物理化学进展  >> Vol. 2 No. 3 (August 2013)

果葡糖浆中5-HMF生成影响因素及其去除方法
Influencing Factors and Removing Method of 5-Hydroxymethylfurfural (5-HMF) Generated in High Fructose Corn Syrup

DOI: 10.12677/JAPC.2013.23005, PDF, HTML, XML, 下载: 2,906  浏览: 9,429 

作者: 张健, 孙学谦*, 崔强, 李秋红, 李伟, 王一

关键词: 果葡糖浆5-羟甲基糠醛颗粒活性炭High Fructose Corn Syrup; 5-Hydroxymethylfurfural; Granular Activated Carbons

摘要: 5-羟甲基糠醛(HMF)是在果葡糖浆生产过程中可能产生的一种物质,会对产品的口感风味和人身健康带来一定的影响。本论文通过单因素实验和正交实验设计,对影响果葡糖浆中HMF产生的影响因素进行了研究。实验表明:温度越高HMF越易产生;pH控制在4~5 HMF产生较少,酸性较强容易产生HMF;干物浓度较高时(>70%),HMF产生的速度较快;操作时间与HMF的产生量成正比关系。正交实验显示,各个影响因素中对HMF产生的影响:温度 > 时间 > 干物浓度 > pH。本论文还对颗粒活性炭去除HMF的方法进行了简单介绍和研究,为公司生产工艺的控制提供了必要的依据。 5-Hydroxymethylfurfural (HMF) is a substance generated in the producing process of high fructose corn syrup, which is harmful to the flavor of products and human healthy. Single factor experiment and orthogonal experi- ment design were adopted to investigate the factors influencing the generation of 5-HMF. The results indicated that 5-HMF increases as the temperature rises. 5-HMF produces less at pH 4 - 5. The stronger acidity of the syrup leads to generate more 5-HMF. The 5-HMF increases faster at higher concentrations (DS > 70%). The reaction time is propor- tional to 5-HMF generation. Orthogonal experiments showed that the influencing effects of factor were followed as: temperature > time > concentrations > pH value. Moreover, the removing method of 5-HMF by using granular acti- vated carbons was also studied in the work. The results might be very meaningful to provide evidence for process con- trol of high fructose corn syrup.

文章引用: 张健, 孙学谦, 崔强, 李秋红, 李伟, 王一. 果葡糖浆中5-HMF生成影响因素及其去除方法[J]. 物理化学进展, 2013, 2(3): 27-32. http://dx.doi.org/10.12677/JAPC.2013.23005

参考文献

[1] 郭峰, 罗建勇, 朱晓立. 果葡糖浆中5-羟甲基糠醛的检测方法研究进展[J]. 农业基础科学, 2010, 11: 20-22.
[2] 杨海军. 前景看好的甜味剂–果葡糖浆[J]. 发酵科技通讯, 2006, 35(4): 32-35.
[3] J. A. Miller. Recent studies on the metabolic activation of che- mical carcinogens. Cancer Research, 1994, 54(7): 1879-1881.
[4] C. Janzowshi, V. Glaab, E. Sammimi, et al. 5-Hydroxymethyl furfural: Assessment of mutagenicity, DNA-damaging potential and reactivity towards cellular glutathione. Food Chemical Toxi- cology, 2002, 38(9): 801-809.
[5] 吴立军. 天然药物化学[M]. 北京: 人民卫生出版社, 2004: 73-74.
[6] 周福富, 廖爱国, 刘风景等. 不同因素对5-羟甲基糠醛含量的影响[J]. 中国药业, 2008, 17(19): 44-45.
[7] 梁振福, 冯世俊, 王化河等. 温度和时间对10-葡萄糖注射液中5-羟甲基糠醛含量的影响[J]. 开封医专学报, 1995, 14(3): 184-186.
[8] 王长虹, 金士朗. 活性炭去除含糖输液中的5-羟甲基呋喃甲醛的实验研究[J]. 新疆医学院学报, 1990, 13(4): 266-269.
[9] GB26762-2011. 结晶果糖、固体果葡糖[S]. 北京: 国家质量监督检验检疫总局, 2011.
[10] F. S. Asghari, H. Yoshida. Kinetics of the decomposition of fruc- tose catalyzed by hydrochloric acid in subcritical water: Forma- tion of 5-hydroxymethylfurfural, levulinic, and formic acids. In- dustrial and Engineering Chemistry Research, 2007, 46(23): 7703-7710.
[11] 聂小娃, 刘新, 刘民等. 果糖在酸性环境中脱水制备5-羟甲基糠醛的理论研究[J]. 石油学报, 2010, 26(1): 73-81.
[12] 张玉玉, 宋弋, 李全宏. 食品中糠醛和5-羟甲基糠醛的产生机理、含量检测及安全性评价研究进展[J]. 食品科学, 2012, 33(5): 275-280.
[13] E. Capuano, A. Ferrigno, I. Acampa, et al. Effect of flour type on Maillard reaction and acrylamide formation during toasting of bread crisp model systems and mitigation strategies. Food Re- search International, 2009, 42(9): 1295-1302.