紫外光降解吲哚的研究
Research on UV Degradation of Indole
DOI: 10.12677/OJNS.2016.44047, PDF, HTML, XML, 下载: 1,796  浏览: 5,698  科研立项经费支持
作者: 施 雯, 刘云琦, 朱晨婷, 刘玉晶:上海师范大学生命与环境科学学院化学系,上海;李 娴:东华大学纺织学院实验中心,上海;单树楠*:上海师范大学生命与环境科学学院化学系,上海;上海师范大学生命与环境科学学院环境工程系,上海;张永明:上海师范大学生命与环境科学学院环境工程系,上海
关键词: 紫外光降解吲哚Ultraviolet Light Degradation Indole
摘要: 本文首次对吲哚溶液进行紫外光降解研究,主要考查了紫外辐射强度、pH值、羟基自由基、自由基抑制剂、水中常见无机阴离子、碱度及腐殖酸等因素对吲哚降解的影响。结果表明,紫外辐射强度、羟基自由基和碱度都会促进吲哚降解,自由基抑制剂和腐殖酸起抑制作用,而常见无机阴离子对吲哚降解影响不大。对于pH值而言,当pH ≤ 7时其影响不大,当pH > 7时会加速吲哚降解。
Abstract: The effects of UV intensity, pH value, hydroxyl radical, hydroxyl radical inhibitor, ordinary orga-nicanions, alkalinity, and humic acid on the degradation efficiency of indole by ultraviolet light were studied for the first time. The results show that UV intensity, hydroxyl radical, and alkalinity can accelerate degradation efficiency, and hydroxyl radical inhibitor and humic acid inhibit it, while ordinary organic anion has little influence on it. For pH value, the degradation efficiency of indole increases when pH > 7, while it almost remains unchanged when pH ≤ 7.
文章引用:施雯, 李娴, 刘云琦, 朱晨婷, 刘玉晶, 单树楠, 张永明. 紫外光降解吲哚的研究[J]. 自然科学, 2016, 4(4): 384-391. http://dx.doi.org/10.12677/OJNS.2016.44047

参考文献

[1] 宫磊, 徐晓军. 焦化废水处理技术的新进展[J]. 工业水处理, 2011(24): 9-11.
[2] 张瑜, 江白茹. 钢铁工业焦化废水治理技术研究[J]. 工业安全与环保, 2002(28): 5-7.
[3] Luthy, R.G. and Harrison, W. (1983) Removal of Organic Contaminants from Coal Conversion Process Condensates. Water Pollution Control Federation, 55, 196-207.
[4] Merabet, S., Bouzaza, A. and Wolbert, D. (2009) Photocatalytic Degradation of Indole in a Circulating up Flow Reactor by UV/TiO2 Process-Influence of Some Operating Parameters. Journal of Hazardous Materials, 166, 1244-1249.
http://dx.doi.org/10.1016/j.jhazmat.2008.12.047
[5] 李咏梅, 赵建夫, 顾国维. 含氮杂环化合物在厌氧和缺氧条件下的降解研究[J]. 上海环境科学, 2003(22): 86-88.
[6] 马娜, 李咏梅, 顾国维. 含氮杂环化合物吲哚的缺氧降解性能研究[J]. 上海环境科学, 2003(22): 734-737.
[7] Qian, Y., Wen, Y. and Zhang, H. (1994) Efficiency of Pre-Treatment Methods in the Activated Sludge Removal of Refractory Compounds in Coke-Plant Wastewater. Water Research, 28, 701-710.
http://dx.doi.org/10.1016/0043-1354(94)90150-3
[8] 何苗, 张晓健, 瞿福平, 顾夏声. 杂环化合物好氧生物降解性能与其化学结构相关性的研究[J]. 中国环境科学, 1997(17): 199-202.
[9] Xu, P., Han, H., Zhuang, H., Hou, B., Jia, S., Wang, D., Li, K. and Zhao, Q. (2015) Anoxic Degradation of Nitrogenous Heterocyclic Compounds by Activated Sludge and Their Active Sites. Journal of Environmental Sciences, 31, 221-225.
http://dx.doi.org/10.1016/j.jes.2014.09.034
[10] Heaney, H. and Ley, S.V. (1974) 1-Benzylindole. Organic Syntheses, 54, 58.
http://dx.doi.org/10.15227/orgsyn.054.0058
[11] Bergman, J. and Venemalm, L. (1992) Efficient Synthesis of 2-Chloro-, 2-Bromo-, and 2-Iodoindole. The Journal of Organic Chemistry, 57, 2495-2497.
http://dx.doi.org/10.1021/jo00034a058
[12] Weiss, J. (1952) The Free Radical Mechanism in the Reactions of Hydrogen Peroxide. Advances in Catalysis, 4, 343- 365.
http://dx.doi.org/10.1016/s0360-0564(08)60618-5
[13] 王李婷, 陈娅, 杜林泽, 周洋, 谢钰蓉, 单树楠, 张永明. 苯并三唑紫外光解影响因素的研究[J]. 自然科学, 2015(3): 105-112.