AMC  >> Vol. 5 No. 3 (July 2017)

    Growth Control of CuO-Si Coaxial Nanowire Array

  • 全文下载: PDF(3149KB) HTML   XML   PP.59-69   DOI: 10.12677/AMC.2017.53008  
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曾 力,高 云,夏晓红:湖北大学材料科学与工程学院,湖北 武汉

阳极氧化等离子体增强化学气相沉积硅–氧化铜同轴纳米线阵列微观结构Anodic Oxidation PECVD Si-CuO Coaxial Nanowires Array Microstructure



CuO-silicon core-shell nanowire array is widely used in various types of sensors and lithium-ion batteries and other fields. In this paper, high quality CuO nanowire array was prepared by anodic oxidation method and the influence of annealing on the surface morphology was studied. Amorphous silicon shell structure was formed on the surface of CuO by low-pressure chemical vapor deposition. The effects of deposition time and doping concentrations of carbon and boron on the microstructure of silicon nanowire arrays were investigated by scanning electron microscopy and Raman spectroscopy.

曾力, 高云, 夏晓红. 氧化铜–硅同轴纳米线阵列结构的生长与控制[J]. 材料化学前沿, 2017, 5(3): 59-69.


[1] Su, X., Wu, Q., Li, J., Xiao, X., Lott, A., Lu, W. and Wu, J. (2014) Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review. Advanced Energy Materials, 4, 1-23.
[2] Beaulieu, L.Y., Eberman, K.W., Turner, R.L., Krause, L.J. and Dahn, J.R. (2001) Colossal Reversible Volume Changes in Lithium Alloys. Electrochemical and Solid-State Letters, 4, 137-140.
[3] Cui, L.F., Yang, Y., Hsu, C.M. and Cui, Y. (2009) Carbon-Silicon Core-Shell Nan-owires as High Capacity Electrode for Lithium Ion Batteries. Nano Letters, 9, 3370-3374.
[4] Wang, C., Wu, H., Chen, Z., McDowell, M. T., Cui, Y. and Bao, Z. (2013) Self-Healing Chemistry Enables the Stable Operation of Silicon Microparticle Anodes for High-Energy Lithium-Ion Batteries. Nature chemistry, 5, 1042-1048.
[5] Chan, C.K., Peng, H., Liu, G., McIlwrath, K., Zhang, X.F., Huggins, R.A. and Cui, Y. (2008) High-Performance Lithium Battery Anodes Using Silicon Nanowires. Nature Nanotechnology, 3, 31-35.
[6] Wu, H., Chan, G., Choi, J.W., Yao, Y., McDowell, M.T., Lee, S.W. and Cui, Y. (2012) Stable Cycling of Double- Walled Silicon Nanotube Battery Anodes through Solid-Electrolyte Interphase Control. Nature Nanotechnology, 7, 310-315.
[7] Cao, F.F., Deng, J.W., Xin, S., Ji, H.X., Schmidt, O.G., Wan, L.J. and Guo, Y.G. (2011) Cu-Si Nanocable Arrays as High-Rate Anode Materials for Lithium-Ion Batteries. Advanced Materials, 23, 4415-4420.
[8] Rakhshani, A.E. (1986) Preparation, Characteristics and Photovoltaic Properties of Cuprous Oxide—A Review. Solid-State Electronics, 29(1), 7-17.
[9] Erdoğan, İ.Y. and Güllü, Ö. (2010) Optical and Structural Properties of CuO Nanofilm: Its Diode Application. Journal of Alloys and Compounds, 492, 378-383.
[10] Qiu, G., Dharmarathna, S., Zhang, Y., Opembe, N., Huang, H. and Suib, S.L. (2011) Facile Microwave-Assisted Hydrothermal Synthesis of CuO Nanomaterials and Their Catalytic and Electrochemical Properties. The Journal of Physical Chemistry C, 116, 468-477.
