纳米Mg(OH)2在酸性气体捕集和水中污染物去除的研究进展
Nano Mg(OH)2 in Acid Gas Capture and Pollutant Removal in Water: A Review
DOI: 10.12677/MS.2022.125044, PDF,    科研立项经费支持
作者: 龚 露, 姚贞英, 朱春梅, 余达伟, 何 柏, 余 波*:重庆科技学院,化学化工学院,重庆
关键词: 纳米Mg(OH)2制备方法酸性气体水中污染物Nano-Mg(OH)2 Preparation Method Acid Gas Pollutants in Water
摘要: 纳米Mg(OH)2是一类新型绿色环保无机纳米材料,广泛应用于环境、材料、增强、阻燃等多个领域。目前致力于研究利用成本低、绿色环保和广泛可用的镁资源来合成高质量的纳米Mg(OH)2材料。将低价值镁盐转化为高价值纳米Mg(OH)2材料是减少资源浪费和实现可持续技术发展的有效途径之一。本文主要论述了纳米Mg(OH)2材料常见的制备方法及其作为吸附剂在环境领域中酸性气体和水中污染物的应用。
Abstract: Nano-Mg(OH)2 is a new type of green and environmentally friendly inorganic nanomaterials, which are widely used in many fields such as environment, materials, reinforcement, and flame retardancy. At present, the research is devoted to the synthesis of high-quality nano-Mg(OH)2 materials using low-cost, green and widely available magnesium resources. Converting low-value magnesium salts into high-value nano-Mg(OH)2 materials is one of the effective ways to reduce resource waste and achieve sustainable technological development. This paper mainly discusses the common preparation methods of nano-Mg(OH)2 materials and their applications as adsorbents in acid gas and water pollutants in the environmental field.
文章引用:龚露, 姚贞英, 朱春梅, 余达伟, 何柏, 余波. 纳米Mg(OH)2在酸性气体捕集和水中污染物去除的研究进展[J]. 材料科学, 2022, 12(5): 419-428. https://doi.org/10.12677/MS.2022.125044

参考文献

[1] Grennfelt, P., Engleryd, A., Forsius, M., Hov, Ø., Rodhe, H. and Cowling, E. (2020) Acid Rain and Air Pollution: 50 Years of Progress in Environmental Science and Policy. Ambio, 49, 849-864. [Google Scholar] [CrossRef] [PubMed]
[2] Chen, B.H., Wang, K., Dong, X. and Lin, H. (2021) Long-Term Changes in Red Tide Outbreaks in Xiamen Bay in China from 1986 to 2017. Estuarine, Coastal and Shelf Science, 249, Article ID: 107095. [Google Scholar] [CrossRef
[3] Tang, T., Effiong, K., Hu, J., Li, C. and Xiao, X. (2021) Chemical Prevention and Control of the Green Tide and Fouling Organism Ulva: Key Chemicals, Mechanisms, and Applications. Frontiers in Marine Science, 8, Article ID: 618950.
