环境灰尘中有机磷酸酯阻燃剂的研究进展
Research Progress of Organophosphate Flame Retardant in Environmental Dust
DOI: 10.12677/AAC.2019.92011, PDF,    科研立项经费支持
作者: 邓 星, 成 祝, 刘 洁, 冉 琴, 刘世成, 苏小东*：重庆科技学院化学化工学院，重庆
关键词: 有机磷酸酯；阻燃剂；灰尘；Organic Phosphate； Flame Retardant； Dust
摘要: 近年来，多溴联苯醚类阻燃剂在世界范围内逐渐被禁用，有机磷酸酯阻燃剂(OPFRs)作为其主要替代品，由于其优秀的阻燃效果，广泛应用于塑料、纺织品、电子设备、家具和建筑材料。OPFRs作为一类新型持久性有机污染物，已经受到了国内外环境科学工作者越来越多的关注。本文介绍了OPFRs的毒性、OPFRs的分析方法研究、室内和室外环境灰尘中OPFRs的研究以及不同国家环境灰尘中OPFRs的分布情况，综述了当前OPFRs的研究现状，并对该领域今后的主要研究方向提出展望，为我国有机磷酸酯阻燃剂的环境污染研究和对人体的健康风险评估提供信息和借鉴。
Abstract: In recent years, polybrominated diphenyl ethers flame retardant has been gradually banned in the world. As the main substitute, organophosphate flame retardant (OPFRs) is widely used in plastics, textiles, electronic equipment, furniture and building materials due to its excellent flame retardant effect. As a new type of persistent organic pollutants, OPFRs has been paid more and more attention by environmental scientists at home and abroad. In this paper, OPFRs toxicity, study on the analytical method of OPFRs, the dust OPFRs detection of indoor and outdoor environment in the research, and different national environmental dust OPFRs distribution were introduced, and summarized the research status quo of the current OPFRs. Furthermore, the future research di-rections in this field are also prospected, which can provide information and reference for the environmental pollution research of OPFRs and the health risk assessment of human body in China.
文章引用：邓星, 成祝, 刘洁, 冉琴, 刘世成, 苏小东. 环境灰尘中有机磷酸酯阻燃剂的研究进展[J]. 分析化学进展, 2019, 9(2): 79-84. https://doi.org/10.12677/AAC.2019.92011

参考文献

[1] 周小丽, 郭珩, 李芹, 等. 气相色谱–质谱法测定塑料中7种有机磷酸酯阻燃剂的含量[J]. 理化检验(化学分册), 2018, 54(1): 64-68.
[2] 林殷, 温尔英, 苏思杰, 等. 纺织品中多种有机磷酸酯化合物的GC/MS法测定[J]. 印染, 2018, 44(3): 54-57.
[3] Li, H., Mark, J.L.G., Liu, H., et al. (2019) Brominated and Organoposphate Flame Retardants along a Sediment Transect Encompassing the Guiyu, China e-Waste Recycling Zone. Science of the Total Environment, 646, 58-67.
[Google Scholar] [CrossRef] [PubMed]
[4] Stapleton, H.M., Klosterhaus, S., Eagle, S., et al. (2009) Detection of Organophosphate Flame Retardants in Furniture Foam and US House Dust. Environmental Science and Technology, 43, 7490-7495.
[Google Scholar] [CrossRef] [PubMed]
[5] Glazer, L., et al. (2018) Developmental Exposure to Low Concentrations of Organophosphate Flame Retardants Causes Life-Long Behavioral Alterations in Zebrafish. Toxicological Sciences, 165, 487-498.
[Google Scholar] [CrossRef] [PubMed]
[6] Kim, J.W., Isobe, T., Chang, K.H., et al. (2011) Levels and Distribution of Organophosphorus Flame Retardants and Plasticizers in Fishes from Manila Bay, the Philippines. Environmental Pollution, 159, 3653-3659.
