基本情况
陈自立，博士，教授，博士生导师，中国人民大学化学系教授。
研究领域
金催化反应方法学及合成应用研究，手性三唑配合物的合成及应用
教育背景
2003 年至2004年 博士后，美国依利洛伊州州立大学芝加哥分校药学院
2002年至2003年 博士后，美国乔治敦大学药学院
1996年至2002年 博士，中国科学院上海有机化研究所
1988年至1992年 学士，武汉大学化学系
工作经历
2005年至今 教授，中国人民大学化学系
2005年至2015年 副教授，中国人民大学化学系
1992年至1996年 技术员，天津碱厂
论文发表
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“Highly N(2)
-Selective Coupling of 1,2,3-Triazoles with Indole and Pyrrole.” Wen, J.; Zhu, L.; Bi, Q.; Shen, Z.; Li, X.;
Li, X.; Wang, Z.; Chen, Z. * Chem. Eur.
J. 2014, 20, 974-978
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“Gold Catalyzed
Enantioselective Intermolecular [3+2] Dipolar Cycloaddition of N-allenyl amides
with Nitrones” Li, G.-H.; Zhou, W;
X.-X.; Li, Bi, Q.-W.; Wang, Z.; Zhao, Z.-G.; Hu, W.-X. *; Chen, Z. * Chem.
Comm. 2013, 49, 4770-4772
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“Gold catalyzed
[3+2] cycloaddition of N-allenyl amides with azomethine imines” Zhou, W; Li,
X.-X.; Li, G.-H.; Wu, Y. *; Chen, Z. * Chem.
Comm. 2013, 49, 3552-3554
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“Azepine Synthesis
from Alkyl Azide and Propargylic Ester via Gold Catalysis”Liu, H.; Li, X.;
Chen, Z.*; Hu, W.-X. * J. Org. Chem.,
2012, 77, 5184
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“Formal
Intermolecular [2+2] Cycloaddition Reaction of Alleneamides with Alkenes via
Gold Catalysis” Li, X.-X.; Zhu, L.-L.;
Zhou, W.; Chen, Z.* Org. Lett., 2012, 14,
436
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“Divergent Synthetic
Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via
Gold(I) Catalysis or Zinc(II) Mediation” Zhu, L.-L.; Li, X.-X.; Zhou, W.; Li,
X.; Chen, Z.* J. Org. Chem., 2011, 76,
8814
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“Base-Catalyzed
Cascade 1,3-H Shift/Cyclization Reaction to Construct Polyaromatic Furans” Wang, Y.-H.; Liu, H.; Zhu, L.-L.; Li, X.-X.;
Chen, Z.* Adv. Synth. & Cata., 2011,
353, 707. (Highlighted by SYNFACTS, S004711SF)
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“Gold Catalyzed
Carbocyclization of Dienyl Acetates to Construct Mutifunctionalized 3-Vinyl
Cyclohexanol Derivatives “ Zhu,
L.-L.; Wang, Y.-H.; Zhang, Y.-X.; Li, X.-X.; Liu, H.; Chen, Z.* J. Org. Chem., 2011, 76, 441
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“Gold Catalyzed Diastereoselective Cascade
Allylation/Enyne Cycloisomerization to Construct Densely Functionalized Oxygen
Hetereocycles” Chen, Z.;* Zhang, Y.-X.; Wang, Y.-H.; Zhu, L.-L.; Liu, H.; Li,
X.-X.; Guo, L.* Org. Lett., 2010, 12,
3468. (Highlighted by Organic Chemistry Portal May 11, 2011)
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“Diastereoselective g-vinyl butyrolactone synthesis via gold catalyzed
cyclization of allylic acetate” Wang, Y.-H.; Zhu, L.-L.; Zhang, Y.-X.; Chen,
Z.* Chem. Comm., 2010, 46, 577
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“Controlled
Consecutive Nucleophilic Addition to Construct 1-alkynyl Substituted 1,3-diols
Compounds” Liu, J.; Wang, Y.-H.; An, Y.;
Jiang, H.-Y.; Chen, Z.* Chem. Eur. J.,
2008, 14, 9131
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“Highly
Enantioselective Alkynylation of a-Keto Ester: An
Efficient Method for Constructing a Chiral Tertiary Carbon Center” Jiang, B.*;
Chen, Z.; Tang, X. Org. Lett., 2002, 4; 3451
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“Zn(ODf)2:
preparation and application in asymmetric alkynylation of aldehydes” Chen, Z.;
Xiong, W.; Jiang, B.* Chem. Commun., 2002, 2098
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“Highly
enantioselective alkynylation of aldehydes catalyzed by a readily available
chiral amino alcohol-based ligand” Jiang, B.*; Chen, Z.; Xiong, W. Chem. Commun., 2002, 1524