Fe79Zr8W1B12合金的微观结构及热性能研究
Microstructure and Thermal Property of Fe79Zr8W1B12 Alloy
DOI: 10.12677/JAPC.2015.42003, PDF, HTML, XML, 下载: 2,384  浏览: 8,462  科研立项经费支持
作者: 杨玉蓉, 刘 立, 闫国民, 皮艳梅:黑河学院物理化学系,黑龙江 黑河
关键词: 非晶微观结构热性能Amorphous Microstructure Thermal Property
摘要: 采用熔体快淬法制备Fe79Zr8W1B12合金非晶薄带,在不同退火温度下对其进行热处理。结合差热分析仪(DTA),X射线衍射仪(XRD)和透射电镜(TEM)等测试技术对Fe79Zr8W1B12合金的热性能和微观结构进行研究。结果表明:Fe79Zr8W1B12合金的晶化过程为非晶→剩余非晶 + α-Fe + α-Mn型→α-Fe + Fe3Zr + ZrFe2 + BFe。由于α-Fe和α-Mn型相具有不同的形核速率导致激活能被划分为两个区间。
Abstract: Fe79Zr8W1B12 amorphous alloy was prepared by melt-spinning and annealed at different temper-atures. The thermal property and microstructures were investigated by differential thermal anal-ysis (DTA), X-ray diffraction (XRD) and transmission electron microscope (TEM). The crystallization progress of Fe79Zr8W1B12 alloy is as follows: amorphous → residual amorphous + α-Fe + α-Mn type → α-Fe + Fe3Zr + ZrFe2 + BFe. The activation is divided into two intervals because the α-Fe and α-Mn type phases have different nucleation rates.
文章引用:杨玉蓉, 刘立, 闫国民, 皮艳梅. Fe79Zr8W1B12合金的微观结构及热性能研究[J]. 物理化学进展, 2015, 4(2): 19-23. http://dx.doi.org/10.12677/JAPC.2015.42003

参考文献

[1] 张志, 李建中, 郭金柱 (2009) FeCuNbSiB非晶合金的纳米晶化及其软磁性能. 铸造技术, 3, 333-336.
[2] 姜少宁, 雷建民, 张敏刚, 贾明武 (2009) 铁基非晶软磁合金的制备及磁性能研究. 电子元件与材料, 7, 30-32.
[3] 曹玲飞, 汪明朴, 谢丹, 郭明星, 徐根应 (2005) 机械合金化制备FeMB纳米晶软磁材料的研究. 材料导报, IV5, 20-26.
[4] 李宇明, 余红雅, 刘仲武, 曾德长 (2010) 冷却速度对快淬Fe-Si-B-Cu合金结构和磁性能的影响. 热加工工艺, 06, 135-138.
[5] Yu, W.Q., Sun, Y.M., Liu, Y.D., et al。 (2012) The effect of Nb addition on the thermal property, microstructure and magnetic property of FeCoZrB alloys. Optoelectronics and Advanced Materials—Rapid Communications, 6, 145-148.
[6] Al-Haj, M. and Barry, J. (1998) Nanocrystallization kinetics of Fe85.5Zr4Nb4B5.5, al1 amorphous alloy. Journal of Materials Science Letters, 17, 1125-1127.
[7] Zhu, D.M., Raviprasad, K., Suzuki, K. and Ringer, S. (2004) Structural and microstructural evolution of nanocrystalline soft magnetic Fe93-x-yZr7BxCuy alloys. Materials Forum, 27, 74-79.
[8] Suzuki, K. and Makino, A. (1994) The role of boron in nanocrystalline Fe-Zr-B soft magnetic alloys. Materials Science and Engineering A, 179-180, 501-505.
[9] Imafuku, M., Sato, S., Koshiba, H., Matsubara, E. and Inoue, A. (2000) Crystallization behavior of amorphous Fe90-xNb10BX(x = 10 and 30) alloys. Materials Transactions, JIM, 41, 1526-1529.
[10] Imafuku, M., Sato, S., Koshiba, H., Matsubara, E. and Inoue, A. (2001) Structural variation of Fe-Nb-B metallic glasses during crystallization process. Scripta Materialia, 44, 2369.
[11] Kissinger, H.E. (1957) Reaction kinetics in differential thermal analysis. Analytical Chemistry Periodical, 29, 1702.