基于CMIA-Cd构建的MOF孔材料的溶剂热合成
The Hydrothermal Synthesis of Porous Material MOF Based on the CMIA-Cd
DOI: 10.12677/AAC.2017.73025, PDF, HTML, XML, 下载: 1,719  浏览: 3,327 
作者: 冯 晨, 张 宁, 付丽影, 冯振东, 王凤春:通化师范学院,化学学院,吉林 通化
关键词: CMIA配体镉配合物金属–有机框架CMIA Ligands Cadmium Complexes Transition Metal-Organic Frameworks
摘要: 本论文利用羧酸类配体CMIA和Cd,利用溶剂热反应,构筑了一个新的稳定的三维MOF孔道材料。结构分析表明该配合物属单斜晶系,空间群均为P21/n,a = 8.1153(4) Å,b = 22.3470(9) Å,c = 25.348(3) Å;α = 90˚,β = 99.4500(10)˚,γ = 90˚,V = 3151.4(2) Å3,并利用红外分析探讨了框架的相互作用。
Abstract: In this paper, pyridine carboxylic acid ligands CMIA and transition meta Cd, thermal reaction with a solvent were used to build a new stable three-dimensional pore MOF materials. Structural analysis shows that the compound belongs to the monoclinic system, space group are P21/n, a = 8.1153(4) Å, b = 22.3470(9) Å, c = 25.348(3) Å, α = 90˚, β = 99.4500(10)˚, γ = 90˚, V = 3151.4(2) Å3, and IR analy-sis was used to explore the MOFs interaction and stability.
文章引用:冯晨, 张宁, 付丽影, 冯振东, 王凤春. 基于CMIA-Cd构建的MOF孔材料的溶剂热合成[J]. 分析化学进展, 2017, 7(3): 196-202. https://doi.org/10.12677/AAC.2017.73025

参考文献

[1] 聂辉. 金(I)-巯基配位聚合物的自组装及其在制备金纳米结构中的应用[D]: [博士学位论文]. 长春: 吉林大学, 2015.
[2] 李志超, 王小锋, 吴刚. 3-吡啶磺酸Cu(II)配位聚合物的合成、结构和性质[J]. 南京晓庄学院学报, 2016(6): 75-78.
[3] Huang, Y.G., Wu, B.L., Yuan, D.Q., et al. (2007) New Lanthanide Hybrid as Clustered Infinite Nanotunnel with 3D Ln-O-Ln Framework and (3, 4)-Connected Net. Inorganic Chemistry, 46, 1171-1176.
https://doi.org/10.1021/ic0615271
[4] Tian, L., Lee, Y.Y., Tien, T.O., et al. (2009) Synthesis of NiS and MnS Nanocrystals from the Molecular Precursors (TMEDA)M(SC{O}C6H5)2(M=Ni, Mn). Crystal Growth & Design, 9, 352-357.
https://doi.org/10.1021/cg800536w
[5] 骆昱晖. 新型晶态配位聚合物材料的合成、结构与性质研究[D]: [博士学位论文]. 长春: 东北师范大学, 2015.
[6] Marius, A., Jean-Pierre, C., Carmen, D., et al. (2009) 3d-4f Combined Chemistry: Synthetic Strategies and Madnetic Properties. Inorganic Chemistry, 48, 3342-3359.
https://doi.org/10.1021/ic801027q
[7] 刘冰, 郭凯, 何婷婷. 5-磺酸间苯二甲酸铜配位聚合物的合成、结构及性能研究[J]. 陕西科技大学学报, 2016, 34(6): 104-109.
[8] 阚卫秋. 一个二维锰配位聚合物的合成、结构、表征和光学带隙研究[J]. 广东化工, 2016, 43(18): 43-44.
[9] 张佳佳, 崔放, 邵青. 从双金属配位聚合物到一维Ag@Co3O4纳米复合催化材料[J]. 高等学校化学学报, 2016, 37(10): 1876-1881.
[10] Wang, Y., Zhao, F.H., Che, Y.X., et al. (2012) A 3D Photoluminescent Cd(II) Polymer Based on Mixed 3,5-Bis-Oxyacetate-Benzoic Acid and Rigid Bis(Imidazole) Ligands with an Unusual (4,8)-Connected Topology. Inorganic Chemistry Communications, 17, 180-183.
https://doi.org/10.1016/j.inoche.2012.01.007
[11] Eddaoudi, M., Kim, J., Rosi, N., et al. (2012) Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage. Science, 295, 469-472.
https://doi.org/10.1126/science.1067208
[12] Vodak, D.T., Braun, M.E., Kim, J., et al. (2011) Metal-Organic Frameworks Constructed from Pentagonal Antiprismatic and Cuboctahedral Secondary Building Units. Chemical Communications, 24, 2534-2535.
[13] Kim, J., Chen, B.L., Reineke, T.M., et al. (2001) Assembly of Metal-Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures. Journal of the American Chemical Society, 123, 8239-8247.
https://doi.org/10.1021/ja010825o
[14] 郝向荣, 吕莹, 郑艳萍, 等. 基于BPA构建的柱撑型MOF孔材料合成[J]. 通化师范学院学报, 2013, 34(12): 22- 25.
[15] Ferey, G., Mellot-Draznieks, C., Serre, C., et al. (2005) Crystal-lized Frameworks with Giant Pores: Are There Limits to The Possible? Accounts of Chemical Research, 38, 217-225.
https://doi.org/10.1021/ar040163i
[16] 王润雪, 王姝文, 齐艳娟. 以邻菲罗啉及均苯三甲酸为配体的钴[Ⅱ]配合物的合成、晶体结构及性质研究[J]. 无机化学学报, 2012, 28(3): 536-540.