泡沫萃取法处理含铊工业废水的研究
Study on Treatment of Wastewater Containing Thallium with Flota-Extraction
摘要:
本研究利用泡沫萃取法处理含铊工业废水,分离泡沫相和水相,通过火焰原子吸收分光光度法测定水相中铊浓度。采用泡沫萃取法能够有效的去除含铊重金属废水,尤其对基质较复杂,盐基度高废水有良好的去除效果。实验结果表明:当废水与萃取剂体积比125:1和50:1,铊去除率达80%和95%。该方法污染小、效果稳定、操作简便。
Abstract:
This study used Flota-extraction to treat Tl-bearing industrial wastewater, separation aqueous phase and foam layer, through flame atomic absorption spectrophotometric method to detect thallium concentration in aqueous phase. Using Foam-Extraction method can effectively remove heavy metal waste water containing thallium, especially for waste water with complex contaminant and a high salinity has good removal effect. By experimental verification, the ratio of wastewater to extractant is 125:1 and 50:1, the removal rate of Tl could reach 80% and 95%. This method has got the characteristics of lower pollution, steady effect and user-friendly control.
参考文献
[1]
|
Delvalls, T.A., Saenz, V., Arias, A.M., et al. (1999) Thallium in the marine environment: First ecotoxicological as-sessments in the Guadal quivirestuary and its potential adverse effect on the donana European natural reserve after the aznalcollar mining spill. Ciencias Marinas, 25, 161-175.
|
[2]
|
陈永亨, 谢文彪, 吴颖娟, 王正辉 (2001) 中国含铊资源开发与铊环境污染. 深圳大学学报, 1, 57-63.
|
[3]
|
张平 (2006) 含铊废水的处理方法. 中国专利: 1715204.
|
[4]
|
刘娟, 王津, 陈永亨 (2013) 黄铁矿烧渣处理含铊重金属废水的研究. 武汉科技大学学报, 4, 295-298.
|
[5]
|
Sebba, F. (1959) Concentration by ion flotation. Nature, 184, 1062-21063. http://dx.doi.org/10.1038/1841062a0
|
[6]
|
文震林, 沈文豪, 余佳平 (2006) 泡沫浮选萃取分离回收废水中铜锌. 上海大学学报(自然科学版), 3, 320-324.
|
[7]
|
刘剑, 王九思, 吕江平, 等 (2008) 表面活性剂在泡沫浮选分离中的应用. 精细石油化工进展, 6, 50-53.
|
[8]
|
陶有胜, 朱联锡, 张克仁 (1993) 沉淀浮选法处理矿山含重金属废水技术初探. 四川环境, 2, 36-38.
|
[9]
|
朱锡海 (1980) 泡沫分离技术. 分析化学, 3, 280-284.
|