硬脂酸改性NiO-TiO2薄膜的摩擦学性能
Tribological Performance of Chemical Modification of NiO-TiO2 Films by Stearic Acid
DOI: 10.12677/AMC.2015.31002, PDF, HTML, XML, 下载: 2,889  浏览: 8,880 
作者: 王艳艳, 董志伟, 万勇:青岛理工大学机械工程学院,山东 青岛;高建国:山东出入境检验检疫局检验检疫技术中心,山东 青岛
关键词: NiO-TiO2硬脂酸溶胶–凝胶自组装摩擦学性能NiO-TiO2 Stearic Acid Sol-Gel Self Assembled Tribological Performance
摘要: 利用溶胶–凝胶技术结合自组装技术在45#钢表面制备了具有优异减摩耐磨性能的有机–无机复合薄膜。首先采用溶胶–凝胶技术在钢基底上制备NiO-TiO2薄膜,然后再用自组装技术在薄膜表面沉积硬脂酸分子获得有机–无机复合薄膜。利用接触角测量仪和X射线粉末衍射仪研究了薄膜的润湿性和晶体结构,用微纳摩擦磨损试验机研究了薄膜在干摩擦条件下与轴承钢球往复滑动的摩擦学性能。结果发现,经硬脂酸改性后得到的双层薄膜呈现高疏水状态,对水接触角达135°,具有优异的摩擦学性能。
Abstract:  The inorganic-organic composite films with friction reduction and wear resistance were fabricated on 45# steel using sol-gel technology combined with self assembled technology. The thin films of NiO-TiO2 were firstly prepared on steel via a sol-gel method. The stearic acid was then deposited on the NiO-TiO2 films to obtain an organic-inorganic composite film. The contact angle measurements and X-ray diffraction were used to investigate the films’ wetting behavior and crystalline structure, respectively. Their tribological performance was evaluated by a micro tribotester. The results indicate that the composite film shows high hydrophobicity with a water contact angle of 135˚ and good friction-reducing performance.
文章引用:王艳艳, 高建国, 董志伟, 万勇. 硬脂酸改性NiO-TiO2薄膜的摩擦学性能[J]. 材料化学前沿, 2015, 3(1): 7-12. http://dx.doi.org/10.12677/AMC.2015.31002

参考文献

[1] Mayer, T.M., Elam, J.W., George, S.M., et al. (2003) Atomic-layer deposition of wear-resistant coatings for micro-electromechanical devices. Applied Physics Letters, 82, 2883-2885.
[2] Niesen, T.P. and De Guire, M.R. (2001) Review: Deposition of ceramic thin films at low temperatures from aqueous solutions. Journal of Electroceramics, 6, 169-207.
[3] 刘维民, 陈云霞, 李斌 (2003) 溶胶–凝胶法陶瓷超薄膜的制备及其摩擦学研究进展. 摩擦学学报, 23, 162-167.
[4] Zhang, W., Liu, W., Li, B., et al. (2002) Characterization and tribological investigation of sol-gel titania and doped titania thin films. Journal of the American Ceramic Society, 85, 1770-1776
[5] Jia, Q., Zhang, Y., Wu, Z., et al. (2007) Tribological properties of anatase TiO2 sol-gel films controlled by mutually soluble dopants. Tribology Letters, 26,19-24.
[6] Taylor, D.J., Fleig, P.F., Schwab, S.T., et al. (1999) Sol-gel derived nanostructured oxide lubricant coatings. Surface and Coatings Technology, 120-121, 465-469.
[7] Wan, Y., Xu, Z., Chao, W., et al. (2013) Sol-gel derived nickel-doped TiO2 films as wear protection coatings. Journal of Experimental Nanoscience, 8, 782-787.
[8] 吴炬, 程先华, 白涛, 等 (2005) γ-甲基丙烯酰氧丙基三甲氧基硅烷自组装膜的制备及其摩擦学性能. 摩擦学学报, 25, 117-120.
[9] 彭倚天, 胡元中, 王慧 (2006) 氨基表面自组装膜成膜及摩擦性能研究. 润滑与密封, 7, 28-30.
[10] 张丙伍, 苏中兴, 张俊彦 (2007) 硅表面自组装双层膜制备及其摩擦磨损性能研究. 摩擦学学报, 27, 199-202.
[11] 杨生荣, 任嗣利, 张俊彦, 等 (2001) 自组装单分子膜的结构及其自组装机理. 高等学校化学学报, 22, 470-476.
[12] Raman, A., Quinones, R., Barriger, L., et al. (2010) Understanding organic film behavior on alloy and metal oxides. Langmuir, 26, 1747-1754.
[13] Raman, A. and Gawalt, E.S. (2007) Self-assembled monolayers of alkanoic acids on the native oxide surface of SS316L by solution deposition. Langmuir, 23, 2284-2288.