[4] Hu, C., Chen, R. and Zheng, N. (2021) Chemical Insights into Interfacial Effects in Inorganic Nanomaterials. Advanced Materials, 33, Article ID: 2006159. [Google Scholar] [CrossRef] [PubMed]
[5] Madima, N., Mishra, S.B., Inamuddin, I. and Mishra, A.K. (2020) Carbon-Based Nanomaterials for Remediation of Organic and Inorganic Pollutants from Wastewater. A Review. Environmental Chemistry Letters, 18, 1169-1191. [Google Scholar] [CrossRef
[6] Alharbi, N.S., Hu, B., Hayat, T., et al. (2020) Efficient Elimination of Environmental Pollutants through Sorption-Reduction and Photocatalytic Degradation Using Nanomaterials. Frontiers of Chemical Science and Engineering, 14, 1124-1135. [Google Scholar] [CrossRef
[7] Falyouna, O., Bensaida, K., Maamoun, I., Ashik, U.P.M., Tahara, A., Tanaka, K., Aoyagi, N., Sugihara, Y. and Eljamal, O. (2022) Synthesis of Hybrid Magnesium Hydroxide/Magnesium Oxide Nanorods [Mg(OH)2/MgO] for Prompt and Efficient Adsorption of Ciprofloxacin from Aqueous Solutions. Journal of Cleaner Production, 342, Article ID: 130949. [Google Scholar] [CrossRef
[8] Sun, Q., Zhu, G.C., Wu, J., Lu, J. and Zhang, Z.H. (2021) Simultaneous Catalytic Ozonation Degradation of Metronidazole and Removal of Heavy Metal from Aqueous Solution Using Nano-Magnesium Hydroxide. Environmental Technology, 42, 894-904. [Google Scholar] [CrossRef] [PubMed]
[9] Takafumi, S., Seitarou, Y. and Naotsugu, I. (2021) Hydrothermal Carbon Dioxide Fixation in Magnesium Hydroxide and Serpentine: Effects of Temperature and pH. The Journal of Supercritical Fluids, 168, Article ID: 105071. [Google Scholar] [CrossRef
[10] Hanif, A., Sun, M.Z., Wang, T.Q., Shang S.S., Daniel, C., Tsang, W. and Shang, J. (2021) Ambient NO2 Adsorption Removal by Mg-Al Layered Double Hydroxides and Derived Mixed Metal Oxides. Journal of Cleaner Production, 313, Article ID: 127956. [Google Scholar] [CrossRef
[11] Pan, Y.K., Xu, H., Chen, M.Q., Wu, K.D., Zhang, Y.Y. and Long, D.H. (2021) Unveiling the Nature of Room-Temperature O2 Activation and O2•- Enrichment on MgO-Loaded Porous Carbons with Efficient H2S Oxidation. ACS Catalysis, 11, 5974-5983. [Google Scholar] [CrossRef
[12] Lin, J., He, S., Wang, X., Zhang, H. and Zhan, Y. (2019) Removal of Phosphate from Aqueous Solution by a Novel Mg(OH)2/ZrO2 Composite: Adsorption Behavior and Mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 561, 301-314. [Google Scholar] [CrossRef
[13] Li, B.W., Pu, S.Y., Mandal, S. and Li, M. (2020) Viscosity Modification Enhanced the Migration and Distribution of Colloidal Mg(OH)2 in Aquifers Contaminated by Heavy Metals. Environment International, 138, Article ID: 105658. [Google Scholar] [CrossRef] [PubMed]
[14] Kumar, S.P., Korving, L., van Loosdrecht, M.C.M. and Witkamp, G.J. (2019) Adsorption as a Technology to Achieve Ultra-Low Concentrations of Phosphate: Research Gaps and Economic Analysis. Water Research X, 4, Article ID: 100029. [Google Scholar] [CrossRef] [PubMed]
[15] Liu, X.M., Liao, C.Z., Lin, L., Gao, H.Q., Zhou, J., Feng, Z. and Lin, Z. (2020) Research Progress in the Environmental Application of Magnesium Hydroxide Nanomaterials. Surfaces and Interfaces, 21, Article ID: 100701. [Google Scholar] [CrossRef
