基于碳纳米管–碳纤维复合材料电磁兼容性能的研究
Carbon Nanotube Carbon Fiber Composites Study on the Performance of EMC
DOI: 10.12677/MS.2018.86077, PDF,    科研立项经费支持
作者: 刘 艳, 王富强, 刘 鹏, 张建东, 赵小文, 苏青林, 王东红:中国电子科技集团公司第三十三研究所,山西 太原
关键词: 碳纤维复合材料电磁兼容吸波性能碳纳米管Carbon Fiber Composite Materials Electromagnetic Compatibility Microwave Absorbing Properties Carbon Nanotubes
摘要: 以T700碳纤维为增强材料,环氧树脂为基体材料,制备了碳纤维复合材料电磁屏蔽体,将碳纳米管分散于环氧树脂中制得碳纳米管/环氧树脂吸波剂,把制得吸波剂喷涂到碳纤维电磁屏蔽体界面上,制得碳纳米管–碳纤维复合材料,该复合材料具有电磁兼容的性能,之后研究了它的吸波性能、力学性能、屏蔽性能以及微观形貌等。结果表明:通过控制碳纳米管/环氧树脂的比例、碳纤维的厚度可获得良好的吸波性能、力学性能、屏蔽性能的碳纳米管–碳纤维复合材料,以期实现复合材料的电磁兼容性。当碳纳米管/环氧树脂 = 6:100,碳纤维厚度为2 mm时(碳纤维布每层为0.25 mm)时,复合材料在8~12 GHz范围内,反射率 ≤ −10 dB,峰值−16.2 dB (9.98 GHz)。拉伸强度878 MPa,屏蔽效能50~70 dB (100 kHz~18 GHz)。
Abstract: The electromagnetic shielding body of carbon fiber composites was prepared by using T700 carbon fiber as reinforced material and epoxy resin as matrix material. Carbon nanotubes/epoxy resin absorbents were prepared by dispersing carbon nanotubes in epoxy resin. A carbon fiber composite material was prepared by spraying the absorbing agent on the interface of carbon fiber electromagnetic shielding. The absorbing properties, mechanical properties, shielding properties and micro morphology of the composite were studied. The results show that carbon nano-tube/carbon fiber composites with good absorbing properties, mechanical properties and shielding properties can be obtained by controlling the ratio of carbon nanotube and epoxy resin, the electromagnetic compatibility of the composites can be achieved by the carbon fiber composites. When carbon nanotube/epoxy resin = 6:100, carbon fiber thickness is 2 mm (0.25 mm per layer of carbon fiber cloth), the composite material is within the range of 8~12 GHz, the reflectance is less than −10 dB, and the peak value is −16.2 dB (9.98 GHz). The tensile strength is 878 MPa and the shielding effectiveness is 75~112 dB (100 kHz~18 GHz).
文章引用:刘艳, 王富强, 刘鹏, 张建东, 赵小文, 苏青林, 王东红. 基于碳纳米管–碳纤维复合材料电磁兼容性能的研究[J]. 材料科学, 2018, 8(6): 650-656. https://doi.org/10.12677/MS.2018.86077

参考文献

[1] Kim, M.S., Kim, H.K. and Byun, S.W. (2002) PET Fabric/Polyrrole Composite with High Electrical Conductivity for EMI Shielding. Synthetic Metals, 126, 233-239.
[Google Scholar] [CrossRef
[2] 陈平, 陈辉, 等. 碳纤维复合材料发动机壳体用韧性环氧树脂基体的研究[J]. 复合材料学报, 2002, 19(2): 24 -27.
[3] 何芳, 万怡灶, 黄远, 李浩, 王玉林. ABS/镀镍碳纤维复合材料电磁屏蔽特性研究[J]. 工程塑料应用, 2007, 35(7): 21-24.
[4] Cedeño, A.J. and Vázquez-Torres H. (2005) Kinetic Study of the Effect of Poly(Phenyl Sulfone) on the Curing of an Epoxy/Amine Resin by Conventional and by Temperature Modulated Differential Scanning Calorimetry. Polymer International, 54, 1141 -1152.
[5] Ebbesen, T.W., Lezec, H.J., Hiura, H., et al. (1996) Electrical Conductivity of Individual Carbon. Nature, 382, 54-56.
[Google Scholar] [CrossRef
[6] 曹茂盛, 高正娟, 朱静. CNTs/Polyester复合材料的微波吸收特性研究[J]. 材料工程, 2003(2): 34-36.
[7] 何芳, 万怡灶, 黄远, 李皓, 王玉林. ABS/镀镍碳纤维复合材料电磁屏蔽特性研究[J]. 工程塑料应用, 2007, 35(5): 21-24.
[8] Falvo, M.R., Clary, G. and Helser, A. (1999) Nanomanipulation Experiments Exploring Fricational and Mechanical Properties of Carbon Nanotubes. Microscopy and Microanalysis, 4, 504.
[Google Scholar] [CrossRef
[9] 张增富, 罗国华, 范壮军. 不同结构碳纳米管的电磁波吸收性能研究[J]. 物理化学学报, 2006, 22(3): 296-300.
[10] Zhang, Y.F., Qi, L., Liu, H. and He, J. (2008) Effect of Interface Strength on Macro Toughness of Fiber Reinforce Composite. Acta Scientiarum Naturalium Universitatis Sunyatseni: Natural Science, 47, 139-143.
[11] 贺福, 王茂章. 碳纤维及复合材料[M]. 北京: 科学出版社, 1995: 289.
[12] 靳武刚, 高建军, 等. 碳纤维复合材料弯曲撑杆成型工艺技术[J]. 电子机械工程, 2003, 19(3): 62-63.
[13] 汝强, 胡社军, 等. 电磁屏蔽理论及屏蔽材料的制备[J]. 包装工程, 2004, 25(5): 21-23.