[Google Scholar] [CrossRef] [PubMed]
[7] Nele, V.D.E., Maho, W., Erratico, C., et al. (2013) First Insights in the Metabolism of Phosphate Flame Retardants and Plasticizers Using Human Liver Fractions. Toxicology Letters, 223, 9-15.
[Google Scholar] [CrossRef] [PubMed]
[8] Chen, G., Jin, Y., Wu, Y., et al. (2015) Exposure of Male Mice to Two Kinds of Organophosphate Flame Retardants (OPFRs) Induced Oxidative Stress and Endocrine Disruption. Environmental Toxicology and Pharmacology, 40, 310-318.
[Google Scholar] [CrossRef] [PubMed]
[9] Farhat, A., Buick, J.K., Williams, A., et al. (2014) Tris(1,3-Dichloro-2-Propyl) Phosphate Perturbs the Expression of Genes Involved in Immune Response and Lipid and Steroid Metabolism in Chicken Embryos. Toxicology and Applied Pharmacology, 275, 104-112.
[Google Scholar] [CrossRef] [PubMed]
[10] Zhong, X., et al. (2019) Exposure to Tris(1,3-Dichloro-2-Propyl) Phosphate (TDCPP) Induces Vascular Toxicity through Nrf2-VEGF Pathway in Zebrafish and Human Umbilical Vein Endothelial Cells. Environmental Pollution, 247, 293-301.
[Google Scholar] [CrossRef] [PubMed]
[11] Krivoshiev, B.V., et al. (2018) Toxicogenomics of the Flame Retardant Tris(2-Butoxye-Thyl) Phosphate in HepG2 Cells Using RNA-seq. Toxicology in Vitro, 46, 178-188.
[Google Scholar] [CrossRef] [PubMed]
[12] 刘琴, 印红玲, 李蝶, 等. 室内灰尘中有机磷酸酯的分布及其健康风险[J]. 中国环境科学, 2017, 37(8): 2831-2839.
[13] 徐亮, 胡琼璞, 刘静, 等. 上海城市污泥中有机磷酸酯阻燃剂/增塑剂分布的初步研究[J]. 环境化学, 2018, 37(8): 1699-1705.
[14] 温裕云, 陈志华, 欧延, 等. 纺织品中9种有机磷酸酯类阻燃剂的超高效液相色谱–串联质谱快速测定方法[J]. 分析化学, 2015, 43(9): 1342-1348.
[15] 索莉莉, 朱群英, 胡美华, 等. 超声辅助萃取-液相色谱-串联质谱法同时检测水产品中11种有机磷酸酯类阻燃剂[J]. 食品工业科技, 2018, 39(6): 210-216.
[16] Carlsson, H., Ulrika Nilsson, A. and Östman, C. (2000) Video Dis-play Units: An Emission Source of the Contact Allergenic Flame Retardant Triphenyl Phosphate in the Indoor Envi-ronment. Environmental Science & Technology, 34, 3885-3889.
[Google Scholar] [CrossRef] 
[17] Ingerowski, G., Friedle, A. and Thumulla, J. (2001) Chlorinated Ethyl and Isopropyl Phosphoric Acid Triesters in the Indoor Environment—An Inter-Laboratory Exposure Study. Indoor Air, 11, 145-149.
[Google Scholar] [CrossRef] [PubMed]
[18] Zhou, L., Hiltscher, M. and Püttmann, W. (2017) Occurrence and Human Exposure Assessment of Organophosphate Flame Retardants (OPFRs) in Indoor Dust from Various Microenvironments of the Rhine/Main Region, Germany. Indoor Air, 27, 1113-1127.
[Google Scholar] [CrossRef] [PubMed]
[19] Brommer, S., Harrad, S., Eede, N.V.D., et al. (2012) Concentrations of Organophosphate Esters and Brominated Flame Retardants in German Indoor Dust Samples. Journal of Environmental Monitoring, 14, 2482-2487.
