电化学方法制备H2O2催化剂研究进展
Recent Advances in Catalysts for Electrochemical Methods of H2O2 Production
DOI: 10.12677/NAT.2022.124026, PDF,  被引量    科研立项经费支持
作者: 韩 涛, 胡俊华, 王晓霞*：华东理工大学机械与动力工程学院，上海；郭子琪, 孙君沣, 姚奕江：华东理工大学材料科学与工程学院，上海；叶浩楠：华东理工大学化工学院，上海
关键词: 过氧化氢；2电子氧还原反应；催化剂；电化学； Hydrogen Peroxide (H2O2)； Two-Electron Oxygen Reduction Reaction； Catalysts； Electrochemistry
摘要: 通过氧的电化学反应制备H2O2，是一种绿色环保、易于实现的新能源利用途径，近年来受到了广泛的关注，有望成为目前工业蒽醌法的替代工艺。有效实现这一工艺的根本条件是使用低成本、高效的电催化剂，这也是决定H2O2生产效率的关键因素。本文综述了近几年通过2电子氧化还原路径直接制备H2O2所取得的进展，着重介绍了催化剂结构、组成与催化活性之间的依赖关系以及相关催化机制，最后，对2电子氧还原催化剂的发展给出了展望。
Abstract: Direct electrochemical production of hydrogen peroxide (H2O2) through two-electron oxygen electrochemistry is an effective way to uti-lization of green energy, which has attracted widespread attention in recent years and has emerged as the most promising method to replace the traditional anthraquinone process. The practical ap-plication of these processes depends greatly on the low-cost and highly effective catalysts, which are also the determining factor for theH2O2 production efficiency. Herein, we review the advances in electrochemical H2O2 production through a two-electron Oxygen Reduction Reaction (ORR). We fo-cus on the relationship between the unique structure-, component-, and composition-dependent electrochemical performance, as well as the related catalytic mechanisms. Finally, the perspective on the development of the catalysts for two-electron ORR is provided.
文章引用：韩涛, 胡俊华, 郭子琪, 孙君沣, 姚奕江, 叶浩楠, 王晓霞. 电化学方法制备H2O2催化剂研究进展[J]. 纳米技术, 2022, 12(4): 258-269. https://doi.org/10.12677/NAT.2022.124026

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