棉织物连续化层层自组装阻燃拒水复合整理
Flame Retardant and Water Repellent Finishing on Cotton Fabrics through a Continuous Layer by Layer Self-Assembly Technology
DOI: 10.12677/HJCET.2016.62003, PDF, HTML, XML,  被引量 下载: 2,173  浏览: 5,692 
作者: 王 烁, 隋晓锋, 徐 红, 钟 毅, 张琳萍, 毛志平：东华大学生态纺织教育部重点实验室，上海
关键词: 层层自组装；棉织物；阻燃；拒水；Layer by Layer Self-Assembly； Cotton Fabric； Flame Retardant； Water Repellent
摘要: 本文采用连续化层层自组装技术在棉织物上制备PDA-bPEI-MMT-PDMS涂层，并利用热重分析(TGA)，垂直燃烧测试和接触角测试对被整理织物的阻燃拒水性能进行了研究。结果表明：SEM图像显示在棉织物表面成功构造了复合涂层，热重分析(TGA)表明被整理织物具有良好的耐热稳定性，垂直燃烧测试虽将阻燃拒水整理织物完全炭化，但仍可保持较完整的织物形态，并且具有良好的疏水性，其接触角可达143˚。
Abstract: PDA-bPEI-MMT-PDMS composite coating was prepared for flame retardant and water repellent properties on cotton fabrics using a continuous layer by layer self-assembly technology. Flame re-tardant and water repellent properties were studied by the thermal gravimetric analysis (TGA), the vertical burning test and contact angle test. The SEM images show that composite coating can be successfully prepared. The coated fabric had good thermal stability; further the vertical burning test verified the flame retardant properties because coated fabrics maintained complete fabric shape after burning. Meanwhile, the coated fabric had good water repellent, the contact angle was 143˚.
文章引用：王烁, 隋晓锋, 徐红, 钟毅, 张琳萍, 毛志平. 棉织物连续化层层自组装阻燃拒水复合整理[J]. 化学工程与技术, 2016, 6(2): 17-24. http://dx.doi.org/10.12677/HJCET.2016.62003

参考文献

[1] Smith, K.T. (2015) Fire, Ice, and Metabolism. Tree Care Industry, 26, 28-32.
[2] 张广知, 黄小华. 纯棉篷盖布涂料染色拒水拒油阻燃复合涂层[J]. 纺织学报, 2013, 34(2): 125-135.
[3] Dong, C.H., Lu, Z., Zhang, F.J., Zhu, P., Zhang, L. and Sui, S.Y. (2015) Preparation and Properties of Cotton Fabrics Treated with a Novel Polysiloxane Water Repellent and Flame Retardant. Materials Letters, 152, 276-279.
http://dx.doi.org/10.1016/j.matlet.2015.03.132
[4] 胡立立, 孟卫东. 拒水、拒油和阻燃性能合一的丙烯酸酯共聚物的合成及应用[J]. 东华大学学报(自然科学版), 2010, 36(5): 531-580.
[5] 薛朝华, 章琳, 贾顺田, 等. 超疏水阻燃棉织物的制备[J]. 印染, 2015(4): 21-24.
[6] 张维, 张强华, 邓典, 等. 羊毛织物的含磷硅溶胶阻燃整理[J]. 印染, 2014(11): 1-10.
[7] 朱峰, 张菁, van Ooij, W.J. 棉织物的等离子体聚合涂覆及其拒水性研究[J]. 东华大学学报(自然科学版), 2002, 28(4): 22-33.