[Google Scholar] [CrossRef] [PubMed]
[20] Yang, F., Ding, J., Huang, W., et al. (2014) Particle Size-Specific Dis-tributions and Preliminary Exposure Assessments of Organophosphate Flame Retardants in Office Air Particulate Matter. Environmental Science & Technology, 48, 63-70.
[Google Scholar] [CrossRef] [PubMed]
[21] Marklund, A., Andersson, B. and Haglund, P. (2005) Organophosphorus Flame Retardants and Plasticizers in Air from Various Indoor Environments. Journal of Environmental Monitoring, 7, 814-819.
[Google Scholar] [CrossRef] [PubMed]
[22] Tokumura, M., Hatayama, R., Tatsu, K., et al. (2017) Organophosphate Flame Retardants in the Indoor Air and Dust in Cars in Japan. Environmental Monitoring and Assessment, 189, 48.
[Google Scholar] [CrossRef] [PubMed]
[23] Hartmann, P.C., Bürgi, D. and Giger, W. (2004) Organophosphate Flame Retardants and Plasticizers in Indoor Air. Chemosphere, 57, 781-787.
[Google Scholar] [CrossRef] [PubMed]
[24] Staaf, T., et al. (2005) Organophosphate Triesters in Indoor Environments. Journal of Environmental Monitoring, 7, 883-887.
[Google Scholar] [CrossRef] [PubMed]
[25] Lai, S., Xie, Z., Song, T., et al. (2015) Occurrence and Dry Deposition of Organophosphate Esters in Atmospheric Particles over the Northern South China Sea. Chemosphere, 127, 195-200.
[Google Scholar] [CrossRef] [PubMed]
[26] Salamova, A., Hermanson, M.H. and Hites, R.A. (2014) Organophosphate and Halogenated Flame Retardants in Atmospheric Particles from a European Arctic Site. Environmental Science & Technology, 48, 6133-6140.
[Google Scholar] [CrossRef] [PubMed]
[27] Ali, N., Dirtu, A.C., Eede, N.V.D., et al. (2012) Occurrence of Alternative Flame Retardants in Indoor Dust from New Zealand: Indoor Sources and Human Exposure Assessment. Chemosphere, 88, 1276-1282.
[Google Scholar] [CrossRef] [PubMed]
[28] Ali, N., Eqani, S.A.M.A.S., Ismail, I.M.I., et al. (2016) Brominated and Organophosphate Flame Retardants in Indoor Dust of Jeddah, Kingdom of Saudi Arabia: Implications for Human Exposure. Science of the Total Environment, 569-570, 269-277.
[Google Scholar] [CrossRef] [PubMed]
[29] Van, d.E.N., Dirtu, A.C., Neels, H., et al. (2011) Analytical Developments and Preliminary Assessment of Human Exposure to Organophosphate Flame Retardants from Indoor Dust. Environment International, 37, 454-461.
[Google Scholar] [CrossRef] [PubMed]
[30] Cristale, J., Hurtado, A., Gómez-Canela, C., et al. (2016) Occurrence and Sources of Brominated and Organophosphorus Flame Retardants in Dust from Different Indoor Environments in Barcelona, Spain. Environmental Research, 149, 66-76.
[Google Scholar] [CrossRef] [PubMed]
[31] Bergh, C., Torgrip, R., Emenius, G., et al. (2010) Organophosphate and Phthalate Esters in Air and Settled Dust—A Multi-Location Indoor Study. Indoor Air, 21, 67-76.
[Google Scholar] [CrossRef] [PubMed]
[32] Ali, N., Eede, N.V.D., Dirtu, A.C., et al. (2012) Assessment of Human Exposure to Indoor Organic Contaminants via Dust Ingestion in Pakistan. Indoor Air, 22, 200-211.
[Google Scholar] [CrossRef] [PubMed]

为你推荐