[16] Klein, F., Humphris, S.E. and Bach, W. (2020) Brucite Formation and Dissolution in Oceanic Serpentinite. Geochemical Perspectives Letters, 16, 1-5. [Google Scholar] [CrossRef
[17] Oun, A.A., Shankar, S. and Rhim, J.W. (2020) Multifunctional Nanocellulose/Metal and Metal Oxide Nanoparticle Hybrid Nanomaterials. Critical Reviews in Food Science and Nutrition, 60, 435-460. [Google Scholar] [CrossRef] [PubMed]
[18] Wu, H.H., Luo, B.J., Gao, C.J., Wang, L.C., Wang, Y.Q. and Zhang, Q. (2020) Synthesis and Size Control of Monodisperse Magnesium Hydroxide Nanoparticles by Microemulsion Method. Journal of Dispersion Science and Technology, 41, 585-591. [Google Scholar] [CrossRef
[19] Wang, P.P., Li, C.H. and Gong, H.Y. (2011) Morphology Control and Growth Mechanism of Magnesium Hydroxide Nanoparticles via a Simple Wet Precipitation Method. Ceramics International, 37, 3365-3370. [Google Scholar] [CrossRef
[20] Jiang, W.J., Hua, X. and Han, Q.F. (2009) Preparation of Lamellar Magnesium Hydroxide Nanoparticles via Precipitation Method. Powder Technology, 191, 227-230. [Google Scholar] [CrossRef
[21] Sierra-Fernandez, A., Gomez-Villalba, L.S. and Milosevic, O. (2014) Synthesis and Morpho-Structural Characterization of Nanostructured Magnesium Hydroxide Obtained by a Hydrothermal Method. Ceramics International, 40, 12285-12292. [Google Scholar] [CrossRef
[22] Zou, G.L., Liu, R. and Chen, W.X. (2007) Preparation and Characterization of Lamellar Like Mg(OH)2 Nanostructures via Natural Oxidation of Mg Metal in Formamide/Water Mixture. Materials Research Bulletin, 42, 1153-1158. [Google Scholar] [CrossRef
[23] Sun, X.T. and Xiang, L. (2008) Hydrothermal Conversion of Magnesium Oxysulfate Whiskers to Magnesium Hydroxide Nanobelts. Materials Chemistry and Physics, 109, 381-385. [Google Scholar] [CrossRef
[24] de Bakker, J., LaMarre, J., Peacey, J. and Davis, B. (2012) The Phase Stabilities of Magnesium Hydroxychlorides. Metallurgical and Materials Transactions B, 43, 758-763. [Google Scholar] [CrossRef
[25] Bloss, W.J., Kramer, L. and Crilley, L.R. (2021) Insights into Air Pollution Chemistry and Sulphate Formation from Nitrous Acid (HONO) Measurements during Haze Events in Beijing. Faraday Discussions, 226, 223-238. [Google Scholar] [CrossRef
[26] Liu, Z., Wang, Z., Chen, H., Cai, T. and Liu, Z. (2021) Hydrochar and Pyrochar for Sorption of Pollutants in Wastewater and Exhaust Gas: A Critical Review. Environmental Pollution, 268, Article ID: 115910. [Google Scholar] [CrossRef] [PubMed]
[27] Barsotti, S. (2020) Probabilistic Hazard Maps for Operational Use: The Case of SO2 Air Pollution during the Holuhraun Eruption (Bárðarbunga, Iceland) in 2014-2015. Bulletin of Volcanology, 82, Article No. 56. [Google Scholar] [CrossRef
[28] Zhang, X., Wang, J., Chen, D. and Liu, L. (2021) The Adsorption Performance of Harmful Gas on Cu Doped WS2: A First-Principle Study. Materials Today Communications, 28, Article ID: 102488. [Google Scholar] [CrossRef
[29] Salehi, E., Eidi, B. and Soleimani, Z. (2019) An Integrated Process Consisting of Mg(OH)2-Impregnated Ceramic Foam Filters as Adsorbent and Mg(OH)2 as Scrubbing Solution for Intensified Desulfurization of Flue Gas. Separation and Purification Technology, 216, 34-42. [Google Scholar] [CrossRef
