基于g-C3N4的复合材料在压电光催化领域的研究进展
Research Progress of g-C3N4-Based Composite Materials in the Field of Piezoelectric Photocatalysis
DOI: 10.12677/ms.2026.163049, PDF,   
作者: 梁语嫣, 董坤范, 邓梓瑜, 贾静茹, 周峻安, 傅仰河*：浙江师范大学含氟新材料研究所，先进催化材料教育部重点实验室，浙江 金华
关键词: 压电光催化；g-C3N4复合材料；Piezoelectric Photocatalysis； g-C3N4-Based Composites
摘要: 压电光催化是一种通过耦合半导体材料的光激发特性和压电材料的机械能响应的新兴协同催化技术，有效解决传统光催化中光生载流子快速复合的关键问题。石墨相氮化碳(g-C3N4)因其独特的非中心对称层状结构(具本征压电性)、可见光响应、适宜能带结构及高稳定性等优势，成为构建高性能压电光催化复合材料的理想基底。本文系统综述了近年来基于g-C3N4的复合材料在压电光催化领域的主要进展，重点阐述材料的设计策略、性能增强机理及应用。
Abstract: Piezoelectric photocatalysis is an emerging synergistic catalytic technology that addresses the critical issue of rapid recombination of photogenerated carriers in traditional photocatalysis by coupling the photoexcitation properties of semiconductor materials with the mechanical energy response of piezoelectric materials. Graphitic carbon nitride (g-C3N4), with its unique non-centrosymmetric layered structure (endowing it with intrinsic piezoelectricity), visible-light responsiveness, suitable band structure, and high stability, serves as an ideal substrate for constructing high-performance piezoelectric photocatalytic composites. This paper systematically reviews recent advances in g-C3N4-based composite materials in the field of piezoelectric photocatalysis, with a focus on design strategies, performance enhancement mechanisms, and applications.
文章引用：梁语嫣, 董坤范, 邓梓瑜, 贾静茹, 周峻安, 傅仰河. 基于g-C3N4的复合材料在压电光催化领域的研究进展[J]. 材料科学, 2026, 16(3): 35-42. https://doi.org/10.12677/ms.2026.163049

参考文献

[1] Liu, Q., Zhao, Y., Wang, J., Zhou, Y., Liu, X., Hao, M., et al. (2023) Application of Single-Atom-Based Photocatalysts in Environmental Pollutant Removal and Renewable Energy Production. Critical Reviews in Environmental Science and Technology, 54, 909-930. [Google Scholar] [CrossRef] 
[2] Yu, C., Tan, M., Tao, C., Hou, Y., Liu, C., Meng, H., et al. (2022) Remarkably Enhanced Piezo-Photocatalytic Performance in BaTiO3/CuO Heterostructures for Organic Pollutant Degradation. Journal of Advanced Ceramics, 11, 414-426. [Google Scholar] [CrossRef] 
[3] Loeb, S.K., Alvarez, P.J.J., Brame, J.A., Cates, E.L., Choi, W., Crittenden, J., et al. (2018) The Technology Horizon for Photocatalytic Water Treatment: Sunrise or Sunset? Environmental Science & Technology, 53, 2937-2947. [Google Scholar] [CrossRef] [PubMed]
[4] Tu, S., Guo, Y., Zhang, Y., Hu, C., Zhang, T., Ma, T., et al. (2020) Piezocatalysis and Piezo‐Photocatalysis: Catalysts Classification and Modification Strategy, Reaction Mechanism, and Practical Application. Advanced Functional Materials, 30, Article 2005158. [Google Scholar] [CrossRef] 
[5] Kumar, D., Sharma, S. and Khare, N. (2021) Piezo-phototronic and Plasmonic Effect Coupled Ag-NaNbO3 Nanocomposite for Enhanced Photocatalytic and Photoelectrochemical Water Splitting Activity. Renewable Energy, 163, 1569-1579. [Google Scholar] [CrossRef] 
[6] Wang, Z., Hu, T., He, H., Fu, Y., Zhang, X., Sun, J., et al. (2018) Enhanced H2 Production of TiO2/ZnO Nanowires Co-Using Solar and Mechanical Energy through Piezo-Photocatalytic Effect. ACS Sustainable Chemistry & Engineering, 6, 10162-10172. [Google Scholar] [CrossRef] 
[7] Lei, H., Wu, M., Mo, F., Ji, S., Dong, X., Jia, Y., et al. (2021) Efficiently Harvesting the Ultrasonic Vibration Energy of Two-Dimensional Graphitic Carbon Nitride for Piezocatalytic Degradation of Dichlorophenols. Environmental Science: Nano, 8, 1398-1407. [Google Scholar] [CrossRef] 
[8] Chen, Z., Yu, X., Zhu, Q., Fan, T., Wu, Q., Zhang, L., et al. (2018) Steam Engraving Optimization of Graphitic Carbon Nitride with Enhanced Photocatalytic Hydrogen Evolution. Carbon, 139, 189-194. [Google Scholar] [CrossRef] 
