合金储氢材料吸/放氢动力学特征及机理研究
The Characters and Mechanism Research of Hydrogen Absorption/Desorption Kinetics for Alloy Hydrogen Storage Materials
摘要: 综述了合金储氢材料的吸放氢动力学特征。为了探求动力学特征的本质，综述了合金储氢材料在吸放氢过程中的晶体结构演变实验研究结果，发现Mg系合金的储氢主体是氢化物，而Ti和稀土系是氢化固溶体。比较了合金储氢材料的原子密堆情况和间隙空间数量及大小等结构特征，阐明了吸氢过程的晶体学行为，并从晶体学行为的热力学定性地解释了合金储氢材料的储氢动力学等特征。在适当的氢压下，不同温度下吸氢动力学曲线的特征是：1) 以氢化物为储氢主体的材料(Mg系)，初始吸氢速率和饱和吸氢量随温度的升高而增加；2) 以氢化固溶体为储氢主体的材料(Ti系和稀土系)初始吸氢速率和饱和吸氢量随温度的升高而降低。
Abstract: The characters of hydrogen absorption/desorption kinetics for alloy hydrogen storage materials have been summarized. For searching the nature of hydrogen absorption/desorption kinetics, the experimental research results of evolution of the phase structure during hydrogen absorption/desorption processes have been summarized. It is found that hydrogen storage host is hydride for Mg system alloys and is hydrogenation solid solution for Ti and rare-earth systems. The situation of atom close packing and the number of interstitial sites as well as size of interstitial space of hydrogen storage materials were compared. The crystallographic behaviors in hydrogen absorption/desorption processes have been expounded. The characters of hydrogen storage kinetics for alloy hydrogen storage materials were qualitatively explained from the thermodynamics of crystallographic behaviors. Under appropriate hydrogen pressure and different temperature, characters of hydrogen absorption kinetics curves are: 1) The hydrogen absorption rate of initial stage and saturation quantity of hydrogen absorption increase with temperature increase for the materials (Mg system) that the host of hydrogen absorption is the hydride; 2) The hydrogen absorption rate of initial stage and saturation quantity of hydrogen absorption decrease with temperature increase for the materials (Ti and rare-earth systems) that the host of hydrogen absorption is the hydrogenation solid solution.
文章引用：杨传铮. 合金储氢材料吸/放氢动力学特征及机理研究[J]. 材料科学, 2020, 10(12): 1002-1026. https://doi.org/10.12677/MS.2020.1012120

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