[30] Wang, Y., Widmann, D., Lehnert, F., Gu, D., Schueth, F. and Behm, R.J. (2017) Avoiding Self-Poisoning: A Key Feature for the High Activity of Au/Mg(OH)2 Catalysts in Continuous Low-Temperature CO Oxidation. Angewandte Chemie International Edition, 56, 9597-9602. [Google Scholar] [CrossRef] [PubMed]
[31] Flores-Flores, M., Luévano-Hipólito, E., Torres-Martínez, L.M. and Do, T.O. (2019) CO2 Adsorption and Photocatalytic Reduction over Mg(OH)2/CuO/Cu2O under UV-Visible Light to Solar Fuels. Materials Chemistry and Physics, 227, 90-97. [Google Scholar] [CrossRef
[32] Zamora-Ledezma, C., Negrete-Bolagay, D., Figueroa, F., Zamora-Ledezma, E., Ni, M., Alexis, F. and Guerrero, V.H. (2021) Heavy Metal Water Pollution: A Fresh Look about Hazards, Novel and Conventional Remediation Methods. Environmental Technology & Innovation, 22, Article ID: 101504. [Google Scholar] [CrossRef
[33] Xiao, L., Liu, J. and Ge, J. (2021) Dynamic Game in Agriculture and Industry Cross-Sectoral Water Pollution Governance in Developing Countries. Agricultural Water Management, 243, Article ID: 106417. [Google Scholar] [CrossRef
[34] Liu, L., Chen, Z., Zhang, J., Shan, D., Wu, Y., Bai, L. and Wang, B. (2021) Treatment of Industrial Dye Wastewater and Pharmaceutical Residue Wastewater by Advanced Oxidation Processes and Its Combination with Nanocatalysts: A Review. Journal of Water Process Engineering, 42, Article ID: 102122. [Google Scholar] [CrossRef
[35] Wadhawan, S., Jain, A., Nayyar, J. and Mehta, S.K. (2019) Role of Nanomaterials as Adsorbents in Heavy Metal Ion Removal from Waste Water: A Review. Journal of Water Process Engineering, 33, Article ID: 101038. [Google Scholar] [CrossRef
[36] Jiang, D., Yang, Y., Huang, C., Huang, M., Chen, J., Rao, T. and Ran, X. (2019) Removal of the Heavy Metal Ion Nickel (II) via an Adsorption Method Using Flower Globular Magnesium Hydroxide. Journal of Hazardous Materials, 373, 131-140. [Google Scholar] [CrossRef] [PubMed]
[37] Le, A.T., Pung, S.Y., Sreekantan, S. and Matsuda, A. (2019) Mechanisms of Removal of Heavy Metal Ions by ZnO Particles. Heliyon, 5, Article ID: e01440. [Google Scholar] [CrossRef] [PubMed]
[38] Yin, W.M., Wang, Y., Hou, Y.C., Sun, Y., Zhang, J.G., Sun, H.L. and Guo, Y.R. (2020) Petaloid-Array Hierarchically Structured Carbon Dots/Mg(OH)2 Composite: Design, Characterization and Removal/Recovery of Cadmium via Slowly Releasing. Chemical Engineering Journal, 401, Article ID: 125961. [Google Scholar] [CrossRef
[39] Xiong, C., Wang, W., Tan, F., Luo, F., Chen, J. and Qiao, X. (2015) Investigation on the Efficiency and Mechanism of Cd(II) and Pb(II) Removal from Aqueous Solutions Using MgO Nanoparticles. Journal of Hazardous Materials, 299, 664-674. [Google Scholar] [CrossRef] [PubMed]
[40] Guo, R., Zhu, Y., Cheng, X., Li, J. and Crittenden, J.C. (2020) Efficient Degradation of Lomefloxacin by Co-Cu-LDH Activating Peroxymonosulfate Process: Optimization, Dynamics, Degradation Pathway and Mechanism. Journal of Hazardous Materials, 399, Article ID: 122966. [Google Scholar] [CrossRef] [PubMed]
