共价有机框架(COFs)在光催化制备过氧化氢(H2O2)领域的研究进展
Research Progress of Covalent Organic Frameworks (COFs) in Photocatalytic Preparation of Hydrogen Peroxide (H2O2)
DOI: 10.12677/aac.2026.161001, PDF,   
作者: 龚文康：浙江师范大学化学与材料科学学院，浙江 金华
关键词: 共价有机框架；光催化；过氧化氢；太阳能转化；Covalent Organic Framework； Photocatalysis； Hydrogen Peroxide； Solar Energy Conversion
摘要: 过氧化氢(H2O2)作为绿色高效氧化剂，广泛应用于化工合成、环境治理及生物医药等领域，但传统蒽醌法存在能耗高、污染大的缺陷，光催化制备过H2O2就是利用太阳能和光催化剂驱动O2还原H2O氧化生成H2O2，是极具前景的绿色路径。共价有机框架(COFs)因结构可调、比表面积大、共轭稳定，结构易调控等特性，成为光催化产H2O2的理想材料。本文梳理了COFs的光催化机制，设计策略、及优化方向，分析了稳定性、成本等挑战，并总结了2020~2025年具有代表性的几种COFs用于光催化产H2O2的设计策略与不足之处，对COFs精准设计与实际应用进行展望，为COFs光催化产H2O2领域的发展提供参考。
Abstract: Hydrogen peroxide (H2O2), as a green and efficient oxidant, is widely used in chemical synthesis, environmental treatment, and biomedicine, etc. However, the traditional anthraquinone method has the drawbacks of high energy consumption and significant pollution. Photocatalytic production of H2O2 utilizes solar energy and photocatalysts to drive the reduction of O2 and oxidation of water to generate H2O2, which is a promising green approach. Covalent organic frameworks (COFs) have become ideal materials for photocatalytic production of H2O2 due to their adjustable structures, large specific surface areas, stable conjugation, and easy structural regulation. This paper reviews the photocatalytic mechanism, design strategies, and optimization directions of COFs, analyzes the challenges such as stability and cost, and summarizes several representative design strategies and shortcomings of COFs for photocatalytic production of H2O2 from 2020 to 2025. It looks forward to the precise design and practical application of COFs, providing reference for the development of COFs in the field of photocatalytic production of H2O2.
文章引用：龚文康. 共价有机框架(COFs)在光催化制备过氧化氢(H2O2)领域的研究进展[J]. 分析化学进展, 2026, 16(1): 1-8. https://doi.org/10.12677/aac.2026.161001

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