[8] Ariga, K., Hill, J.P. and Ji, Q.M. (2007) Layer-by-Layer Assembly as a Versatile Bottom-Up Nanofabrication Technique for Exploratory Research and Realistic Application. Physical Chemistry Chemical Physics, 9, 2319-2340.
http://dx.doi.org/10.1039/b700410a
[9] Li, Y.-C., Mannen, S., Morgan, A.B., Chang, S., Yang, Y.-H., Condon, B., et al. (2011) Intumescent All-Polymer Multilayer Nanocoating Capable of Extinguishing Flame on Fabric. Advanced Materials, 23, 3926-3931.
http://dx.doi.org/10.1002/adma.201101871
[10] Laufer, G., Kirkland, C., Morgan, A.B. and Grunlan, J.C. (2012) Intumescent Multilayer Nanocoating, Made with Renewable Polyelectrolytes, for Flame-Retardant Cotton. Biomacro-molecules, 13, 2843-2848.
http://dx.doi.org/10.1021/bm300873b
[11] Li, Y.-C., Schulz, J., Mannen, S., Delhom, C., Condon, B., Chang, S., et al. (2010) Flame Retardant Behavior of Polyelectrolyte Clay Thin Film Assemblies on Cotton Fabric. ACS Nano, 4, 3325-3337.
http://dx.doi.org/10.1021/nn100467e
[12] Chang, S., Slopek, R.P., Condon, B. and Grunlan, J.C. (2014) Surface Coating for Flame-Retardant Behavior of Cotton Fabric Usinga Continuous Layer-by-Layer Process. Industrial & En-gineering Chemistry Research, 53, 3805-3812.
http://dx.doi.org/10.1021/ie403992x
[13] Chen, S.S., Li, X., Li, Y. and Sun, J.Q. (2015) Intumescent Flame-Retardant and Self-Healing Superhydrophobic Coatings on Cotton Fabric. ACS Nano, 9, 4070-4076.
http://dx.doi.org/10.1021/acsnano.5b00121
[14] 于艳红, 陈启宏. 无氟拒水整理剂NT-X018[J]. 印染, 2014(8): 36-39.
[15] Jindasuwan, S., Sukmanee, N., Supanpong, C., Suwan, M., Nimittrakoolchai, O. and Supothina, S. (2013) Influence of Hydrophobic Substance on Enhancing Washing Durability of Watersoluble Flame-Retardant Coating. Ap-plied Surface Science, 275, 239-243.
http://dx.doi.org/10.1016/j.apsusc.2012.12.139
[16] Wang, Z.-X., Lau, C.-H., Zhang, N.-Q., Bai, Y.-P. and Shao, L. (2015) Mussel-Inspired Tailoring of Membrane Wettability for Harsh Water Treatment. Journal of Materials Chemistry A, 3, 2650-2657.
http://dx.doi.org/10.1039/C4TA05970K
[17] Lu, S.-Y. and Hamerton, I. (2002) Recent Developments in the Chemistry of Halogen-Free Flame Retardant Polymers. Progress in Polymer Science, 27, 1661-1712.
http://dx.doi.org/10.1016/S0079-6700(02)00018-7
[18] 续通. 无机粘土包覆有机纤维复合材料的制备及其耐火阻燃性能研究[D]: [博士学位论文]. 上海: 东华大学, 2013.
[19] 郑成志, 赵曙辉, 陈艳艳, 等. 蒙脱土纳米复合材料的制备及其在棉织物阻燃整理中的应用[J]. 东华大学学报(自然科学版), 2014, 40(4): 469-480.
[20] 安秋凤, 李明涛, 金云霞, 李临生. N-环己基-γ-氨丙基聚二甲基硅氧烷的合成、表征与膜形态[J]. 高分子材料科学与工程, 2006, 22(4): 52-55.
[21] Podsiadlo, P., Pavaine, S., Rouillard, J.M., Zhang, Z.F., Lee, J., Lee, J.-W., et al. (2005) Layer-by-Layer Assembly of Nacre-Like Nanostructured Composites with Antimicrobial Properties. Langmuir, 21, 11915-11921.
http://dx.doi.org/10.1021/la051284+
[22] Alongi, J. and Malucelli, G. (2015) Cotton Flame Retardancy: State of the Art and Futureperspectives. RSC Advances, 5, 24239-24263.
[23] Bereck, A., Riegel, D., Matzat, A., Habereder, P. and Lautenschlager, H. (2006) Silicones on Fibrous Substrates: Their Mode of Action. AATCC Review, 1, 45-49.