2018) Functionalization Techniques for Improving SERS Substrates and Their Applications in Food Safety Evaluation: A Review of Recent Research Trends. Trends in Food Science & Technology, 72, 162-174. [Google Scholar] [CrossRef] 
[5] 徐娅, 边捷, 张伟华. 局域表面等离激元纳米光学传感器的原理与进展[J]. 激光与光电子学进展, 2019, 56(20): 101-112.
[6] Zhang, S., Xu, J., Liu, Z., Huang, Y. and Jiang, S. (2022) Facile, Ecofriendly, and Efficient Preparation of Flexible Gold Nanoparticles@bacterial Nanocellulose Surface-Enhanced Raman Scattering Sensors by Magnetron Sputtering for Trace Detection of Hazardous Materials. ACS Sustainable Chemistry & Engineering, 10, 13059-13069. [Google Scholar] [CrossRef] 
[7] 王稳, 陶霞芳, 吴赟炎, 赵南, 程晓农, 杨娟, 周亚洲. 三明治结构纳米银/氧化石墨烯基底的制备及SERS性能[J]. 高等学校化学学报, 2019, 40(4): 667-675.
[8] Rao, G., Jian, X., Lv, W., et al. (2017) A Highly-Efficient Route to Three-Dimensional Nanoporous Copper Leaves with High Surface Enhanced Raman Scattering Properties. Chemical Engineering Journal, 321, 394-400. [Google Scholar] [CrossRef] 
[9] Mohanty, A.K., Vivekanandhan, S., Pin, J.M. and Misra, M. (2018) Composites from Renewable and Sustainable Resources: Challenges and Innovations. Science, 362, 536-542. [Google Scholar] [CrossRef] [PubMed]
[10] 叶代勇, 黄洪, 傅和青, 陈焕钦. 纤维素化学研究进展[J]. 化工学报, 2006, 57(8): 1782-1791.
[11] Liu, D.Y., Sui, G.X. and Bhattacharyya, D. (2014) Synthesis and Characterisation of Nanocellulose-Based Polyaniline Conducting Films. Composites Science and Technology, 99, 31-36. [Google Scholar] [CrossRef] 
[12] Klemm, D., Cranston, E.D., Fischer, D., et al. (2018) Nanocellulose as a Natural Source for Groundbreaking Applications in Materials Science: Today’s State. Materials To-day, 21, 720-748. [Google Scholar] [CrossRef] 
[13] Raffi, M., Rumaiz, A.K., Hasan, M.M. and Ismat Shah, S. (2007) Studies of the Growth Parameters for Silver Nanoparticle Synthesis by Inert Gas Condensation. Journal of Materials Research, 22, 3378-3384. [Google Scholar] [CrossRef] 
[14] Zikmund, T., Bulíř, J., Novotný, M., et al. (2023) Silver Nanoparti-cles for Fluorescent Nanocomposites by High- Pressure Magnetron Sputtering. Materials, 16, Article No. 1591. [Google Scholar] [CrossRef] [PubMed]
[15] 晋传贵, 姜山, 陈刚. 化学还原法制备银纳米颗粒[J]. 安徽工业大学学报(自然科学版), 2008, 25(2): 120-122.
[16] Chen, W. and Zhang, J. (2003) Ag Nanoparticles Hosted in Mono-lithic Mesoporous Silica by Thermal Decomposition Method. Scripta Materialia, 49, 321-325. [Google Scholar] [CrossRef] 
[17] Liu, F., Zhang, X., Fang, X. and Lin, Y. (2016) Plasmonic Microcavity Using Photo-Reduced Silver Nanoparticles and Light-Emitting Polymer. Optics Express, 24, 1747-1757. [Google Scholar] [CrossRef] 
[18] 廖学红, 朱俊杰, 赵小宁, 陈洪渊. 纳米银的电化学合成[J]. 高等学校化学学报, 2000(12): 1837-1839.
[19] Wang, W., Yu, Z., Alsammarraie, F.K., et al. (2020) Properties and Anti-microbial Activity of Polyvinyl Alcohol-Modi- fied Bacterial Nanocellulose Packaging Films Incorporated with Silver Nanoparticles. Food Hydrocolloids, 100, Article ID: 105411. [Google Scholar] [CrossRef] 
[20] Lee, P.C. and Meisel, D. (1982) Adsorption and Sur-face-Enhanced Raman of Dyes on Silver and Gold Sols. The Journal of Physical Chemistry, 86, 3391-3395. [Google Scholar] [CrossRef] 
[21] Cao, Y., Liang, P., Dong, Q., Wang, D., Zhang, D., Tang, L., Wang, L., Jin, S., Ni, D. and Yu, Z. (2019) Facile Reduction Method Synthesis of Defective MoO2–x Nanospheres Used for SERS Detection with High Chemical Enhancement. Analytical Chemistry, 91, 8683-8690. [Google Scholar] [CrossRef] [PubMed]

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