离子液体[C2O2BBTA][TFA]催化合成3,4-二氢嘧啶-2-(1H)-酮/硫酮
Synthesis of 3,4-Dihydropyrimidine-2-(1H)- Ones/Thiones Catalyzed by Ionic Liquid [C2O2BBTA][TFA]
DOI: 10.12677/JOCR.2017.52010, PDF, HTML, XML, 下载: 1,634  浏览: 4,816  国家自然科学基金支持
作者: 张增鹏, 麻 荣, 郭 磊, 刘晨江：石油天然气精细化工教育部&自治区重点实验室，新疆大学理化测试中心，新疆 乌鲁木齐
关键词: 离子液体；催化；无溶剂；3；4-二氢嘧啶酮-2(1H)-酮/硫酮；Ionic Liquids； Catalysis； Solvent-Free； 3；4-Dihydropyrimidin-2(1H)-Ones/Thiones
摘要: 无溶剂条件下，阳离子为苯并三唑、阴离子为三氟乙酸根的羧基功能化离子液体作为环境友好的催化剂，高效地合成了一系列3,4-二氢嘧啶-2(1H)-酮或硫酮。此外，离子液体[C2O2BBTA][TFA]循环使用至少4次，且催化活性没有明显降低。
Abstract: Carboxyl functional ionic liquid with benzotriazole cation and trifluoroacetate anion can be used as environmental-friendly catalyst for the efficient synthesis of 3,4-dihydropyrimidin-2(1H) ones /thiones under solvent-free conditions. Moreover, the ionic liquid [C2O2BBTA][TFA] can be easily recycled and reused for at least four cycles without obvious loss of catalytic activity.
文章引用：张增鹏, 麻荣, 郭磊, 刘晨江. 离子液体[C2O2BBTA][TFA]催化合成3,4-二氢嘧啶-2-(1H)-酮/硫酮[J]. 有机化学研究, 2017, 5(2): 78-85. https://doi.org/10.12677/JOCR.2017.52010

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