MS  >> Vol. 5 No. 4 (July 2015)

    溶胶–凝胶法制备钒掺杂TiO2薄膜的摩擦学特性
    Tribological Properties of the V Ion Doped TiO2 Film Obtained by Sol-Gel Method

  • 全文下载: PDF(548KB) HTML   XML   PP.168-173   DOI: 10.12677/MS.2015.54023  
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作者:  

张明星,王艳艳,曹 磊,万 勇:青岛理工大学机械学院,山东 青岛

关键词:
TiO2钒参杂摩擦学性能溶胶凝胶法TiO2 V Ion Doped Tribological Properties Sol-Gel Method

摘要:

使用溶胶凝胶法在普通玻璃基体上制备了不同质量分数的钒参杂的TiO2薄膜,利用扫描电子显微镜,X射线衍射仪和接触角测量仪对薄膜的表面形貌,晶体结构及表面能进行了表征,并用摩擦磨损实验机评价了薄膜的摩擦学性能。结果表明,V掺杂的TiO2薄膜具有较好的减摩及耐磨性能,特别是5% V-TiO2薄膜的接触角最大且摩擦学性能最好。

The TiO2 thin film doped by different mass fraction of metal V ion was prepared on simple glass surface via a sol-gel method. Scanning electron microscopy, X-ray diffraction spectroscopy and contact angle measuring instrument were used to analyze the morphological features, crystalline and surface energy of the film, respectively. Moreover, the tribological behavior of the film was evaluated by using friction and wear tester. It was found that the TiO2 film with metal V ion has a better friction-reducing and wear-resisting properties; especially 5% V-TiO2 film has a biggest contact angle and the best tribological properties.

文章引用:
张明星, 王艳艳, 曹磊, 万勇. 溶胶–凝胶法制备钒掺杂TiO2薄膜的摩擦学特性[J]. 材料科学, 2015, 5(4): 168-173. http://dx.doi.org/10.12677/MS.2015.54023

参考文献

[1] Jämting, Å.K., Bell, J.M., Swain, M.V., et al. (1998) Measurement of the micro mechanical properties of sol-gel TiO2 films. Thin Solid Films, 332, 189.
http://dx.doi.org/10.1016/S0040-6090(98)01102-X
[2] Olofinjana, A.O., Bell, J.M. and Jämting, Å.K. (2000) Evaluation of the mechanical properties of sol-gel-deposited titania films using ul-tra-micro-indentation method. Wear, 241, 174.
http://dx.doi.org/10.1016/S0043-1648(00)00372-0
[3] Zhang, W., Liu, W. and Wang, C. (2002) Tribological behavior of sol-gel TiO2 films on glass. Wear, 253, 377.
http://dx.doi.org/10.1016/S0043-1648(02)00139-4
[4] Zhang, W., Liu, W., Li, B., et al. (2002) Characterization and tribological investigation of sol-gel titania and doped titania thin films. Journal of the American Ceramic Society, 85, 1770.
http://dx.doi.org/10.1111/j.1151-2916.2002.tb00351.x
[5] 陈云霞, 刘维民, 张平余, 等 (2002) 纳米 Au-TiO2 复合薄膜的溶胶–凝胶法制备, 表征和性能. 高等学校化学学报, 8, 1574.
[6] 董志伟 (2013) 45#钢表面超疏水薄膜的制备及其摩擦学性能的研究. 青岛理工大学硕士学位论文. 青岛.
[7] Wang, Y., Wang, H. and Yan, F. (2009) Effects of UV irradiation on tribological properties of nano TiO2 thin films. Surface and Interface Analysis, 41, 399.
http://dx.doi.org/10.1002/sia.3039
[8] Siva Rama Krishna, D. and Sun, Y. (2005) Effect of thermal oxidation conditions on tribological behaviour of titanium films on 316L stainless steel. Surface and Coatings Technology, 198, 447.
http://dx.doi.org/10.1016/j.surfcoat.2004.10.102
[9] 贾庆远, 张玉娟, 吴志申, 等 (2006) Ag掺杂对TiO2纳米薄膜结构及摩擦学性能的影响. 润滑与密封, 32, 139.
[10] Wan, Y., Xu, Z., Chao, W.L., et al. (2013) Sol-gel de-rived nickel-doped TiO2 films as wear protection coatings. Journal of Experimental Nanoscience, 8, 618.
http://dx.doi.org/10.1080/17458080.2011.607192
[11] Ramírez-Meneses, E., García-Murillo, A., Carrillo-Romo, F.J., et al. (2009) Preparation and photocatalytic activity of TiO2 films with Ni nanoparticles. Journal of Sol-Gel Science and Technology, 52, 267.
http://dx.doi.org/10.1007/s10971-009-2015-1