[41] 王家宏, 郭茹, 曹瑞华. 纳米氢氧化镁对水中络合态三价铬的吸附研究[J]. 中国皮革, 2019, 48(3): 46-53. [Google Scholar] [CrossRef
[42] El Bouraie, M. and Masoud, A.A. (2017) Adsorption of Phosphate Ions from Aqueous Solution by Modified Bentonite with Magnesium Hydroxide Mg(OH)2. Applied Clay Science, 140, 157-164. [Google Scholar] [CrossRef
[43] Jing, H.P., Li, Y., Wang, X., Zhao, J. and Xia, S. (2019) Simultaneous Recovery of Phosphate, Ammonium and Humic Acid from Wastewater Using a Biochar Supported Mg(OH)2/Bentonite Composite. Environmental Science: Water Research & Technology, 5, 931-943. [Google Scholar] [CrossRef
[44] AL-Darwish, N. and Abu-Sharar, T.M. (2021) Kinetics of Fluoride Adsorption onto Native and Mg(OH)2-Amended Limestone. Applied Water Science, 11, Article No. 37. [Google Scholar] [CrossRef
[45] Wei, Z.D., Liu, J.Y. and Shangguan, W.F. (2020) A Review on Photocatalysis in Antibiotic Wastewater: Pollutant Degradation and Hydrogen Production. Chinese Journal of Catalysis, 41, 1440-1450. [Google Scholar] [CrossRef
[46] Lu, J., Sun, Q., Wu, J. and Zhu, G. (2020) Enhanced Ozonation of Antibiotics Using Magnetic Mg(OH)2 Nanoparticles Made through Magnesium Recovery from Discarded Bischofite. Chemosphere, 238, Article ID: 124694. [Google Scholar] [CrossRef] [PubMed]
[47] Wang, Y., Lin, J., Wang, Y., Liu, Z., Lian, J. and Liu, M. (2020) Highly Efficient and Selective Removal of Low- Concentration Antibiotics from Aqueous Solution by Regenerable Mg(OH)2. Journal of Environmental Sciences, 87, 228-237. [Google Scholar] [CrossRef] [PubMed]
[48] Li, W., Mu, B. and Yang, Y. (2019) Feasibility of Industrial-Scale Treatment of Dye Wastewater via Bio-Adsorption Technology. Bioresource Technology, 277, 157-170. [Google Scholar] [CrossRef] [PubMed]
[49] Wong, S., Yac’cob, N.A.N., Ngadi, N., Hassan, O. and Inuwa, I.M. (2018) From Pollutant to Solution of Wastewater Pollution: Synthesis of Activated Carbon from Textile Sludge for Dye Adsorption. Chinese Journal of Chemical Engineering, 26, 870-878. [Google Scholar] [CrossRef
[50] Jiang, D., Wang, F., Lan, B., Wang, D., Liang, K., Li, T. and Li, Y. (2020) Efficient Treatment of Anthraquinone Dye Wastewater by Adsorption Using Sunflower Torus-Like Magnesium Hydroxide Microspheres. Korean Journal of Chemical Engineering, 37, 434-447. [Google Scholar] [CrossRef
[51] Liu, M., Yin, W., Zhao, T.L., Yao, Q.Z., Fu, S.Q. and Zhou, G.T. (2021) High-Efficient Removal of Organic Dyes from Model Wastewater Using Mg(OH)2-MnO2 Nanocomposite: Synergistic Effects of Adsorption, Precipitation, and Photodegradation. Separation and Purification Technology, 272, Article ID: 118901. [Google Scholar] [CrossRef
[52] Yan, H., Bai, J., Chen, X., Wang, J., Zhang, H., Liu, Q. and Liu, L. (2013) High U(VI) Adsorption Capacity by Mesoporous Mg(OH)2 Deriving from MgO Hydrolysis. RSC Advances, 3, 23278-23289. [Google Scholar] [CrossRef
[53] Chen, Y.Y., Yu, S.H., Yao, Q.Z., Fu, S.Q. and Zhou, G.T. (2018) One-Step Synthesis of Ag2O@Mg(OH)2 Nanocomposite as an Efficient Scavenger for Iodine and Uranium. Journal of Colloid and Interface Science, 510, 280-291. [Google Scholar] [CrossRef] [PubMed]