[9] Feng, Q., Liu, Z., Su, R., Chen, Y., Wang, Y., Ma, D., et al. (2025) Revealing the Reaction Mechanism of the Novel P-N Heterojunction Mn3O4-C3N4 in Efficient Activation of Chlorite to Degrade Organic Pollutants under Piezoelectric Catalysis. Applied Catalysis B: Environment and Energy, 362, Article 124714. [Google Scholar] [CrossRef] 
[10] Zhu, W., Yue, Y., Wang, H., Zhang, B., Hou, R., Xiao, J., et al. (2023) Recent Advances on Energy and Environmental Application of Graphitic Carbon Nitride (g-C3n4)-Based Photocatalysts: A Review. Journal of Environmental Chemical Engineering, 11, Article 110164. [Google Scholar] [CrossRef] 
[11] Xie, M., Tang, J., Kong, L., Lu, W., Natarajan, V., Zhu, F., et al. (2019) Cobalt Doped g-C3N4 Activation of Peroxymonosulfate for Monochlorophenols Degradation. Chemical Engineering Journal, 360, 1213-1222. [Google Scholar] [CrossRef] 
[12] Kang, Z., Ke, K., Lin, E., Qin, N., Wu, J., Huang, R., et al. (2022) Piezoelectric Polarization Modulated Novel Bi2WO6/g-C3N4/ZnO Z-Scheme Heterojunctions with G-C3n4 Intermediate Layer for Efficient Piezo-Photocatalytic Decomposition of Harmful Organic Pollutants. Journal of Colloid and Interface Science, 607, 1589-1602. [Google Scholar] [CrossRef] [PubMed]
[13] Gong, S., Zhang, W., Liang, Z., Zhang, Y., Gan, T., Hu, H., et al. (2023) Construction of a BaTiO3/Tubular g-C3N4 Dual Piezoelectric Photocatalyst with Enhanced Carrier Separation for Efficient Degradation of Tetracycline. Chemical Engineering Journal, 461, Article 141947. [Google Scholar] [CrossRef] 
[14] Su, T., Hood, Z.D., Naguib, M., Bai, L., Luo, S., Rouleau, C.M., et al. (2019) 2D/2D Heterojunction of Ti3C2/g-C3N4 Nanosheets for Enhanced Photocatalytic Hydrogen Evolution. Nanoscale, 11, 8138-8149. [Google Scholar] [CrossRef] [PubMed]
[15] Zhao, Z., Chen, R., Ling, Q., Yan, K., Gan, W., Lu, Y., et al. (2025) Enhanced H2O2 Production via Piezo-Photocatalysis Using BaTiO3/g-C3N4 S-Scheme Heterojunction. Journal of Environmental Chemical Engineering, 13, Article 115575. [Google Scholar] [CrossRef] 
[16] Zhao, B., Zhong, W., Chen, F., Wang, P., Bie, C. and Yu, H. (2023) High-Crystalline G-C3N4 Photocatalysts: Synthesis, Structure Modulation, and H2-Evolution Application. Chinese Journal of Catalysis, 52, 127-143. [Google Scholar] [CrossRef] 
[17] Li, Y., Jin, R., Xing, Y., Li, J., Song, S., Liu, X., et al. (2016) Macroscopic Foam‐Like Holey Ultrathin g‐C3N4 Nanosheets for Drastic Improvement of Visible‐Light Photocatalytic Activity. Advanced Energy Materials, 6, Article 1601273. [Google Scholar] [CrossRef] 
[18] Xiao, J., Liu, Q., Song, M., Li, X., Li, Q. and Shang, J.K. (2021) Directing Photocatalytic Pathway to Exceedingly High Antibacterial Activity in Water by Functionalizing Holey Ultrathin Nanosheets of Graphitic Carbon Nitride. Water Research, 198, Article 117125. [Google Scholar] [CrossRef] [PubMed]
[19] Gao, S., Wang, X., Song, C., Zhou, S., Yang, F. and Kong, Y. (2021) Engineering Carbon-Defects on Ultrathin g-C3N4 Allows One-Pot Output and Dramatically Boosts Photoredox Catalytic Activity. Applied Catalysis B: Environmental, 295, Article 120272. [Google Scholar] [CrossRef] 
[20] Xue, Y., Ma, C., Yang, Q., Wang, X., An, S., Zhang, X., et al. (2023) Construction of g-C3N4 with Three Coordinated Nitrogen (N3C) Vacancies for Excellent Photocatalytic Activities of N2 Fixation and H2O2 Production. Chemical Engineering Journal, 457, Article 141146. [Google Scholar] [CrossRef] 