[11] Xiang, J.Y, Tu, J.P, Zhang, L., et al. (2010) Self-Assembled Synthesis of Hierarchical Nanostructured CuO with Various Morphologies and Their Application as Anodes for Lithium Ion Batteries. Journal of Power Sources, 195, 313- 319.
[12] Ke, F.S., Huang, L., Wei, G.Z., Xue, L.J., Li, J.T., Zhang, B. and Sun, S.G. (2009) One-Step Fabrication of CuO Nanoribbons Array Electrode and Its Excellent Lithium Storage Performance. Electrochimica Acta, 54, 5825-5829.
[13] Hsieh, C.T., Chen, J.M., Lin, H.H. and Shih, H.C. (2003) Field Emission from Various CuO Nanostructures. Applied Physics Letters, 83, 3383-3385.
[14] Bedi, R.K. and Singh, I. (2010) Room-Temperature Ammonia Sensor Based on Cationic Surfactant-Assisted Nanocrystalline CuO. ACS Applied Materials & Interfaces, 2, 1361-1368.
[15] Zhang, X., Gu, A., Wang, G., Wei, Y., Wang, W., Wu, H. and Fang, B. (2010) Fabrication of CuO Nanowalls on Cu Substrate for a High Performance Enzyme-Free Glucose Sensor. CrystEngComm, 12, 1120-1126.
[16] Aslani, A. and Oroojpour, V. (2011) CO Gas Sensing of CuO Nanostructures, Synthesized by an Assisted Solvothermal Wet Chemical Route. Physical B: Condensed Matter, 406, 144-149.
[17] Chen, J.T., Zhang, F., Wang, J., Zhang, G.A., Miao, B.B., Fan, X.Y. and Yan, P.X. (2008) CuO Nanowires Synthesized by Thermal Oxidation Route. Journal of Alloys and Compounds, 454, 268-273.
[18] Liang, J., Kishi, N., Soga, T. and Jimbo, T. (2011) The Synthesis of Highly Aligned Cupric Oxide Nanowires by Heating Copper Foil. Journal of Nanomaterials, 15, 1-18.
[19] Wang, W., Varghese, O.K., Ruan, C., Paulose, M. and Grimes, C.A. (2003) Synthesis of CuO and Cu2O Crystalline Nanowires Using Cu(OH)2 Nanowire Templates. Journal of Materials Research, 18, 2756-2759.
[20] Wen, X., Zhang, W. and Yang, S. (2003) Synthesis of Cu (OH)2 and CuO Nanoribbon Arrays on a Copper Surface. Langmuir, 19, 5898-5903.
[21] Wu, X., Bai, H., Zhang, J., et al. (2005) Copper Hydroxide Nanoneedle and Nanotube Arrays Fabricated by Anodization of Copper. The Journal of Physical Chemistry B, 109, 22836-22842.
[22] Chrzanowski, J. and Irwin, J.C. (1989) Raman Scattering from Cupric Oxide. Solid State Communications, 70, 11-14.
[23] Yu, T., Zhao, X., Shen, Z.X., Wu, Y.H. and Su, W.H. (2004) Investigation of Individual CuO Nanorods by Polarized Micro-Raman Scattering. Journal of Crystal Growth, 268, 590-595.
[24] Chen, X.K., Irwin, J.C. and Franck, J.P. (1995) Evidence for a Strong Spin-Phonon Interaction in Cupric Oxide. Physical Review B, 52, 13130-13133
[25] Han, D., Lorentzen, J.D., Weinberg-Wolf, J., McNeil, L.E. and Wang, Q. (2003) Raman Study of Thin Films of Amorphous-to-Microcrystalline Silicon Prepared by Hot-Wire Chemical Vapor Deposition. Journal of Applied Physics, 94, 2930-2936.
[26] Doi, A. (2004) Fabrication of Uniform Poly-Si Thin Film on Glass Substrate by AIC. Thin Solid Films, 451, 485-488.