1,1',2,3-四氯丙烯合成工艺的研究进展
Research Progress on Synthetic Technology of 1,1',2,3-Tetrachloropropene
DOI: 10.12677/HJCET.2018.81002, PDF,   
作者: 王 蓓, 陈向莹, 贾爱铨, 张千峰：安徽工业大学分子工程与应用化学研究所，安徽 马鞍山
关键词: 1；1'；2；3-四氯丙烯(HCC-1230xa)；制冷剂中间体；合成路径；工艺技术；1；1'；2；3-Tetrachloropropene (HCC-1230xa)； Refrigerant Intermediate； Synthetic Route； Process Engineering
摘要: 1,1',2,3-四氯丙烯(HCC-1230xa)是除草剂野麦畏和新一代环保型制冷剂2,3,3',3''-四氟丙烯(HFO-1234yf)的重要中间体，本文围绕1,1',2,3-四氯丙烯的合成工艺情况进行分析，并针对现有工艺技术的优缺点以及结合目前国内的技术现状，有必要探寻一个具有发展前景和清洁绿色合成高产率和高纯度1,1',2,3-四氯丙烯的新路径。
Abstract: 1,1',2,3-Tetrachloropropene (HCC-1230xa) is an important intermediate for Herbicide triallate and new generation of environmentally friendly refrigerant 2,3,3',3''-tetrafluoropropene (HFO- 1234yf). Synthetic routes of 1,1',2,3-tetrachloropropene were comparatively investigated in detail. Based upon advantages and disadvantages of different process engineering, it is quite necessary to explore a clean and environmentally friendly technology to synthesize 1,1',2,3-tetrachloropro- pene with high yield and purity.
文章引用：王蓓, 陈向莹, 贾爱铨, 张千峰. 1,1',2,3-四氯丙烯合成工艺的研究进展[J]. 化学工程与技术, 2018, 8(1): 10-16. https://doi.org/10.12677/HJCET.2018.81002

参考文献

[1] 田晓宏, 李建高, 汤效先. 1,1',2,3-四氯丙烯生产工艺[P]. CN101955414 A, 2011-1-26.
[2] 张彦, 雷俊, 周华东, 等. 一种1,1',2,3-四氯丙烯的制备方法[P]. CN103524296 A, 2014-1-22.
[3] 赵新堂, 杨会娥, 刘坤峰, 等. 1,1',2,3-四氯丙烯制备技术研究进展[J]. 浙江化工, 2010, 41(8): 8-10.
[4] 张炳炎. 野麦畏及其应用[M]. 兰州: 甘肃科学技术出版社, 2002: 8-32.
[5] 陈万义. 农药生产与合成[M]. 北京: 化学工业出版社, 2000: 458-461.
[6] Calm, J.M. (2008) The Next Generation of Refrigerants-Historical Review, Considerations, and Outlook. International Journal of Refrigeration, 31, 1123-1333. [Google Scholar] [CrossRef] 
[7] Nielsen, O.J., Javadi, M.S., Sulbaek Andersen, M.P., et al. (2007) Atmospheric Chemistry of CF3CF=CH2: Kinetics and Mechanisms of Gas-Phase Reactions with CI Atoms, OH Radicals, and O3. Chemical Physics Letters, 439, 18-22. [Google Scholar] [CrossRef] 
[8] 良伟. 新一代汽车空调制冷剂的角逐: R-744 PK R-1234yf [J]. 中国化工信息, 2009(25): 14.
[9] 曹霞. HFO-1234yf——新一代汽车空调制冷剂[J]. 制冷与空调, 2008, 8(6): 55-61.
[10] Elsheikh, Maher, Y., et al. Catalytic Gas Phase Fluorination of 1230xa to1234yf. WO 2009158321. 2009-12-30.
[11] Haszeldine, R.N. (1953) Synthesis and Reactions of Some 3,3',3''-Trihalogenopropenes. Journal of the Chemical Society, 3371-3378. [Google Scholar] [CrossRef] 
[12] Smith, L.R. Preparation of 1,1',2,3-Tetrachloropropene from 1,2,3-Trichloropropane. US 3823195, 1974-7-9.
[13] Smith, L.R. and Chesterfield, Mo. Preparation of 1,1',2,3-Tetrachloropropene from 2,3-Trichloropropane. US 3926758, 1975-12-6.
[14] Asahara, T. and Sato, T. (1971) Telomerization of Ethylene with Carbon Tetrachloride Initiated by N-Dichloro-n-bu- tylamine-Amines. The Journal of the Society of Chemical Industry, Japan, 74, 1845-1847. [Google Scholar] [CrossRef] 
[15] Woodard, S.S. and Maryland, H.Mo. Preparation for Producing 1,1',2,3-Tetrachloropropene. US 4535194, 1985-8-13.
[16] Woodard, S.S. Maryland Heights, MO. Preparation for Producing 1,1',2,3-Tetrachloropropene. US 4650914, 1987-3- 17.
[17] Wang, H.Y. and Sung, T.H. Synthesis of 1,1',2,3-Trihalogenopropenes. US 20140221705A1, 2014-8-7.
[18] Merkel, D.C., Tung, H.S., Van Der Puy, M. and Ma, J.J. Processes for Preparing 1,1',2,3-Tetrachloropropene. US 8258355 B2, 2012-9-4.
[19] Nose, M. and Suzuki, A. Processes for Preparing 1,1',2,3-Tetrachloropropene. WO 2011065574, 2011-6-3.