[21] Li, W., Zeng, H., Zhou, Z., Li, L., Tang, R., Ding, C., et al. (2025) Sulfur-Synergized Dual-Cobalt Anchoring Configuration in Carbon Nitride: Deciphering Cooperative Mechanisms for Boosted Peroxymonosulfate Activation. Chemical Engineering Journal, 520, Article 166214. [Google Scholar] [CrossRef] 
[22] Mottammal, D., Cherusseri, J., Thomas, S.A., Isaac R.S., R., Rajendran, D.N. and Choi, M.Y. (2025) Toward Doping in Graphitic Carbon Nitride: Progress and Perspectives on Catalytic Hydrogen Production. Advanced Materials Technologies, 10, e00667. [Google Scholar] [CrossRef] 
[23] Qaraah, F.A., Mahyoub, S.A., Shen, H., Yin, X., Salah, A., Onaizi, S.A., et al. (2025) Synergistic Role of Dual-Metal Sites (Ag-Ni) in Hexagonal Porous g-C3N4 Nanostructures for Enhanced Photocatalytic CO2 Reduction. Carbon, 232, Article 119735. [Google Scholar] [CrossRef] 
[24] Low, J., Yu, J., Jaroniec, M., Wageh, S. and Al‐Ghamdi, A.A. (2017) Heterojunction Photocatalysts. Advanced Materials, 29, Article 1601694. [Google Scholar] [CrossRef] [PubMed]
[25] Mishra, S., Kumar, A. and Verma, N. (2025) G-C3N4-Supported Nibo3 (B = Ti, Sn) Perovskite-Based Arrow-Up Dual-S Scheme Heterostructure for Efficient Hydrogen Production via Water Splitting. Fuel, 399, Article 135673. [Google Scholar] [CrossRef] 
[26] Wang, W., Fang, J., Shao, S., Lai, M. and Lu, C. (2017) Compact and Uniform TiO2@g-C3N4 Core-Shell Quantum Heterojunction for Photocatalytic Degradation of Tetracycline Antibiotics. Applied Catalysis B: Environmental, 217, 57-64. [Google Scholar] [CrossRef] 
[27] Khadim, H.J., Ammar, S.H., Al-Farraji, A., Mohammed, M.S., Jabbar, Z.H. and Alabdly, H.A. (2025) Fabrication of AgBr/Br-Doped g-C3N4 Hybrids for Efficient Piezo-Photocatalytic Degradation of Organic Pollutants in Split-Plate Airlift Reactor. Journal of Water Process Engineering, 76, Article 108118. [Google Scholar] [CrossRef] 
[28] Mohammed, M.S., Ammar, S.H., Kareem, Y.S. and Al-Farraji, A. (2025) Assembly of Fe-Doped g-C3N4 as a Robust Piezophotocatalyst System for Degradation of Organic Dyes. Journal of Molecular Structure, 1344, Article 142962. [Google Scholar] [CrossRef] 
[29] Wu, T., Liu, Z., Shao, B., He, Q., Pan, Y., Zhang, X., et al. (2024) Enhanced Piezo-Photocatalytic Degradation of Organic Pollutants by Cambered Wall Lamellar Structure of Porous Tubular g-C3N4. Nano Energy, 120, Article 109137. [Google Scholar] [CrossRef] 
[30] Tang, R., Gong, D., Zhou, Y., Deng, Y., Feng, C., Xiong, S., et al. (2022) Unique g-C3N4/PDI-g-C3N4 Homojunction with Synergistic Piezo-Photocatalytic Effect for Aquatic Contaminant Control and H2O2 Generation under Visible Light. Applied Catalysis B: Environmental, 303, Article 120929. [Google Scholar] [CrossRef] 
[31] Liu, G., Zhao, T., Wu, J., Chang, M., Fei, H., Li, F., et al. (2025) Enhanced Removal and Selective Conversion for NO with N-Vacancies g-C3N4/BaTiO3 by Piezo-Photocatalysis. Separation and Purification Technology, 360, Article 130914. [Google Scholar] [CrossRef] 
[32] Cui, Y., Wang, Z., Li, B., Yan, Y., Xu, R., Meng, M., et al. (2022) Fluid-Induced Piezoelectric Field Enhancing Photocatalytic Hydrogen Evolution Reaction on g-C3N4/liNbO3/PVDF Membrane. Nano Energy, 99, Article 107429. [Google Scholar] [CrossRef] 
[33] Meng, L., Zhao, C., Zhang, X., Guo, R., Zheng, Y., Chu, H., et al. (2024) Piezo-Photocatalytic Synergetic for H2O2 Generation via Dual-Pathway over Z-Scheme ZIF-L/g-C3N4 Heterojunction. Nano Energy, 128, Article 109795. [Google Scholar] [CrossRef] 
[34] Wang, P., Fan, S., Li, X., Duan, J. and Zhang, D. (2023) Modulating the Molecular Structure of Graphitic Carbon Nitride for Identifying the Impact of the Piezoelectric Effect on Photocatalytic H2O2 Production. ACS Catalysis, 13, 9515-9523. [Google Scholar] [CrossRef] 

为你推荐