三维多孔弹性体海绵的可控制备及吸油性能研究
Study on Controllable Preparation and Oil Absorption Performance of Three-Dimensional Porous Elastomeric Sponge
摘要: 以白砂糖颗粒为致孔剂,采用模板法制备了具有三维多孔结构的疏水亲油型聚二甲基硅氧烷(PDMS)弹性体海绵吸油材料。考察了白砂糖颗粒尺寸、填充浓度、吸附时间等条件对弹性体海绵吸油性能的影响。结果表明:采用粗粒径白砂糖作为致孔剂、80%填充浓度条件下制备的PDMS多孔材料具有最佳的吸油性能,吸油率高达205.3%。通过物理挤压PDMS多孔海绵,可以将材料中吸收的油类物质回收,并且吸油性能得到恢复,从而实现材料的循环使用。该研究为水体油污的去除以及油水分离提供了一种经济、高效的吸油材料。
Abstract: The hydrophobic and oleophilic polydimethy lsiloxane (PDMS) elastomer sponge oil-absorbing material having a three-dimensional porous structure was prepared by a template method using white sugar particles as a porogen. The influence of white sugar particle size, filling concentration and adsorption time on the oil absorption performance of elastomer sponges were investigated. The experimental results indicate that the PDMS porous material prepared by using coarse-grained white granulated sugar particles as porogen and 80% filling concentration has the best oil absorption performance, and the efficiency of oil absorption can reach 205.3%. The porous PDMS oil-absorbing material can recover the absorbed oil solution only by the physical extrusion, and the material can also restore the oil-adsorption capacity, being renewable. The study provides an economical and efficient material for the removal of oil from water and the oil-water separation.
文章引用:陈世, 张子贺, 雷德河, 沈超, 高琦, 李佳霓, 潘 超. 三维多孔弹性体海绵的可控制备及吸油性能研究[J]. 材料科学, 2019, 9(8): 813-820. https://doi.org/10.12677/MS.2019.98101

参考文献

[1] Shannon, M.A., Bohn, P.W., Elimelech, M., Georgiadis, J.G., Marinas, B.J. and Mayers, A.M. (2008) Science and Technology for Water Purification in the Coming Decades. Nature, 452, 301-310. [Google Scholar] [CrossRef] [PubMed]
[2] 陈健, 封严. 吸油材料的研究进展[J]. 化工新型材料, 2014, 42(4): 4-6.
[3] Calcagnile, P., Fragouli, D., Bayer, I.S., Anyfantis, G.C., Martiradonna, L., Cozzoli, P.D., Cingolani, R. and Athanassiou, A. (2012) Magnetically Driven Floating Foams for the Removal of Oil Contaminants from Water. ACS Nano, 6, 5413-5416. [Google Scholar] [CrossRef] [PubMed]
[4] 雷小梅. 聚二甲基硅氧烷多孔小球的制备及对有机溶剂和油的吸附研究[D]: [硕士学位论文]. 重庆: 重庆工商大学, 2014.
[5] 赵佳钧, 叶会见, 张冰攀, 楼才溢, 任思佳, 郁家豪, 祁玥, 徐立新. 蔗糖模板法制备PDMS多孔材料及其吸油性能研究[J]. 化工新型材料, 2018, 46(8): 265-268.
[6] 曹梓楷, 项丽, 董欣琦, 唐建设. 多孔聚二甲基硅氧烷吸油材料制备及吸油性质机理研究[J]. 功能材料, 2017, 48(9): 9192-9196.
[7] Zhang, L., Wu, J.J., Wang, Y.X., Long, Y.H., Zhao, N. and Xu, J. (2012) Combination of Bioinspiration: A General Route to Superhydrophobic Particles. Journal of the American Chemical Society, 134, 9879-9881. [Google Scholar] [CrossRef] [PubMed]
[8] Xu, L.P., Wu, X.W., Meng, J.X., Peng, J.T., Wen, Y.Q., Zhang, X.J. and Wang, S.T. (2013) Papilla-Like Magnetic Particles with Hierarchical Structure for Oil Removal from Water. Chemical Communications, 49, 8752-8754. [Google Scholar] [CrossRef] [PubMed]
[9] Khorasani, M.T., Mirzadeh, H. and Kermani, Z. (2005) Wettability of Porous Polydimethylsiloxane Surface: Morphology Study. Applied Surface Science, 242, 339-345. [Google Scholar] [CrossRef